Andrew Turner

Andrew Turner
University of Plymouth | UoP · Marine Institute

About

262
Publications
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Introduction
Elemental characterisation of microplastics; Impacts of polystyrene debris; Particle-water interactions of emerging contaminants; Hazardous metals in plastics; XRF spectrometry

Publications

Publications (262)
Article
Dust storms are important vehicles for the erosion and translocation of geogenic material in arid and semi-arid climates but little is known about their role in transporting microplastics (MPs). In this study, local soils (n = 20) and dusts deposited from a storm (n = 41) have been sampled from a remote region of northeastern Iran (Sarakhs) and the...
Article
Full-text available
Highlights Microplastics (MPs) and microrubbers (MRs) determined in lichens and mosses around Shiraz. In lichens, MPs mainly thin fibres up to 1 MP g⁻¹; MRs were < 0.1 MP g⁻¹. In mosses, abundances were similar but with a greater fraction of larger, non-fibrous particles. Larger MPs and MRs decreased in abundance with distance and elevation from Sh...
Article
Full-text available
Metals may be associated with plastics as additives arising from manufacture or through acquisition from the environment, but these associations are often poorly defined or referred to synonymously when considering metal availability. In this study, samples of plastic litter (n = 22) have been collected from various environmental and industrial com...
Preprint
Full-text available
Surgical masks have played a crucial role in healthcare facilities to protect against respiratory and infectious diseases, particularly during the COVID-19 pandemic. However, the synthetic fibers, mainly made of polypropylene, used in their production may adversely affect the environment and human health. Recent studies have confirmed the presence...
Article
Microalgae play a critical role in the food web and biogeochemical cycling and produce compounds that are commercially exploited. However, their reactions and responses to microplastic contamination are not well understood. In this study, the widely distributed and commercially important cyanobacterium, Spirulina (Arthrospira platensis), was expose...
Article
Full-text available
Tritium (3H) is a radioactive isotope of hydrogen that is abundantly released from the nuclear industries. It is extremely mobile in the environment and in all biological systems, representing an increasing concern for the health of both humans and non-human biota (NHB). The present review examines the sources and characteristics of tritium in the...
Article
Soils are an important source of microplastics (MPs) to the atmosphere but the fluxes and mechanisms involved in MPs entrainment are not well understood. In the present study, a series of horizontally aligned sediment traps have been deployed at different heights within 1 m above the ground and for a two-month period at various locations in an arid...
Article
Although airborne urban particles are a concern for air quality and human health, little information exists on the levels and characteristics of microplastics (MPs) and microrubbers (MRs) in this setting. In the present study, MPs and MRs are quantified and characterised in road dusts and accumulations captured passively (and up to elevations of 17...
Article
X-ray fluorescence (XRF) spectrometry has been used to measure lead (Pb) in painted surfaces and indoor dusts from 14 rented properties in the city of Plymouth, UK. Lead was detected in 78 out of 164 surfaces measured (and in 69 out of 150 interior surfaces) with an overall median concentration of 7100 mg kg⁻¹ (range from 157 to 139,000 mg kg⁻¹), a...
Article
Full-text available
Abandoned boats represent a pervasive and growing problem in the coastal zone that has received little regulatory or scientific attention. In this study, we show how Google Earth can be employed to remotely identify abandoned boats and provide information on their size, age and condition. Based on specified criteria for abandonment, a survey of sou...
Article
Metals commonly employed in boat paint (Ba, Cr, Cu, Pb, Sn and Zn) have been determined in 63-μm-fractionated intertidal sediments and in Ulva lactuca and Fucus vesiculosus sampled in the vicinity of abandoned vessels. Metal concentrations in sediment were elevated but highly variable, both between sites and amongst replicates from the same site (e...
Article
Although potentially hazardous chemical elements (e.g., Cu, Cr, Pb, Sb, Ti, Zn) have been studied in clothing textiles, their presence in cleaning textiles is unknown. In this study, 48 cleaning cloth products (consisting of 81 individual samples) purchased in Europe, and consisting of synthetic (petroleum-based), semi-synthetic or natural fibres o...
Article
During the decommissioning and removal of radioactive material in nuclear facilities, fine, tritiated dusts of stainless steel, cement or tungsten are generated that could be accidentally released to the environment. However, the potential radio- and ecotoxicological effects these tritiated particles may have are unknown. In this study, stainless s...
Article
Despite the significance of groundwater to the hydrological cycle and as a source of potable water, very little information exists on microplastics (MPs) in this environment. In the present study, MPs have been determined in ten well samples obtained from an alluvial aquifer in a semi-arid region (Shiraz, Iran) following filtration, digestion and i...
Article
Despite the importance and prevalence of agricultural soils, little is known about the fate of microplastics (MPs) in this environment. In this study, MPs have been determined in soils and wind-eroded sediments from two vegetable-growing fields in the Fars province of Iran, one using plastic mulch for water retention (Field 1) and the other using w...
Article
Airborne particulate matter (PM) with an aerodynamic size cutoff of 10 µm (PM10) has been collected using a high volume air sampler at two locations (urban and residential) in the city of Ahvaz, Iran, for sixteen 24-hour periods over four months (late summer to early winter). Microplastics (MPs) in the PM were isolated after sample digestion and we...
Article
Hypersaline lakes support unique ecosystems and biogeochemistries but are often subject to anthropogenic pressures from pollution, water abstraction-diversion and climate change. Less understood, however, are the inputs, distributions and impacts of microplastics (MPs) in hypersaline environments. In this study, MPs are determined in water and sedi...
Article
Full-text available
Brominated flame retardants (BFRs) are an important group of additives in plastics that increase resistance to ignition and slow down the rate of burning. Because of concerns about the environment and human health, however, some of the most widely employed BFRs, including hexabromocyclododecane (HBCD) and commercial mixtures of penta-, octa- and de...
Article
Samples of fresh snow (n = 34) have been collected from 29 locations in various urban and remote regions of northern Iran following a period of sustained snowfall and the thawed contents examined for microplastics (MPs) according to established techniques. MP concentrations ranged from undetected to 86 MP L⁻¹ (mean and median concentrations ~20 MP...
Preprint
Full-text available
Abandoned boats represent a pervasive and growing problem in the coastal zone that have received little regulatory or scientific attention. In this study, we show how Google Earth TM can be employed to remotely identify abandoned boats and provide information on their size, age and condition. Based on specified criteria for abandonment, a survey of...
Article
Plastic food packaging and containers (n = 263) have been retrieved from the scarped foredunes at Perran Beach, SW England, following a storm surge. Samples displayed evidence of cracking, scratching, discolouration, staining and hydroxyl and carbonyl stretching, but legible text indicating their origin, dates of manufacture/expiration, packaging c...
Article
Polypropylene (PP) inkjet cartridges spilled during January 2014 in the northwest Atlantic Ocean from a container ship and subsequently retrieved from beaches around Europe and the Azores along with a matching reference cartridge that had not been exposed to the environment were physically and chemically characterized. Compared with the reference,...
Article
Dust storms are common events in arid and semi-arid regions that have a wide range of impacts on the environment and human health. This study addresses the presence, characteristics and potential sources of microplastics (MPs) in such events by analysing MPs deposited with dust particles in the metropolis of Shiraz, southwest Iran, following an int...
Article
Full-text available
Historically, many additives and catalysts used in plastics were based on compounds of toxic metals (and metalloids), like arsenic, cadmium, chromium(VI), and lead. Despite subsequent restrictions, hazardous additives remain in plastics in societal circulation because of the pervasiveness of many products and the more general contamination of recyc...
Article
Full-text available
Plastics (n = 3880) have been sampled from 39 beaches of ten Swiss lakes of varying sizes, hydrodynamics, and catchments, with a selection (n = 598) analysed for potentially hazardous (and regulated) chemical elements (As, Ba, Br, Cd, Cr, Hg, Pb, Sb, Se) by X-ray fluorescence spectrometry. Plastic objects and fragments with identifiable or unidenti...
Article
Microplastics (MPs) are a pervasive and ubiquitous environmental contaminant. However, very little information exists on the quantities or characteristics of MPs in the indoor setting. In the present study, MPs have been isolated from settled classroom dust samples collected from 50 schools in the city of Shiraz, Iran. Concentrations of MPs on a nu...
Article
Microplastics (MPs) are ubiquitous and pervasive contaminants whose impacts on human health are unclear but are gaining interest in the scientific literature. Human exposure to MPs may arise through inhalation and ingestion, with research into the latter route focusing on foodstuffs and beverages contaminated from the environment or during processi...
Article
Non-fibrous microplastics sampled by the Continuous Plankton Recorder (CPR) Survey throughout the North Atlantic Ocean during 2018 have been recorded and a selection (n = 17, or 16.7%) physically and chemically characterised. The average abundance of non-fibrous particles captured by the plankton silks and detectable by microscopy was estimated to...
Article
Full-text available
Polyvinyl chloride (PVC) is one of the most widely used thermoplastics but is also a material of concern because of the generation and release of harmful chemicals during its life cycle. Amongst the chemicals added to PVC are metal-based stabilisers and Sb-based halogenated flame retardant synergists. However, very little quantitative information e...
Article
We report observations of negatively buoyant plastics washed up on the shores of a beach in southwest England in association with deposits of kelp. Items retrieved included polyethylene terephthalate (PET) bottle fragments, polyvinyl chloride toys, electrical casings and construction plastics, polycarbonate goggles, carcass tags, pot rubber, fishin...
Article
Full-text available
Because paint particles consist of a resin (polymer) combined with one or more additives, they bear compositional similarities with microplastics. Despite these shared characteristics, however, paint particles are often undetected, deliberately overlooked or evade classification in the pool of micro-debris (all synthetic debris of < 5 mm in size),...
Article
Microplastics (MP) have been retrieved from settled dusts and rainfall collected monthly over a period of a year and daily over an additional period of ten days in the city of Shiraz and at an elevated remote site (Mount Derak) in Iran. Total monthly deposition of ranged from about 1000 to 3500 MP m−2 at Shiraz and about 200 to 600 MP m−2 at Mount...
Article
Although microplastics (MPs) are ubiquitous environmental contaminants, little is known about their occurrence and behavior in the terrestrial setting. In this study, MPs have been isolated from soils collected from various geomorphological features (yardangs, sand dunes, moving sands, seasonal lakes) of the Kavir and Lut Deserts on the Iranian pla...
Article
Observations of beached polypropylene inkjet cartridges, spilled from a ship container lost in the North Atlantic Ocean, have been compiled through calls on international social media. Within a period of four years from the spillage, a total of about 1500 cartridges was reported in locations as far apart as Florida and northern Norway. The distribu...
Article
Exposure of microplastics (MPs) to a cohort of adults of various demographics from different regions of Iran has been quantitatively assessed. Specifically, MPs were retrieved from filtered washes of the hand and face skin, head hair and saliva of individuals (n = 2000) after an exposure period of 24 h and were counted and, in a selected number of...
Article
Full-text available
Polyester fibres are usually contaminated by antimony because of its use as a catalyst in the production of polyethylene terephthalate and as a flame retardant synergist in a variety of new and recycled polymers. The present study determined the release of antimony (at total concentrations ranging from about 125 to 470 μg g⁻¹) from polyester textil...
Article
Because of their unique properties, rare earth elements (REEs), comprising the lanthanide elements plus Sc and Y, have a variety of integral applications in modern electronic equipment. Consequently, it has been suggested that REEs may act as contaminants of and tracers for recycled electrical and electronic plastics in consumer goods. In this stud...
Article
Full-text available
Oxaliplatin is the newest platinum-based drug to be used widely in chemotherapy. However, very little is known about its behaviour and toxicity once discharged to the environment. In this study, the freshwater macrophyte, Lemna minor, has been exposed to three concentrations of the drug (low, medium and high; 0.4, 10 and 100 μg mL⁻¹, respectively)...
Article
Polystyrene foam (expanded and extruded polystyrene: EPS and XPS, respectively) is a ubiquitous and pervasive type of marine plastic whose physical properties, transport and fate are distinctly different to those of other common (unfoamed) types of thermoplastic litter. In this study, a range of fragments of EPS and XPS retrieved from three beaches...
Article
Tumble dryer lint has been employed as a surrogate for synthetic and processed (microplastic) fibres discharged to the environment from laundering activities and exposed to marine mussels (Mytilus galloprovinciallis) in controlled experiments for a period of 7 d. A range of biological responses at different levels of organisation were subsequently...
Article
Antifouling paint particles (APPs) and associated metals have been identified in sediments around boatyards and marinas globally, but the effects of APPs on benthic organisms are largely unknown. Sub-lethal endpoints were measured following laboratory exposures of the harbour ragworm (Hediste diversicolor) and the common cockle (Cerastoderma edule)...
Article
Full-text available
X-ray fluorescence spectrometry has been employed to measure Pb in a wide range of consumer and environmental plastics, including food-packaging material, household goods, electronic casings, beach litter and agricultural waste. Results reveal high concentrations of Pb (>1000 mg kg-1) in historical items that are still in use or circulation (e.g. t...
Article
Full-text available
With an inherent density marginally below that of seawater, polyolefins (polyethylene-polypropylene) are predicted to float or undergo beaching in the marine environment. Polyolefins commonly observed on the seabed, therefore, require additional considerations that are usually based around increasing density through fouling or packaging into sinkin...
Article
Foamed polystyrene (PS) that may be either expanded (EPS) or extruded (XPS) is a rigid, lightweight insulating thermoplastic that has a variety of uses in the consumer, packaging, construction, and marine sectors. The properties of the material also result in waste that is readily generated, dispersed, and fragmented in the environment. This review...
Article
Antimony (Sb) widely occurs in plastics as a pigment and reaction residue and through the use and recycling of electronic material enriched in Sb as a flame retardant synergist. In this study, clean estuarine sediment has been contaminated by different microplastics prepared from pre-characterised samples of different types of plastic (including a...
Article
Samples of beached plastics and historical and contemporary consumer plastics containing hazardous elements derived from reaction residues or functional additives have been micronised and subject to extraction conditions representative of the digestive environment of seabirds. Mobilisation of Br, Cd, Cr, Hg, Pb and Sb into NaCl solution, an avian p...
Article
Full-text available
Kohl is an eye cosmetic that was traditionally used in many Asian and African countries but that is now more widely available. Ingredients of kohl reported in previous studies seem to be rather variable but mention is frequently made of minerals based on Pb whose use in cosmetic products is prohibited in Europe. We purchased 23 products of kohl fro...
Article
Devon Great Consols (DGC) is a region in southwest England where extensive mining for Cu, Sn and As took place in the nineteenth century. Because of its historical and geological significance, DGC has protected status and is part of the Cornwall and West Devon Mining Landscape UNESCO World Heritage Site. Recently, the region was opened up to the pu...
Article
Although the production and usage of bismuth (Bi) have been increasing, very little is known about the environmental behaviour of this heavy metal. In the present study, the particle-water interactions of Bi are examined under controlled conditions in which the metal is added as a tracer to estuarine sediment suspended in different, environmentally...
Article
Microplastics are known to be associated with co-contaminants, but little is understood about the mechanisms by which these chemicals are transferred from ingested plastic to organisms. This study simulates marine avian gastric conditions in vitro to examine the bioaccessibility of authigenic metals (Fe, Mn) and trace metals (Co, Pb) that have been...
Article
We report concentrations of brominated flame retardants (BFRs) in 23 plastic samples from 20 new and second-hand children's toys sourced from the UK that had been previously shown to be Br-positive by XRF. The results reinforce existing evidence that the recycling of BFR-treated electronic plastics has led to the unintentional BFR contamination of...
Article
The residence times of plastics in the oceans are unknown, largely because of the durability of the material and the relatively short (decadal) period of time over which plastic products have been manufactured. In this study, classic LEGO bricks constructed of acrylonitrile butadiene styrene (ABS) and washed up on the strandlines of beaches of sout...
Article
There are two means by which metals associate with microplastics in the aquatic environment. Firstly, they may be adsorbed to the plastic surface or hydrogenous-biogenic accumulations thereon, and secondly, they may be present in the polymeric matrix as functional additives or as reaction or recyclate residues. In this study, the relative significa...
Article
Concentrations of antimony have been determined for paints and enamels that are available to the consumer or accessible to the public by x-ray fluorescence spectrometry. The metalloid was only present in consumer paints of a speciality (e.g. artistic) nature, but was common in old household paints as an anti-chalking agent and in brightly-coloured...
Article
Antimony (Sb) is a technology critical element whose presence is ubiquitous in manufactured products, and in particular in plastics where it is used extensively as a flame retardant synergist for brominated compounds, as a catalyst for polyethylene terephthalate production, and as a pigment for colour. This study reviews the usage, regulations and...
Article
Cadmium has had a number of historical applications in plastics but is now highly regulated. In this study, plastics containing pigmented or recycled Cd at concentrations up to 16,300 μg g-1 were processed into microplastic-sized fragments and added to clean estuarine sediment. Plastic-sediment mixtures (mass ratio = 1:100) were subsequently expose...
Article
Black consumer plastics are often contaminated with hazardous chemicals because of technological constraints on sorting dark plastic during recycling of municipal waste coupled with the convenience of waste electrical and electronic equipment (WEEE) as a secondary source of black plastic. In this study, samples of beached plastic litter (n = 524) f...
Article
Items of marine plastic litter are conventionally classified as primary or secondary, depending on whether they are distinct objects or angular fragments, respectively. "Pyroplastic" is an additional type of plastic litter that is described here, based on observations made on beached samples from south west England. Pyroplastics are derived from th...
Article
The glass and enamelled decorations of bottles of alcoholic beverages sourced from retailers in the UK were analysed by x-ray fluorescence spectrometry for various heavy metals. In the glass substrate, lead, cadmium and chromium were present at concentrations up to about 1100 g g-1, 1100 g g-1 and 3000 g g-1, respectively, but their environmenta...
Article
Antifouling paint particles (APPs) of between 500 μm and >2 mm in diameter have been identified in silty, intertidal estuarine sediments through a combination of microscopy and x-ray fluorescence spectrometry. APPs were heterogeneously distributed, with maximal concentrations of 430 particles L ⁻¹ (0.2 g L ⁻¹ ) near to a facility where boats are re...
Article
Primary microplastics have been collected from 17 beaches along the Atlantic, English Channel and southern North Sea coasts of western Europe. Based on visual characteristics, these plastics were differentiated as either relatively smooth, lentil- or disc-shaped pre-production pellets (or nurdles), which were usually a few mm in diameter and were m...
Article
Seventy samples of laundry dryer lint from 19 households have been analysed for trace elements (As, Br, Cu, Fe, Ni, Pb, Sb, Zn) by energy-dispersive portable X-ray fluorescence (XRF) spectrometry. Bromine, Fe and Zn were detected in more than sixty samples encompassing all households, with dry weight concentrations ranging from 5.5 to 213 μg g ⁻¹ ,...
Article
Ceramic fragments and fractionated (<2 mm) sediment have been sampled from two beaches in southwest England, along with sediment from a control beach where ceramic waste was lacking. Analysis of the glazed ceramic surfaces by X-ray fluorescence (XRF) spectrometry returned concentrations of Pb up to 729,000 mg kg⁻¹, while XRF analysis of sediment sa...
Article
Cadmium is a toxic heavy metal that has been increasingly regulated over the past few decades. The main exposure routes for the general public are the consumption of certain foods and the inhalation of cigarette smoke. However, additional exposure may occur through the current and historical use of the metal in consumer products. In this paper, the...
Article
While the distribution and effects of microplastics (MPs) have been extensively studied in aquatic systems, there exits little information on their occurrence in the terrestrial environment and their potential impacts on human health. In the present study, street dust and suspended dust were collected from the city and county of Asaluyeh, Iran. Sam...
Article
In this study, the feasibility of measuring the Sb content in different plastic materials by laser induced plasma spectroscopy (LIBS) is explored. Measurements were performed initially on a sample of pure Sb in order to identify the most prominent element transitions before different consumer plastics of varying matrix, composition and color were e...
Article
A portable x-ray fluorescence (XRF) spectrometer and mobile test stand have been employed to examine the feasibility of on site measurements of trace metals in estuarine sediment. In the laboratory, the instrument was able to detect the trace metals: As, Cr, Cu, Pb, Sn and Zn; and the geochemical proxy metals: Ca, Fe, K and Rb; in both fresh and fr...
Chapter
Metal pollution through anthropogenic inputs, particularly in coastal areas, into the marine ecosystem has elevated to large extents for the past decades. Heavy metals, once become bioavailable, tend to bioaccumulate through food chain and ultimately harm human beings. Of particular concerns are cadmium, copper, mercury, lead, and zinc. With emergi...
Article
Deciduous leaves (n = 87) from beech (Fagus sylvatica), birch (Betula spp.) and oak (Quercus spp.) trees have been collected from three metal mine-impacted sites in southwest England and tested for concentrations of trace elements (As, Cu, Pb and Zn) using a field-portable-x-ray fluorescence (FP-XRF) spectrometer configured in a low density mode an...
Article
Black products constitute about 15% of the domestic plastic waste stream, of which the majority is single-use packaging and trays for food. This material is not, however, readily recycled owing to the low sensitivity of black pigments to near infrared radiation used in conventional plastic sorting facilities. Accordingly, there is mounting evidence...
Article
Legacy paint on publicly-accessible structures in residential areas of Plymouth, UK (a bridge parapet, hospital railings, a goal frame, urban street paving and a telephone kiosk) and local paint-contaminated soils have been analysed for lead and other heavy metals (chromium, zinc and barium) by X-ray fluorescence spectrometry. Lead was detected in...
Article
Full-text available
Over 3,000 samples of plastic litter have been retrieved from 12 pebble beaches around the shores of Lake Geneva. The plastic stock consisted of identifiable objects of various size and color, including bottles, bottle tops, cotton buds, pens, toys, and straws, an heterogeneous assortment of fragments whose origin was either discernible or unknown,...
Article
Samples of plastic collected from two beaches in southwest England (n = 185) have been analysed by XRF spectrometry for elements that are hazardous or restricted in synthetic polymers (namely, As, Ba, Br, Cd, Cr, Hg, Pb, Sb and Se). Overall, one or more restricted element was detected in 151 samples, with 15 cases exhibiting non-compliance with res...
Article
About 200 second-hand plastic toys sourced in the UK have been analysed by x-ray fluorescence spectrometry for hazardous elements (As, Ba, Cd, Cr, Hg, Pb, Sb, Se) and Br as a proxy for brominated flame retardants. Each element was detected in > 20 toys or components thereof with the exception of As, Hg and Se, with the frequent occurrence of Br, Cd...
Article
A range of plastic consumer products and components thereof have been analysed by x-ray fluorescence (XRF) spectrometry in a low density mode for Br as a surrogate for brominated flame retardant (BFR) content. Bromine was detected in about 42% of 267 analyses performed on electronic (and electrical) samples and 18% of 789 analyses performed on non-...
Article
The mechanisms of sublethal toxicity of the antifouling biocide, zinc pyrithione (ZnPT), have not been well-studied. This investigation demonstrates that 14-d sublethal exposure to ZnPT (0.2 or 2 μM, alongside inorganic Zn and sea water controls) is genotoxic to mussel haemocytes but suggests that this is not caused by oxidative DNA damage as no si...
Article
Externally decorated glassware used for the consumption of beverages, purchased new or sourced second-hand, and including tumblers, beer glasses, shot glasses, wine glasses and jars, has been analysed for Pb and Cd by portable x-ray fluorescence (XRF) spectrometry. Out of 197 analyses performed on distinctly different colours and regions of enamell...
Article
Fresh and freeze-dried sample sections of the coastal macroalgae, Fucus serratus and F. vesiculosus, and the brackish water macroalga, F. ceranoides, have been analysed for trace elements by field-portable-X-ray fluorescence (FP-XRF) spectrometry using a Niton XL3t in a low density mode with thickness correction. When analysed fresh in a laboratory...
Article
Samples of microplastic (n = 924) from two beaches in south west England have been analysed by field-portable-x-ray fluorescence (FP-XRF) spectrometry, configured in a low-density mode and with a small-spot facility, for the heavy metals, Cd and Pb, and the halogen, Br. Primary plastics in the form of pre-production pellets were the principal type...
Article
The performance of a portable x-ray fluorescence spectrometer configured in a test stand and coupled to a laptop has been evaluated for the determination of various elements (including Br, Cd, Cl, Cr, Cu, Fe, Pb and Zn) in beached microplastics. Under laboratory conditions, analysis of samples that covered the 3-mm x-ray beam returned concentration...

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