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Publications (3)
We report the synthesis, crystal structure, and characterisation of the dinuclear Co(II) compound with thiodiacetate (tda) and phenantroline (phen) as ligands (1), and of a series of metal complexes isomorphous...
We report magnetic, EPR, and computational studies on two representative examples of structurally well‐characterized one dimension (1D) molecular systems: the copper complexes catena‐[bis(μ‐pyridine‐2‐carboxylato)‐copper dihydrate] and catena‐[(μ2‐pyridine‐2,6‐dicarboxylato)‐diaqua‐copper(II)], hereafter 1 and 2, respectively. Experimental and theo...
Co(II) and Cu(II) ions are two paramagnetic transition metal ions showing different relaxation rates (ν), with νCo(II) >> νCu(II). To measure the isotropic exchange constant (J) between high spin Co(II) ions and between Cu(II) and high spin Co(II) ions, we performed magnetic and EPR measurements complemented with computational calculations on pure...