Bartlomiej Graczykowski

Adam Mickiewicz University | UAM

The hypersonic phonon propagation in large-area two-dimensional colloidal crystals is probed by spontaneous micro Brillouin light scattering. The dispersion relation of thermally populated Lamb waves reveals multi-band filtering due to three distinct types of acoustic band gaps. We find Bragg gaps accompanied by two types of hybridization gaps in b...

Colloidal crystals realized by self-assembled polymer nanoparticles have prominent attraction as a platform for various applications from assembling photonic and phononic crystals, acoustic metamaterials to coating applications. However, the fragility of these systems limits their application horizon. In this work the uniform mechanical reinforceme...

A thermal rectifier/diode is a nonreciprocal element or system that enables preferential heat transport in one direction. In this work we demonstrate a single-material thermal diode operating at high temperatures. The diode is made of nanostructured silicon membranes exhibiting spatially and temperature-dependent thermal conductivity and, therefore...

Telecommunication devices exploit hypersonic gigahertz acoustic phonons to mediate signal processing with microwave radiation, and charge carriers to operate various microelectronic components. Potential interactions of hypersound with charge carriers can be revealed through frequency- and momentum-resolved studies of acoustic phonons in photoexcit...

Brillouin light scattering and elastodynamic theory are concurrently used to determine and interpret the hypersonic phonon dispersion relations in brush particle solids as a function of the grafting density with perspectives in optomechanics, heat management, and materials metrology. In the limit of sparse grafting density, the phonon dispersion re...

Aggregation of the polydopamine (PDA) molecular building blocks at the air/water interface leads to obtaining large surface nanometric-thin films. This mechanism follows two possible pathways, namely, covalent or non-covalent self-assembly, which result in a different degree of structure order and, consequently, different structural properties. Con...

Silk fibroin is an important biomaterial for photonic devices in wearable systems. The functionality of such devices is inherently influenced by the stimulation from elastic deformations, which are mutually coupled through photo-elasticity. Here, we investigate the photo-elasticity of silk fibroin employing optical whispering gallery mode resonatio...

Observation of Fano resonances in various physical phenomena is usually ascribed to the coupling of discrete states with background continuum, as it has already been reported for various physical phenomena. Here, we report on Fano lineshapes of nonthermal GHz phonons generated and observed with pumped Brillouin light scattering in gold-silicon thin...

Plasmonic coupling between adjacent metallic nanoparticles can be exploited for acousto-plasmonics, single-molecule sensing, and photochemistry. Light absorption or electron probes can be used to study plasmons and their interactions, but their use is challenging for disordered systems and colloids dispersed in insulating matrices. Here, we investi...

Hypothesis Polymer particles self-assembled into colloidal crystals have exciting applications in photonics, phononics, templates for nanolithography, and coatings. Cold soldering utilizing polymer plasticization by supercritical fluids enables a novel, low-cost, low-effort, chemical-free means for uniform mechanical strengthening of fragile polyme...

Silk fibroin is an important biomaterial for photonic devices in wearable systems. The functionality of such devices is inherently influenced by the stimulation from elastic deformations, which are mutually coupled through photo-elasticity. Here, we investigate the photo-elasticity of silk fibroin employing optical whispering gallery mode resonatio...

Liquid crystal elastomers that offer exceptional load-deformation response at low frequencies often require consideration of the mechanical anisotropy only along the two symmetry directions. However, emerging applications operating at high frequencies require all five true elastic constants. Here, we utilize Brillouin light spectroscopy to obtain t...

How phonons propagate in nanostructures determines the flow of elastic and thermal energy in dielectric materials. However, a reliable theoretical prediction of the phonon dispersion relation requires experimental verification both near to and far from the Brillouin zone of the nanostructure. We report on the experimental hypersonic phonon dispersi...

Transport of heat and hypersound with gigahertz (GHz) to terahertz (THz) phonons is crucial for heat management in electronics, mediating signal processing with microwave radiation, thermoelectrics, and various types of sensors based on nanomechanical resonators. Efficient control of heat and sound transport requires new materials, novel experiment...

The actuation of micro- and nanostructures controlled by external stimuli remains one of the exciting challenges in nanotechnology due to the wealth of fundamental questions and potential applications in energy harvesting, robotics, sensing, biomedicine, and tunable metamaterials. Photoactuation utilizes the conversion of light into motion through...

Free-standing and flexible field-effect transistors based on 6,13-bis(triisopropylsilylethynyl)-pentacene (TIPS-pentacene)/polystyrene bilayers are obtained by well-controlled phase separation of both components. The phase separation is induced by solvent vapor annealing of initially amorphous blend films, leading to crystallization of TIPS-pentace...

Irreversible adsorption at polymer/substrate interfaces has been reported to influence glassy properties in thin films. However, consideration has yet to be extended to the nanocomposite geometry, wherein a large interfacial area and high processing temperatures afford especially favorable conditions for irreversible adsorption at the polymer/nanop...

Colloidal supraparticles are micron-scale spherical assemblies of uniform primary particles, which exhibit emergent properties of a colloidal crystal, yet exist as a dispersible powder. A prerequisite to utilize these emergent functionalities is that the supraparticles maintain their mechanical integrity upon the mechanical impacts that are likely...

Transition metal carbides have gathered increasing attention in energy and electrochemistry applications, mainly due to their high structural and physicochemical properties. Their high refractory properties have made them an ideal candidate coating technology and more recently their electronic similarity to the platinum group has expanded their use...

Monolayer graphene is stronger than bulk graphite: the elastic properties of graphene are such that it could hypothetically withstand an elephant balancing on a pencil. A contactless optical technique, reported by Bartlomiej Graczykowski and co-workers in article number 2008614 now shows that this is not the case for MoSe2, an attractive semiconduc...

Few‐layer van der Waals (vdW) materials have been extensively investigated in terms of their exceptional electronic, optoelectronic, optical, and thermal properties. Simultaneously, a complete evaluation of their mechanical properties remains an undeniable challenge due to the small lateral sizes of samples and the limitations of experimental tools...

Phononic crystals (PnCs) control the transport of sound and heat similar to the control of electric currents by semiconductors and metals or light by photonic crystals. Basic and applied research on PnCs spans the entire phononic spectrum, from seismic waves and audible sound to gigahertz phononics for telecommunications and thermal transport in th...

Optomechanical crystal cavities (OMC) have rich perspectives for detecting and indirectly analysing biological particles, such as proteins, bacteria and viruses. In this work we demonstrate the working principle of OMCs operating under ambient conditions as a sensor of submicrometer particles by optically monitoring the frequency shift of thermally...

Optomechanical crystal cavities have rich perspectives for detecting and indirectly analysing biological particles, such as proteins, bacteria and viruses. In this work we demonstrate the working principle of an optomechanical crystal cavity operating under ambient conditions as a sensor of submicrometer analytes by optically monitoring the frequen...

Cellular membranes have long served as an inspiration for nanomaterial research. The preparation of ultrathin polydopamine (PDA) films with integrated protein pores containing phospholipids and an embedded domain of a membrane protein glycophorin A as simplified cell membrane mimics is reported. Large area, ultrathin PDA films are obtained by elect...

The central concept in phononics is the tuning of the phonon dispersion relation, or phonon engineering, which provides a means of controlling related properties such as group velocity or phonon interactions and, therefore, phonon propagation, in a wide range of frequencies depending on the geometries and sizes of the materials. Phononics exploits...

Despite the growing application of nanostructured polymeric materials, there still remains a large gap in our understanding of polymer mechanics and thermal stability under confinement and near polymer–polymer interfaces. In particular, the knowledge of polymer nanoparticle thermal stability and mechanics is of great importance for their applicatio...

We present the spontaneous Brillouin light scattering (BLS) under simultaneous one-dimensional confinement of sound and light and show that the photon-phonon coupling results from nontrivial interplay of the photoelastic and moving-interface effects. We reveal two types of BLS self-canceling: governed by mode symmetry and driven by destructive inte...

In this work we study the effects of disorder on the thermal conductivity of porous 100 nm thick silicon membranes, in which the size, shape and position of the pores were varied randomly. Measurements using two-laser Raman thermometry on both non-patterned and porous membranes revealed more than a 10-fold reduction of the thermal conductivity comp...

Metal-polymer nanocomposites are hybrid materials combining the superior plasmonic, electrical, and thermal properties of metals with the good elasticity and manufacturability of polymers. This renders metal-polymer nanocomposites promising candidates for conductive filler and coating applications, where mechanical properties are optothermally coup...

Polymers with nanoparticle inclusions are attractive materials because physical properties can be tuned by varying size and volume fraction range. However, elastic behavior can degrade at higher inclusion fractions when particle-particle contacts become important, and sophisticated measurement techniques are required to study this crossover. Here,...

Advances in nanoparticle synthesis, self-assembly, and surface coating or patterning have enabled a diverse array of applications ranging from photonic and phononic crystal fabrication to drug delivery vehicles. One of the key obstacles restricting its potential is structural and thermal stability. The presence of a glass transition can facilitate...

We report measurements and Monte Carlo simulations of thermal conductivity of porous 100nm- thick silicon membranes, in which size, shape and position of the pores were varied randomly. Measurements using 2-laser Raman thermometry on both plain membrane and porous membranes revealed more than 10-fold reduction of thermal conductivity compared to bu...

Measuring polymer surface dynamics remains a formidable challenge of critical importance to applications ranging from pressure-sensitive adhesives to nanopatterning, where interfacial mobility is key to performance. Here, we introduce a methodology of Brillouin light spectroscopy to reveal polymer surface mobility via nanoparticle vibrations. By me...

The performance gain oriented nano-structurisation has opened a new pathway for tuning mechanical features of solid matter vital for application and maintained performance. Simultaneously, the mechanical evaluation has been pushed down to dimensions way below one micrometre. To date, the most standard technique to study the mechanical properties of...

Heat conduction in silicon can be effectively engineered by means of sub-micrometre porous thin free-standing membranes. Tunable thermal properties make these structures good candidates for integrated heat management units such as waste heat recovery, rectification or efficient heat dissipation. However, possible applications require detailed therm...

We report a record low thermal conductivity in polycrystalline MoS2 obtained by varying grain sizes and orientations in ultrathin films. By optimizing the sulphurisation parameters of nanometre-thick Mo layer, we could grow MoS2 films with tuneable morphologies. The thermal conductivity is extracted from a Raman laser power-dependent study on suspe...

Determination of the mechanical properties of nanostructured soft materials and their composites in a quantitative manner is of great importance to improve the fidelity in their fabrication and to enable the subsequent reliable utility. Here, we report on the characterization of the elastic and photoelastic parameters of a periodic array of nanowal...

We report thermal conductivity measurements on 5 nm thick polycrystalline MoS2 by means of 2-laser Raman thermometry. The free-standing, drum-like MoS2 nanomembranes were fabricated using a novel polymer-and residue-free, surface-tension-assisted wet transfer, in which we took advantage of the hydrophobic properties of MoS2 to transfer the CVD-grow...

We report on nanoscale pillar-based hypersonic phononic crystals in single crystal Z-cut lithium niobate. The phononic crystal is formed by a two-dimensional periodic array of nearly cylindrical nanopillars 240 nm in diameter and 225 nm in height, arranged in a triangular lattice with a 300-nm lattice constant. The nanopillars are fabricated by the...

The design and fabrication of phononic crystals (PnCs) hold the key to control the propagation of heat and sound at the nanoscale. However, there is a lack of experimental studies addressing the impact of order/disorder on the phononic properties of PnCs. Here, we present a comparative investigation of the influence of disorder on the hypersonic an...

We report a technique for transferring large areas of the CVD-grown, few-layer MoS2 from the original substrate to another arbitrary substrate and onto holey substrates, in order to obtain free-standing structures. The method consists of a polymer- and residue-free, surface-tension-assisted wet transfer, in which we take advantage of the hydrophobi...

This chapter reviews phonon research in ultrathin free-standing silicon membranes made of silicon-on-insulator (SOI) wafers. The membranes are stress-free and some are intentionally stressed. Their fabrication is described in both cases. Calculations and experimental work on confined acoustic phonons, dispersion relations, phonon lifetimes, and tra...

Understanding and controlling vibrations in condensed matter is emerging as an essential ne-cessity both at fundamental level and for the development of a broad variety of technological applications.Intelligent design of the band structure and transport properties of phonons at the nanoscale and of theirinteractions with electrons and photons impac...

In this paper, we report a theoretical investigation of surface acoustic waves propagating in one-dimensional phononic crystal. Using finite element method eigenfrequency and frequency response studies, we develop two model geometries suitable to distinguish true and pseudo (or leaky) surface acoustic waves and determine their propagation through f...

Free-standing Si films have been and remain an excellent example to study experimentally the effect of the reduction of the characteristic size on the phonon dispersion relation. A step further in geometrical complexity and, therefore, in increasing the control and manipulation of phonons is achieved by introducing periodicity in the medium to form...

Present silicon technology provides single crystal films and membranes with thicknesses on the order of 10 nm and below. Along the years, the thermal studies on such structures have shown a reduction of the thermal conductivity consistent with the decrease of the characteristic size. Although the lowering of thermal conductivity is detrimental for...

Nanofibrillated cellulose, a polymer that can be obtained from one of the most abundant biopolymers in Nature, is being increasingly explored due to its outstanding properties for packaging and device applications. Still, open challenges in engineering its intrinsic properties remain to address. The results obtained show the precise determination o...

A detailed understanding of the connections of fabrication and processing to structural and thermal properties of low-dimensional nanostructures is essential to design materials and devices for phononics, nanoscale thermal management and thermoelectric applications. Silicon provides an ideal platform to study the relations between structure and hea...

We investigate experimentally and theoretically the acoustic phonon propagation in two-dimensional phononic crystal membranes. Solid-air and solid-solid phononic crystals were made of square lattices of holes and Au pillars in and on 250 nm thick single crystalline Si membrane, respectively. The hypersonic phonon dispersion was investigated using B...

We report on stress induced changes in the dispersion relations of acoustic phonons propagating in 27 nm thick single crystalline Si membranes. The static tensile stress (up to 0.3 GPa) acting on the Si membranes was achieved using an additional strain compensating silicon nitride frame. Dispersion relations of thermally activated hypersonic phonon...

Hypersonic, thermally activated surface acoustic waves propagating in the surface of crystalline silicon patterned with periodic stripes were studied by Brillouin light scattering. Two characteristic directions (normal and parallel to the stripes) of surface acoustic waves propagation were examined exhibiting a distinctive propagation behavior. The...

We report on the reduction of the thermal conductivity in ultra-thin suspended Si membranes with high crystalline quality. A series of membranes with thicknesses ranging from 9 nm to 1.5 μm was investigated using Raman thermometry, a novel contactless technique for thermal conductivity determination. A systematic decrease in the thermal conductivit...

We present a novel high resolution contactless technique for thermal conductivity determination and thermal field mapping based on creating a thermal distribution of phonons using a heating laser, while a second laser probes the local temperature through the spectral position of a Raman active mode. The spatial resolution can be as small as $300$ n...

The paper presents the influence of the martensitic phase transition on hypersonic thermally excited surface acoustic waves propagating in Cu–14%Al–4%Ni (wt%) shape memory alloy. Non-destructive and non-contact testing using Brillouin light scattering spectroscopy permitted determination of the elastic constants of austenite versus temperature. Exp...

This paper presents the problem of Rayleigh surface waves which scatter over single surface inhomogeneities in the form of rectangular steps (downward or upward) or grooves. The reflection, transmission, and losses coefficients are calculated by means of the finite element method for waves propagating in isotopic silicon surface. The criterion of m...

We present experimental and theoretical evidence of a phononic band gap in a hypersonic range for thermally activated surface acoustic waves in two-dimensional (2D) phononic crystals. Surface Brillouin light scattering experiments were performed on the (001) surface of silicon, loaded with a 2D square lattice of 100- or 150-nm-high aluminum pillars...

Surface Brillouin spectroscopy was applied to characterise the dynamics of surface acoustic waves in a silicon-based nanocomposite. The propagation velocities of Rayleigh phonons and their anisotropy in silicon support (1 1 1) loaded with a nanosized nickel island structure were determined. Deposition of a 2D nickel nanostructure on silicon substra...