Can Li

Can Li
Guiyang university · Graduate Office Of Guiyang University

Professor

About

957
Publications
163,557
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71,168
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Introduction
Carry out the research on the key techniques of the domestication, breeding and deep processing of giant salamander, and has carried out the research work on “Modified Atmosphere Toxicology of Insects” In the direction of transcriptome and proteomics, the research work on functional polypeptides of giant salamander has been led in the field. In serving the development of modern Chinese medicine industry, pest control management and controlled atmosphere toxicology have been carried out. The concept of "Insect Controlled Atmosphere Toxicology" has been put forward for the first time in the world, and more than ten years of research has been organized. To supplement the theory, carried out systematic studies on the toxicology of pests in stored Chinese medicinal materials at the physiologica

Publications

Publications (957)
Article
Full-text available
The photocatalytic oxidation of water with gaseous oxygen is environmentally benign for the synthesis of hydrogen peroxide (H2O2), but it is currently constrained by the inadequate supply of gaseous oxygen at the catalyst surface in a solid–liquid–gas triple‐phase reaction system. Herein, we address this challenge by employing the zeolite encapsula...
Article
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Compared to the sluggish kinetics observed in methanol-mediated side-chain alkylation of methyl groups with sp³ C–H bonds, CO2 hydrogenation emerges as a sustainable alternative strategy, yet it remains a challenge. Here, as far as we know, it is first reported that using CO2 hydrogenation replacing methanol can conduct the side-chain alkylation of...
Article
The photocatalytic oxidation of water with gaseous oxygen is environmentally benign for the synthesis of hydrogen peroxide (H2O2), but it is currently constrained by the inadequate supply of gaseous oxygen at the catalyst surface in a solid‐liquid‐gas triple‐phase reaction system. Herein, we address this challenge by employing the zeolite encapsula...
Article
Full-text available
Plasmonic resonance intensity in metallic nanostructures plays a crucial role in charge generation and separation, directly affecting plasmon‐induced photocatalytic activity. Engineering strategies to enhance plasmonic effects involve designing specific nanostructures, such as triangular nanoplates with sharp corners or dimer nanostructures with ho...
Preprint
We report transport measurements of infinite-layer cuprate Sr$_{1-x}$Eu$_{x}$CuO$_{2+y}$ films with controlled electron (by trivalent europium) and hole (by interstitial apical oxygen) carriers grown on SrTiO$_3$(001) with molecular beam epitaxy. An unusual enhancement of superconductivity upon moderate electron-hole coexistence in the films is fou...
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The development of efficient and durable electrocatalysts for the acidic oxygen evolution reaction (OER) is essential for advancing renewable hydrogen energy technology. However, the slow deprotonation kinetics of oxo‐intermediates, involving the four proton‐coupled electron steps, hinder the acidic OER progress. Herein, a RuTiOx solid solution ele...
Preprint
Unconventional superconductors that spontaneously break space-group symmetries of their underlying crystal lattice are distinguished by spatial modulations of the superconducting order parameter. These states have recently captured significant attention in various strongly correlated materials, where the breaking of translational or intra-unit-cell...
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Developing an efficient strategy to replace the conventional synthesis method for producing isoindolinone (IIO) scaffold, a crucial structural motif for constructing pharmaceutical molecules, remains to be a great challenge. Herein, a single‐atom Pd/TiO2 tandem catalysis has been developed for the IIO scaffold synthesis by using readily available p...
Article
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Photogenerated charge separation is pivotal for effecting efficient photocatalytic reactions. Understanding this process with spatiotemporal resolution is vital for devising highly efficient photocatalysts. Here, we employed pump–probe transient reflection microscopy to directly observe the temporal and spatial evolution of photogenerated electrons...
Article
Developing an efficient strategy to replace the conventional synthesis method for producing isoindolinone (IIO) scaffold, a crucial structural motif for constructing pharmaceutical molecules, remains to be a great challenge. Herein, a single‐atom Pd/TiO2 tandem catalysis has been developed for the IIO scaffold synthesis by using readily available p...
Article
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Bismuth-based binary alloy β-Bi2Pd has recently been suggested as a connate topological superconductor with immense promise for Majorana zero modes. However, the epitaxial thin films down to the ultimate level of single unit-cell have been challenging. Here, we employed the state-of-the-art molecular beam epitaxy to prepare single unit-cell superco...
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Cytochrome P450 monooxygenases (CYP), crucial detoxification enzymes in insects, are involved in the metabolism of endogenous substances as well as the activation and degradation of exogenous compounds. In this study, T. castaneum was utilized to investigate the roles of TcCYP6K1 and TcCYP9F2 genes influencing in the trehalose metabolism pathway un...
Article
Host plants can strongly influence the population performance of insects. Here, we investigated the development, survival, and oviposition of Scirtothrips dorsalis Hood on 6 host plants—Camellia sinensis ( L.) Kuntze (Ericales: Theaceae), Rosa chinensis Jacq. (Rosales: Rosaceae), Capsicum annuum L. (Solanales: Solanaceae), Eustoma grandiflorum (Hoo...
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Although the nickel–molybdenum electrocatalyst exhibits excellent activity in the alkaline hydrogen evolution reaction (HER), its stability is poor mainly due to molybdenum leaching. This work reports that doping samarium into nickel–molybdenum electrocatalyst effectively suppresses molybdenum leaching by forming a stable phase consisting of Sm, Mo...
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It is challenging to develop highly active and durable electrocatalysts for hydrogen evolution reaction (HER) in alkaline water electrolysis. Herein, an electrocatalyst is synthesized with highly dispersed cerium in a nickel matrix, showing an overpotential of 169 mV for HER at a current density of 500 mA cm⁻², about 137 mV lower than that observed...
Article
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BACKGROUND MicroRNA (miRNA) pathway genes have been widely reported to participate in several physiological events in insect lifecycles. The cigarette beetle Lasioderma serricorne is an economically important storage pest worldwide. However, the functions of miRNA pathway genes in L. serricorne remain to be clarified. Herein, we investigated the fu...
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Hindered ethers are ubiquitous in natural products and bioactive molecules. However, developing an efficient method for the stereocontrolled synthesis of all stereoisomers of chiral hindered ethers is highly desirable but challenging. Here we show a strategy that utilizes in situ-generated water as a nucleophile in an asymmetric cascade reaction in...
Article
Soil microbiomes play a crucial role in enhancing plant growth, health, and overall agricultural productivity. Nevertheless, the influence of distinct agricultural management practices on the microbial diversity and community structure within tea (Camellia sinensis) plantations has remained enigmatic. This study postulates that organic agricultural...
Article
Solar-driven photocatalytic reactions offer a promising route to clean and sustainable energy, and the spatial separation of photogenerated charges on the photocatalyst surface is the key to determining photocatalytic efficiency. However, probing the charge-separation properties of photocatalysts is a formidable challenge because of the spatially h...
Article
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Erythroneurini is the largest tribe of the microleafhopper subfamily Typhlocybinae. Most prior research on this tribe has focused on traditional classification, phylogeny, and control of agricultural pests, and the phylogeography of the group remains poorly understood. In this study, the mitochondrial genomes of 10 erythroneurine species were seque...
Article
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Modified atmosphere is effective in controlling Tribolium castaneum Herbst, but it has adaptations. Comprehending the potential mechanism of resistance to T. castaneum in a modified atmosphere will help advance related management methods. This study conducted a comparative transcriptomic and metabolomic analysis to understand the physiological mech...
Article
Erythroneurine leafhoppers (Hemiptera, Cicadellidae, Typhlocybinae, Erythroneurini) are utilized to resolve the relationship between the four erythroneurine leafhopper (Hemiptera, Cicadellidae, Typhlocybinae, Erythroneurini): Arboridia ( Arboridia ) rongchangensis sp. nov., Thaia ( Thaia ) jiulongensis sp. nov., Mitjaevia bifurcata Luo, Song & Song...
Article
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Upgrading of polyethylene terephthalate (PET) waste into valuable oxygenated molecules is a fascinating process, yet it remains challenging. Herein, we developed a two‐step strategy involving methanolysis of PET to dimethyl terephthalate (DMT), followed by hydrogenation of DMT to produce the high‐valued chemical methyl p‐methyl benzoate (MMB) using...
Article
Full-text available
Converting CO2 to olefins is an ideal route to achieve carbon neutrality. However, selective hydrogenation to light olefins, especially single‐component olefin, while reducing CH4 formation remains a great challenge. Herein, we developed ZnZrOx/SSZ‐13 tandem catalyst for the highly selective hydrogenation of CO2 to light olefins. This catalyst show...
Article
Upgrading of polyethylene terephthalate (PET) waste into valuable oxygenated molecules is a fascinating process, yet it remains challenging. Herein, we developed a two‐step strategy involving methanolysis of PET to dimethyl terephthalate (DMT), followed by hydrogenation of DMT to produce the high‐valued chemical methyl p‐methyl benzoate (MMB) using...
Article
Converting CO2 to olefins is an ideal route to achieve carbon neutrality. However, selective hydrogenation to light olefins, especially single‐component olefin, while reducing CH4 formation remains a great challenge. Herein, we developed ZnZrOx/SSZ‐13 tandem catalyst for the highly selective hydrogenation of CO2 to light olefins. This catalyst show...
Article
Although size engineering has been recognized as a useful strategy in elevating the photocatalytic performance, the significant role of crystal size in the charge separation process within semiconductor photocatalysts remains...
Article
By means of molecular beam epitaxy, x-ray diffraction, transmission electron microscopy, and in situ scanning tunneling microscopy, we successfully prepare type-II Dirac semimetal 1T−NiTe2 films and investigate their surface morphology, electronic structure, and topological characteristics on the atomic scale. Atomically flat NiTe2 films can be rea...
Article
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Introduction: The tea green leafhopper, Empoasca (Matsumurasca) onukii Matsuda, R., 1952 (Hemiptera: Cicadellidae), is currently one of the most devastating pests in the Chinese tea industry. The long-term use of chemical pesticides has a negative impact on human health, impeding the healthy and sustainable development of the tea industry in this r...
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Leafhoppers (Hemiptera, Auchenorrhyncha, Cicadellidae) are distributed worldwide and include around 2550 genera, more than 21,000 species, including almost 2000 species in China. Typhlocybinae is the second largest subfamily in Cicadellidae after Deltocephalinae. Previously, morphological characteristics were the diagnostic basis of taxonomy, but t...
Article
Pt catalyst has been considered as the state-of-the-art catalyst for hydrogen evolution reaction (HER) under acid condition. However, its catalytic kinetics under alkaline conditions is not well-understood. Herein, we report a Ni-Pt(SAs) (SAs = single atoms) catalyst with Pt atomically dispersed in a Ni matrix, and it possesses an impressive HER pe...
Article
Full-text available
The CO2 concentration at ribulose-1,5-bisphosphate carboxylase/oxygenase (Rubisco) is crucial to improve photosynthetic efficiency for biomass yield. However, how to concentrate and transport atmospheric CO2 towards the Rubisco carboxylation is a big challenge. Herein, we report the self-assembly of metal-organic frameworks (MOFs) on the surface of...
Article
The oxygen evolution reaction (OER) from water is a sequential oxidation reaction process, involved in transformation of multiple reaction intermediates. For photo(electro)catalytic OER, revealing the intermediates transformation kinetics is quite challenging due to its coupling with photogenerated charge dynamics. Herein, we specifically study the...
Article
Although spatial charge separation between different facets of semiconductor crystals has been recognized as a general strategy in photocatalysis, the vital role of crystal morphology symmetry in charge separation properties still remains elusive. Herein, taking monoclinic bismuth vanadate (BiVO4) as a platform, we found distinct charge separation...
Preprint
Full-text available
Electronic liquid-crystal phases are observed in numerous strongly-correlated systems including high-temperature superconductors. However, identifying these exotic phases and understanding their interplay with superconductivity in topological materials remain challenging. Here we employ a cryogenic scanning tunneling microscopy to discover a smecti...
Article
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The robust and scalable oxygen evolution electrocatalysts that can deliver high current densities at low applied potential is a great challenge for the large‐scale industrial application in hydrogen production. Here, the preparation of a grain‐boundary‐rich Ni‐Fe (oxy)hydroxide catalyst on Ni foam is reported using a scalable coating approach follo...
Article
The inert C(sp3)-H bond and easy overoxidation of toluene make the selective oxidation of toluene to benzaldehyde a great challenge. Herein, we present that a photocatalyst, constructed with a small amount (1 mol %) of amorphous BiOCl nanosheets assembled on TiO2 (denoted as 0.01BOC/TiO2), shows excellent performance in toluene oxidation to benzald...
Article
Superconducting infinite-layer Sr1−xEuxCuO2 films at optimal doping (x∼0.15) have been epitaxially grown on SrTiO3(001) substrates with oxide molecular beam epitaxy. By combining x-ray diffraction and transport measurements, we have established a narrow window of growth conditions [i.e., ozone pressure, substrate temperature, (Sr+Eu)/Cu flux ratio,...
Article
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We report on ambipolar modulation doping of monolayer FeSe epitaxial films grown by molecular beam epitaxy and in-situ spectroscopic measurements via a cryogenic scanning tunneling microscopy. It was found that hole doping kills superconductivity in monolayer FeSe films on metallic Ir(001) substrate, whereas electron doping from polycrystalline IrO...
Article
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Leafhoppers have been identified as a serious threat to different plants. To explore the characteristics of mitogenomes and reveal the phylogenetic positions of two species in the Typhlocybinae, complete mitogenomes of Singapora shinshana and Seriana bacilla were sequenced and annotated for the first time with lengths of 15,402 bp and 15,383 bp, re...
Article
High fecundity is a common characteristic of insect pests which increases the difficulty of population control. Serine/threonine kinase Akt is an indispensable component of the insulin signaling pathway. Silencing of LsAkt severely hinders reproduction in Lasioderma serricorne, a stored product insect pest. However, the post-transcriptional pathway...
Article
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Understanding how applied voltage drives the electrocatalytic reaction at the nanoscale is a fundamental scientific problem, particularly in non-metallic electrocatalysts, due to their low intrinsic carrier concentration. Herein, using monolayer molybdenum disulfide (MoS2) as a model system of non-metallic catalyst, the potential drops across the b...
Article
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Although modulating oxygen vacancies in semiconductors has attracted broad interest in photocatalysis and photoelectrocatalysis, identifying the intrinsic roles of oxygen vacancies on photoelectrocatalytic properties is often elusive. Herein, we regulated the oxygen vacancies in a typical semiconductor lead chromate (PbCrO4 ) via controlling the ox...
Article
The role of formate species for CO2 hydrogenation is still under debate. Although formate has been frequently observed and commonly proposed as the possible intermediate, there is no definite evidence for the reaction of formate species for methanol production. Here, formate formation and conversion over the ZnZrOx solid solution catalyst are inves...
Article
ZnZrO/Mg-Si-ZSM-5 tandem catalysts enable CO2 hydrogenation to para-xylene (PX) with PX selectivity up to 28% and proportion of PX in xylene up to 84%. SiO2 and MgO modification increases PX...
Article
Full-text available
Bismuth‐based halide perovskite materials have attracted extensive attention for optoelectronic applications due to nontoxicity and ambient stability. However, limited by low‐dimensional structure and isolate octahedron arrangement, the undesirable photophysical properties of bismuth‐based perovskites are still not well modulated. Here, the rationa...
Article
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The interfacial barrier of charge transfer from semiconductors to cocatalysts means that the photogenerated charges cannot be fully utilized, especially for the challenging water oxidation reaction. Using cobalt cubane molecules (Co4O4) as water oxidation cocatalysts, we rationally assembled partially oxidized graphene (pGO), acting as a charge‐tra...
Article
The interfacial barrier of charge transfer from semiconductors to cocatalysts means that the photogenerated charges cannot be fully utilized, especially for the challenging water oxidation reaction. Using cobalt cubane molecules (Co 4 O 4 ) as water oxidation cocatalysts, we rationally assembled partially oxidized graphene (pGO), acting as a charge...
Article
Full-text available
In order to explore the influence of stored cereal volatiles on the behavior of Sitophilus oryzae, the olfactory responses of adult rice weevils to the volatiles of different rice cultivars [Red brown rice (RBR), Daohuaxiangmi (DHXM), Baishuigongmi (BSGM), Yashuixinmi (YSXM), and white glutinous rice (WGR)] were studied using electroantennography (...
Article
Surface plasmon resonance-induced charge separation plays key roles in plasmon-related applications, especially in photocatalysis and photovoltaics. Plasmon coupling nanostructures exhibit extraordinary behaviors in hybrid states, phonon scattering, and ultrafast plasmon dephasing, but plasmon-induced charge separation in these materials remains un...