B.K. Mukherjee

B.K. Mukherjee
Royal Military College of Canada · Department of Physics

B.Sc. Ph.D

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93
Publications
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Publications

Publications (93)
Article
Full-text available
We present a procedure for determining the reduced piezoelectric, dielectric, and elastic coefficients for a C(∞) material, including losses, from a single disk sample. Measurements have been made on a Navy III lead zirconate titanate (PZT) ceramic sample and the reduced matrix of coefficients for this material is presented. In addition, we present...
Article
Full-text available
We present a technique to measure the piezoelectric strain (charge) coefficient using an optical lever technique. The optical lever consists of a laser source, a levered mirror connected to the sample and a linear CCD array detector (pixel size = 13 μm). A field on the sample creates a displacement due to the piezoelectric effect. The displacement...
Article
This article gives a review of the research done in our lab over the past few years on the characterization of the transverse elongation of polymeric electrostatic actuators induced by Maxwell stress. Dielectric elastomers are known to produce large transverse strains in response to Maxwell stresses and thus provide a useful form of electromechanic...
Conference Paper
Full-text available
We present a procedure for determining the reduced piezoelectric, dielectric and elastic coefficients for a C<sub>∞</sub> material, including losses, from a single disk sample. Measurements have been made on a Navy III PZT (Channel 5804) ceramic sample and the reduced matrix of coefficients for this material is presented.
Article
Full-text available
The relative permittivity and dielectric loss tangent of transparent lead lanthanum zirconate titanate (PLZT) (9.5/65/35) and (9.0/65/35) ceramics were measured as a function of temperature, ranging from -60 to 100 ° C , and as a function of frequency, ranging from 0.12 to 5000 kHz. Diffuse maxima were observed in the complex permittivity plots of...
Article
The continuing need for large actuation and a continually increasing variety of applications has seen the use of piezoelectric materials under a growing range of conditions. These include large applied AC fields, DC bias fields, applied stresses as well as a wider range of frequencies and temperatures. Under these conditions the behaviour of the ma...
Article
Full-text available
Review of techniques for characterizing piezoelectric/electrostrictive material for transducer applications.
Conference Paper
Resonance characterisation has been used to determine the variation of the independent piezoelectric, elastic, and dielectric material coefficients, as well as the electromechanical coupling factors, of typical soft and hard lead zirconate titanate (PZT) ceramics as a function of temperature ranging from -165degC to 195degC. The piezoelectric coeff...
Article
Full-text available
We have used resonance methods to determine the variation of all the independent piezoelectric, elastic, and dielectric material coefficients, as well as the corresponding electromechanical coupling factors, of soft and hard doped piezoelectric lead zirconate titanate (PZT) ceramics with compositions near the morphotropic phase boundary, as a funct...
Article
Different cations doped lead-free piezoelectric (Bi1/2Na1/2)TiO3 ceramics with the general formula Na0.4995Bi0.4995Ba0.001Ti0.998M0.002O3 (M=Nb, Ta, and Sb) were fabricated. The effects of processing parameters and doping on phase content, microstructure, dielectric and piezoelectric properties of the materials were discussed. Experimental results...
Article
Full-text available
Resonance methods were used to determine the variation of several piezoelectric, elastic and dielectric constants, as well as the corresponding electromechanical coupling factors of soft and hard doped Pb(ZrxTi1-x)O3 (PZT) ceramics, with compositions near the morphotropic phase boundary (MPB), as a function of temperature ranging from -165 °C to 19...
Article
Some dielectric elastomers produce large electric-field-induced strains that can be used for electromechanical actuation. When an electric field E is applied on an electroactive polymer film electroded on both sides, the film is subjected to a stress T due to the electrostatic force (Maxwell stress) and this causes it to deform, producing a strain...
Article
Acoustic sensors and actuators often utilize piezoelectric transducers in active methods of noise and vibration control and in other smart applications. The increasing range of these applications requires the piezoelectric materials to be used under a variety of conditions that include large applied AC fields, DC bias fields, applied stresses and a...
Article
Single crystals of Pb(Zn 1/3 Nb 2/3 )O 3 -PbTiO 3 (PZN-PT) produce high levels of strains with large electromechanical coupling coefficients and they exhibit high dielectric permittivity. These properties make PZN-PT single crystals promising materials for transducer and actuator applications. The large strains in these materials are partly due to...
Article
Full-text available
Dielectric elastomers are known to produce large transverse strains in response to electrically induced Maxwell stresses and thus provide a useful form of electromechanical actuation. The transverse strain response of silicone (Dow Corning HS III RTV) based Maxwell stress actuators have been measured earlier as a function of driving electric field,...
Article
Electric-field-induced phase transitions and piezoelectric properties of <001>-oriented Pb(Mg1/3Nb2/3)O3-32%PbTiO3 (PMN-PT) single crystals have been investigated as a function of temperature. It was found that the phase transitions and piezoelectric properties for PMN-PT crystals are strongly dependent on temperature. The measurements of polarizat...
Conference Paper
The structure and dielectric properties of CaCu<sub>3</sub>Ti<sub>4</sub>O<sub>12</sub> ceramics have been investigated. The starting CaCu<sub>3</sub>Ti<sub>4</sub>O<sub>12</sub> powders were synthesized by a modified glycine nitrate process. The ceramics obtained exhibit a cubic perovskite structure. Dielectric constant up to 57,200 and dielectric...
Conference Paper
Full-text available
Some electroactive polymers show large electric-field-induced strain. However, it is difficult to characterize the transverse strain response, especially the dynamic response, under high driving electric fields. In this work, a transverse strain measurement system based on a ZYGO laser Doppler interferometer has been developed. This system can meas...
Article
Some electroactive polymers produce large electric-field-induced strains that can be used for electromechanical actuation. The measurement of the strain response, especially the dynamic response under high driving fields, is difficult. We have developed a transverse strain measurement system based on the Zygo laser Doppler interferometer. The syste...
Article
Large, high-quality single crystals of (1−x)Pb(Zn1/3Nb2/3)–xPbTiO3 [PZN–PT] relaxors (with the composition range from ∼6 to ∼10% mol. PT) have been grown with a high degree of reproducibility by the gradient cooling method in a specially designed furnace from high-temperature solution. The crystal size is limited by the crucible diameter only. A pr...
Article
Full-text available
The piezoelectric d15 coefficients of 〈111〉-oriented (1−x)Pb(Zn1/3Nb2/3)O3–xPbTiO3 single crystals for x = 0.045 and x = 0.08 (PZN-4.5%PT and PZN-8%PT) have been measured as functions of dc bias field and frequency using a Zygo laser interferometer system. High d15 values ( ∼ 5500 pC/N for PZN-4.5%PT and ∼ 7500 pC/N for PZN-8%PT) were obtained in t...
Article
Single crystals of the relaxor ferroelectric solid solution family Pb(Zn1/3Nb2/3)O3-PbTiO3 (PZN-PT) have been shown to produce very high levels of electric field induced strains with large electromechanical coupling coefficients when poled aong the direction. These materials also exhibit a high dielectric permittivity and they are therefore very pr...
Article
The nonlinear behaviors of the dielectric and piezoelectric responses of oriented Pb(Zn1/3Nb2/3)O3-xPbTiO3 (PZN-PT) single crystals for x=4.5% and 8% have been investigated as a function of ac electric fields and dc bias fields. At relatively low applied fields, the polarization and strain of PZN-PT single crystals poled along the direction show li...
Article
Full-text available
We have investigated the electromechanical response of piezoelectric ceramics as a function of the amplitude and frequency of large electric fields and studied the effects of dc bias fields. In order to characterize the materials under these conditions, a ZMI 2000 laser interferometer system from Zygo Corp. has been installed and modified to direct...
Article
Full-text available
A previously described model of hysteresis [J. C. Piquette and S. E. Forsythe, J. Acoust. Soc. Am. 106, 3317-3327 (1999); 106, 3328-3334 (1999)] is generalized to apply to a dynamical system. The original model produces theoretical hysteresis loops that agree well with laboratory measurements acquired under quasi-static conditions. The loops are pr...
Article
A simple physical picture, useful for extended applications of a well-demonstrated phenomenological polarization model [J. C. Piquette and S. E. Forsythe, J. Acoust. Soc. Am. 101, 289 (1997)] is presented. The Weiss model of interacting dipoles (orginally suggested by Weiss for magnetic dipoles but applied here to electric dipoles) is generalized f...
Article
Laser Doppler interferometry has been used to determine the strain and piezoelectric response of Pb(Mg1/3Nb2/3)O3-PbTiO3 (PMN-PT) electrostrictive ceramics as a function of electric fields up to 4 MV m-1, frequencies between 0.1 Hz and 2.5 kHz and DC bias fields up to 3 MV m-1. The strain and polarization of PMN-15 with a composition of 0.9PMN-0.1P...
Article
Electric-field-induced phase transitions and piezoelectric properties of 〈001〉-oriented Pb(Zn1/3Nb2/3)O3–xPbTiO3 single crystals for x = 4.5% and 8% (PZN–4.5%PT and PZN–8%PT) have been investigated as a function of temperature. It was found that the piezoelectric properties and phase transitions for both crystals are strongly dependent on temperatu...
Article
Various piezoelectric, elastic and dielectric constants of typical soft and hard lead zirconate titanate (PZT) ceramics have been determined as a function of applied AC field, DC bias field, pre-stress, temperature and frequency. Our results show significant non-linear effects and many of the effects are caused by extrinsic, or domain related effec...
Article
The piezoelectric d coefficients of 〈111〉 oriented (1-x)Pb(Zn1/3Nb2/3)O3-xPbTiO3 single crystals for x = 0.045 and x = 0.08 (PZN-4.5%PT and PZN-8%PT) have been measured as functions of DC bias field and frequency using a Zygo laser interferometer system. The d coefficients decreased as the DC bias was increased, perhaps because of domain wall clamp...
Conference Paper
The temperature dependence of dielectric properties and phase transitions of <001> oriented (1-x)Pb(Zn<sub>1</sub>3/Nb<sub>2</sub>3/)O<sub>3</sub>-xPbTiO<sub>3</sub> (PZN-PT) single crystals for x = 4.5% and x = 8% have been investigated as a function of DC bias field. These crystals exhibit frequency dispersion and increasing the PT content in die...
Conference Paper
Full-text available
The piezoelectric d coefficients of <111> oriented (1-x)Pb(Zn<sub>1</sub>3/Nb<sub>2</sub>3/)O<sub>3</sub>-xPbTiO<sub>3</sub> single crystals for x = 0.045 and x = 0.08 (PZN-4.5%PT and PZN-8%PT) have been measured as functions of DC bias field and frequency using a Zygo laser interferometer system. The d coefficients decreased as the DC bias was inc...
Article
The problem of determining the drive waveform that produces a desired output from a hysteretic, saturating material is considered both theoretically and experimentally. The specific problem of interest is the production of a high-amplitude, but monofrequency, sinusoidal polarization response. (The techniques presented could also be used to control...
Article
Sensors and actuators based on piezoelectric ceramics are finding an increasingly large variety of applications under a very wide range of environmental conditions and applied signals. Some actuator applications require the piezoelectric materials to support large mechanical loads and produce high strain output. In order to accomplish this requirem...
Conference Paper
The temperature and electric field dependence of the piezoelectric properties and phase transitions of 〈001〉 oriented Pb(Zn<sub>1/3</sub>Nb<sub>2/3</sub>)O<sub>3</sub>-xPbTiO<sub>3</sub> single crystals for x = 4.5% and 8% have been investigated. Both piezoelectric properties and phase transitions are strongly dependent on temperature and electric...
Article
Full-text available
Piezoelectric ceramics are often used under compressive stress. It is therefore important to know the properties of these materials as a function of applied stress. We have developed an experiment that allows us to find the piezoelectric charge coefficient d33, elastic compliance S 33, and dielectric constant ϵ 33 as a function of uniaxial stress i...
Article
Full-text available
The temperature dependence of the material properties of PMN-PT-La (0.85/0.15/1%) electrostrictive ceramics manufactured by TRS Ceramics Inc. have been investigated. The measurements reported here include: the temperature and frequency dependence of dielectric permittivity and dissipation, the quasi-static strain as a function of applied electric f...
Article
A laser Doppler interferometer system has been used to measure the strains of ferroelectric ceramics. The strains and polarisation of piezoelectric and electrostrictive ceramics have been investigated as a function of electric fields up to 4 MV/m in the frequency range from 0.01 Hz up to 1 kHz. The field and frequency dependence of the appropriate...
Conference Paper
We have measured some of the dielectric, elastic, and piezoelectric constants of several types of PZT piezoelectric ceramics, manufactured by EDO Corporation, as a function of applied electric field and mechanical stress. Both the high frequency impedance resonance method and the low frequency response of the material under electrical and mechanica...
Conference Paper
Full-text available
A Zygo laser interferometer system has been used to measure the strain induced in piezoelectric lead zirconate titanate (PZT) and electrostrictive lead magnesium niobate (PMN) based ceramics. The piezoelectric coefficients d<sub>33</sub>, d<sub>31</sub> and d<sub>15 </sub> of PZT ceramics have been determined as a function of electric field and fre...
Conference Paper
Full-text available
Piezoelectric ceramics are often used under compressive stress. We have measured the dynamic value of the piezoelectric charge coefficient, d<sub>33</sub>, as a function of uniaxial stress in the poled direction. Results on two types of PZT ceramics manufactured by EDO Corporation are presented; in general, they show a nonlinear behaviour with an i...
Article
Large scale actuated structures often require piezoelectric elements in the thickness range 10-50μm. For manufacturing purposes, the chemical solution deposition of sol gel composites can create such structures using methods compatible with semiconductor fabrication technology. The piezoelectric characteristics of structures fabricated by patternin...
Article
Complex material constants are now being used to accurately model the dynamic response of piezoelectric materials. A simple physical model of piezoelectric materials will be used to show how complex material constants can be conveniently used to characterize losses in the dielectric, elastic, and piezoelectric response of piezoelectric materials. T...
Article
An experiment has been developed to measure the piezoelectric d coefficient as a function of uniaxial stress on a piezoelectric or electrostrictive ceramic material. Measurements on piezoelectric ceramic specimens show that there is a very significant enhancement in the value of the piezoelectric coefficient as a function of applied stress with the...
Article
Full-text available
Smart structures based on piezoelectric materials are now finding applications in a wide variety of environmental conditions. We have used the impedance resonance technique to measure the impedance spectra of lead zirconate titanate ceramic specimens over temperatures ranging between 0ºC and 100ºC. The analysis of the radial, thickness, thickness s...
Article
Full-text available
We present an analytical expression of the electromechanical coupling constant of a piezoelectric bimorph. A simplified impedance equation is presented that allows for the determination of the electromechanical coupling, flexural rigidity, and free permittivity of the bimorph.
Article
Full-text available
We have measured the electromechanical properties of the “reversible” electrostrictive ceramic (TRS Ceramics Inc) PMN/PT/La (0.9/0.1/1%) at room temperature, which is slightly above Tmax, the temperature at which the real part of the material's low frequency permittivity has a maximum. Under DC bias fields up to about 0.5 MV/m, the material behaves...
Article
Full-text available
We present a non-linear theory for electromechanical materials based on a Taylor's series expansion of the thermodynamic potentials to 3rd and higher order terms in field and stress, and we show that this general theory is applicable to both piezoelectric and ideal electrostrictive materials depending with an appropriate choice of material coeffici...
Article
Full-text available
Electrostrictive materials, such as the ceramic PMN/PT/La, operating above Tmax with a DC bias field behave as a piezoelectric ceramic materials with CINF symmetry. The effective piezoelectric and electromechanical coupling coefficients are found to be linear as a function of the DC bias field up to about 0.5MV/m, while the elastic constant and the...
Article
Full-text available
We describe an experiment in which a ramped or step stress can be applied to a piezoelectric sample and the charge generated on the sample can be determined by measuring the short-circuit current with a very high impedance electrometer. The low frequency direct piezoelectric charge coefficient, d33, can then be determined and is found to be substan...
Article
Full-text available
A set of thickness resonators of PVDF-TrFE copolymer have been characterized as a function of the frequency and DC bias. The first six resonance peaks in the impedance spectra were analyzed to determine the degree of frequency dispersion in the complex elastic, piezoelectric, and dielectric constants. Modeling the dispersion in the material constan...
Conference Paper
Full-text available
This paper discusses the use of complex material constants to model the response of piezoelectric materials to alternating fields. The various material constants needed to describe the behavior of piezoelectric materials in transducers are introduced. The reasons for using complex coefficients to characterize the frequency dependent dielectric, ela...
Conference Paper
Full-text available
Quantitative validation is critical to the effective utilization of large-scale modeling in advanced biomedical ultrasonic imaging applications. This work describes an incremental “model-build-test” validation exercise centered around a nonproprietary, 5 MHz, 1D linear array design. The step-by-step sequence reported here includes piezoceramic sliv...
Conference Paper
Full-text available
The design, construction, performance, and comparison to FEM simulation of a broadband 375 kHz, 100 element, composite based, 115 mm radius curved receive array is described. This array was designed for use in a forward-looking, mine-hunting application with 60, 1.5° beams scanning a 900 sector. A 150° sector can be scanned with beamwidths widening...
Conference Paper
Full-text available
Equivalent circuit models for unloaded piezoelectric vibrators are presented. The new circuit model includes terms which take into account the dielectric and piezoelectric loss as well as the mechanical loss found in the standard Van Dyke's model. The new model contains two branches, the motional branch and the static branch, like the Van Dyke's mo...
Article
Full-text available
The results of our analysis of a set of lead zirconate titanate (PZT-5H)/hard polyurethane 1 - 3 piezoelectric composites produced by injection molding are presented. Two groups of samples with 15 and 30 volume percent PZT were analyzed using impedance resonance techniques. Results from the thickness, radial, length thickness, thickness shear, and...
Article
Full-text available
This paper reports on our determination of the small signal properties of Motorola 3203 HD, including the effects of losses and dispersion, and it shows the limitations imposed by assuming that the material is loss-less. A set of PZT 3203 HD unloaded resonators manufactured by Motorola was cut to specifications outlined in the IEEE Standard on Piez...
Article
Full-text available
An alternative method to determine the electromechanical coupling constant k13 for the length-thickness piezoelectric resonator is presented. Data relating the electromechanical coupling constant k13 to the parallel resonance frequency ratios are tabulated. A third order polynomial was found to represent the relationship accurately for k13 = 0.01 t...
Article
Full-text available
The design of ferroelectric/piezoelectric smart structures is limited by the accuracy to which the material properties of the sensor/actuator materials are determined. In particular, it is important to understand the effects of losses, dispersion, and the non-linearities that become significant when large fields are applied. This paper presents the...
Conference Paper
Full-text available
A set of thickness resonators of PVDF-TrFE copolymer have been characterized as a function of the frequency and DC bias. The first six resonance peaks in the impedance spectra were analyzed to determine the degree of frequency dispersion in the complex elastic, piezoelectric, and dielectric constants. Modeling the dispersion in the material constan...
Article
Full-text available
We have compared the measured effective dielectric, piezoelectric and hydrostatic properties of 0.500 mm thick P(VDF-TrFE) copolymer with flexible electrodes manufactured by AMP Sensors Inc. with similar properties of three different thicknesses of the same polymer with stiff electrodes manufactured by the same company. The presence of the stiff el...
Article
A plasma-spray process was used to produce piezoelectric lead zirconate titanate (PZT)-glass composite thick films. The films were found to have the same crystal structure as the PZT (Navy-type V) and lead-based glass starting powder mixture. The films showed good adhesion to stainless steel and silver-coated glass slides and poor adhesion to alumi...
Article
Full-text available
The recent past has seen the introduction of many new types of piezoelectric materials with relatively high dissipation and low mechanical Q (PVDF, ceramic?polymer composites). In order for designers to predict the performance of these materials in transducers, the imaginary components of the dielectric,elastic, and piezoelectric constants need to...
Article
Full-text available
We describe a new method for determining the real and imaginary parts of the material constants of piezoelectric resonators. Our method is applicable to any of the common resonator geometries, it is non-iterative and its accuracy is comparable to that of other methods which are currently in use.
Article
Full-text available
Piezoelectric 0–3 ceramic-glass composites have been developed by firing a mixture of modified Lead Zirconate Titanate (PZT) and a lead based glass powder. Composites with 58 to 92 volume percent PZT were fabricated and their dielectric, piezoelectric and hydrostatic properties have been determined. The hydrostatic properties were pressure independ...
Article
Full-text available
We describe a new piezoelectric hydrophone material, a 1-3 type Lead Zirconate Titanate (PZT)-Air composite, which is constructed in such a way that the PZT rods are isolated from stresses in the 1 and 2 directions. The theory for these new composites predicts a hydrophone figure of merit that is substantially greater than that of PZT. Measurements...
Article
Full-text available
The usual methods for determining the electromechanical coupling constants of piezoelectric materials are described in the IEEE standard on piezoelectricity (IEEE Standard on Piezoelectricity 176-1987). When spurious resonances are present, the standard recommends the use of a method that involves the use of a numerical table of corresponding value...
Conference Paper
Full-text available
Chemical coprecipitation and gel processing techniques have been used to synthesize precursor powders of a modified lead titanate composition. The effects of powder processing parameters and sintering conditions on the microstructure and dielectric, piezoelectric, and pyroelectric properties of the products are discussed. Powders and products produ...