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An extended Peng-Robinson equation of state (EPR-EOS) is used to model the vapor-liquid equilibrium (VLE) in systems containing (water + NaCl + CO 2), (water + methanol + NaCl + CO2), (water + Na 2S04 + CO2) and (water + NH4Cl + CO2). The binary and ternary interaction parameters between salt and solvent are adjusted to experimental mean solvent ac...