Abdelkader Zarrouk

Abdelkader Zarrouk
Université Mohammed Premier | UMP · Department of Chemistry

Professor

About

540
Publications
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9,131
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Publications

Publications (540)
Article
In this study, plant ethanolic extract OCEE (Origanum Compactum Ethanolic Extract), a promising natural product with a cheap cost, was used as a green and sustainable mild steel corrosion inhibitor in a 1 M HCl solution. Chemical, electrochemical, surface analysis, and quantum chemical calculations were used to examine the inhibitory efficacy of OC...
Article
In the present work, two new 8-hydroxyquinoline derivatives namely, 5-(((2-hydroxybenzylidene)amino)methyl) 8-hydroxyquinoline [HBMQ] and 5-(((4-chlorobenzylidene)amino)methyl) 8-hydroxyquinoline [CBMQ] were synthesized and investigated as corrosion inhibitors against the dissolution of carbon steel (C38 steel) in 1 M HCl. These compounds were obta...
Article
Full-text available
In the present work, two new 8-hydroxyquinoline derivatives namely, 5-(((2-hydroxybenzylidene)amino)methyl) 8-hydroxyquinoline [HBMQ] and 5-(((4-chlorobenzylidene)amino)methyl) 8-hydroxyquinoline [CBMQ] were synthesized and investigated as corrosion inhibitors against the dissolution of carbon steel (C38 steel) in 1 M HCl. These compounds were obta...
Article
Cellulose is the most abundant renewable resource in nature and has many industrial uses because of its promising characteristics. The broad-leaved reed is a plant species of the family Typha latifolia, widespread in arid regions, and has good potential for industrial use. In this study, highly crystalline cellulose microfibers were extracted from...
Article
The inhibition influence of synthesized ethyl 5-methyl-1-(((6-methyl-4-nitropyridin-3-yl)amino)methyl)-1H-pyrazole-3-carboxylate (EMPC) on corrosion of carbon steel (CS) in 1M HCl solution was investigated using mass loss measurements, electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization measurements (PDP) techniques. The e...
Article
In this work, we presented a study on the solid phase adsorption of Pb (II) ion by raw cellulose (CB) and by modified cellulose (CM). The metal Pb (II) adsorption mechanism was also interpreted by spectroscopy FTIR and energy-dispersive X-ray (EDX). The most important results for this adsorption can be summarized to: The effect of some experimental...
Article
The inhibitory effect investigation of aqueous and ethanolic extracts of Origanum elongatum Plant (will be referred to in this paper, respectively, as “OEAq and OEEt”) on mild steel corrosion in HCl solutions has been evaluated. The analysis and characterization of both products extracted (OEAq and OEEt) were performed using HPLC-UV-ELSD-MS techniq...
Poster
Full-text available
Food colorants are widely employed in the food industry to improve the aesthetic and sensory qualities of their products. However, the significant amount of these food colorants in industrial effluents makes them classifiable as pollutants. Consequently, effluents containing dyes from food processing plants must be thoroughly cleaned before disposa...
Article
In this work, the new Cu2MgGeS4 quaternary compound thin film was synthesized for the first time by spray-ultrasonic of Cu−.Mg−.Ge precursors onto glass-substrate followed by a sulfurization for 1h at 500°C. The EDX Mapping shows a uniform desitribution of Cu−Mg−Ge-S with a value near to the ideal stoichiometry of 2:1:1:4 of Cu2MgGeS4. X-ray diffra...
Article
The inhibitory effect investigation of aqueous and ethanolic extracts of Origanum elongatum Plant (will be referred to in this paper, respectively, as “OEAq and OEEt”) on mild steel corrosion in HCl solutions has been evaluated. The analysis and characterization of both products extracted (OEAq and OEEt) were performed using HPLC-UV-ELSD-MS techniq...
Article
The new inorganic compound AgSrCu4.5(PO4)6 (BP) was synthesized and characterized by XRD, SEM, and EDS and was finally examined for restraint the deterioration of C35E steel in a hostile medium of hydrochloric acid. During this investigation, electrochemical techniques and surface examination were performed. This new phosphate acts as a cathodic or...
Chapter
Full-text available
Currently, the eco-friendly corrosion inhibitors are widely used to protect the metallic materials from the corrosion destruction. The eco-friendly corrosion inhibitors are biodegradable, low toxic, low volatile, low cost, good water soluble, good adsorbent, and do not contain heavy metals or other toxic compounds. The plant extracts and natural su...
Article
Full-text available
The anti-corrosion potency of 8-(4-methoxyphenyl)-3,6-dioxo-2-(p-tolyl)-3,6-dihydro-2H-thiazolo[3′,2′:2,3][1,2,4]triazolo[1,5-a]pyrimidine-7-carbonitrile (HTPC) was studied by electrochemical experiment measurements complemented by surface analysis using scanning electron microscopy. The DFT method is used to generate Frontier Molecular Orbitals. T...
Article
Full-text available
New 8-hydroxyquinoline-based piperazine, namely 5-((4-phenylpiperazine-1-yl)methyl)8-hydroxyquinoline (PPMQ), has been synthesized and examined as the corrosion inhibitors of carbon steel (CS) in a 1 M HCl medium using electrochemical measurements such as electrochemical impedance spectroscopy, potentiodynamic polarization measurements (PDP), gravi...
Article
Full-text available
The MnPO4·H2O thin film for supercapacitor applications was prepared by potentiodynamic electrodeposition on a platinum electrode. The morphology and microstructure were examined by scanning electron microscope coupled to an energy dispersive X-ray spectroscopy (SEM/EDX) and X-ray diffraction (XRD) respectively. The electrochemical performance of t...
Article
Full-text available
New cationic Gemini surfactant (CGS) molecules were synthesized and investigated as anticorrosive materials for carbon steel (CS) in 1 M HCl solution by chemical, electrochemical and theoretical studies such as DFT and MDS approaches. The anticorrosion efficacy increased with the increase in the CGS concentration. It reached 95.66% at 5 × 10-3 M of...
Article
Full-text available
The synthesis of six aluminum potassium calcium based-phosphate glasses with molar composition of xAl2O3-(50-x)P2O5-10CaO-40K2O, where x = 2.5, 5, 7.5, 10, 12.5, and 15 mol% was complemented. Their structural analyses were performed through XRD, SEM-EDX, DSC, FTIR, and Raman. Further density (ρ) estimations of all samples by the Archimedes method w...
Article
Full-text available
The inhibiting effect of two newly synthesized organic compounds based on 8-hydroxyquinoline, 2-amino-4-phenyl-2H-pyrano[3,2-h]quinolin-3-carbonitrile (QP-H) and 2-amino-4-(4-methoxyphenyl)-2H-pyrano[3,2-h]quinolin-3-carbonitrile (QP-OCH3), on mild steel (MS) corrosion in 1 M HCl has been assessed using various electrochemical techniques [potentiod...
Article
Inhibition of mild steel (M.S) corrosion by some pyrazole-2-acetohydrazide derivatives, namely; ((E)-2-(3,5-dimethyl-1H-pyrazol-1-yl)-N'-(4-hydroxy-3-methoxybenzylidene)acetohydrazide (DHA) and (E)-2-(3,5-dimethyl-1H-pyrazol-1-yl)-N'-(furan-2-ylmethylene)acetohydrazide (DFA)) in 1 M HCl was studied using weight loss (WL), electrochemical impedance...
Article
Photovoltaic properties and kinetic adsorption the various organic dyes have been employed in our work. B3LYP/6-311G (d, p) method is utilized to obtain the optimal geometries of the electronic properties also of the parameters adsorption of the different organic dyes as cationic as [safranin (SF) and Methylene bleu] and anionic as [(MO)] on the bi...
Article
Full-text available
The performance of clay purified and intercalated with Ca²⁺ against Nicrofer 3127 alloy corrosion in hydrodynamics conditions was evaluated utilizing electrochemical techniques, weight loss method, and surface analysis. The characterization technique has shown that the clay tested is the montmorillonite type. Purified montmorillonite and Ca²⁺-montm...
Article
Full-text available
The optimization of the factors influencing the co-electrodeposition method makes it extremely efficient in the production of thin films formed by multiple elements. This work presents the synthesis of Cu2CoSnS4 (CCTS) thin films by the simultaneous electrodeposition of Co, Sn, Cu, and S elements on the FTO substrate using tartaric acid (HT) as a c...
Article
Using ethylenediamine (en) as a structure-directing agent, a novel hybrid decavanadate (diethylenediammonium diammonium decavanadate tetrahydrated) (NH4)2(H2en)2{V10O28}.4H2O has been synthesized via a slow evaporation approach. A low-temperature single-crystal X-ray diffraction investigation was used to investigate its structural structure. Its cr...
Article
Full-text available
The aim of this work is to evaluate the adsorption of Tenofovir using activated carbon (ACc) produced from local maize cobs by the thermochemical activation method with phosphoric acid (H3PO4). The ACc proprieties were evaluated using a variety of methods, including Fourier Transform Infrared Spectrometry (FTIR), Scanning Electron Microscopy (SEM),...
Article
e Chamaerops humilis L. fruit contains several therapeutic qualities. The effect of soxhlet and cold maceration on the chemical composition and antioxidant potential of the extracts produced was the focus of this investigation. According to the research, the oils had a high oleic acid content (32.55 - 43.29 %). The methanolic extracts prepared by m...
Article
In this project, the protective effect of two newly quinoline-3-carboxylate derivatives methyl 2-amino-4-(4-chlorophenyl)-4H-pyrano[3,2–h]quinoline-3-carboxylate (P-1) and methyl 2-amino-4-(4-methoxyphenyl)-4H-pyrano[3,2–h]quinoline-3-carboxylate (P-2) on mild steel (MS) in 1 M HCl has been assessed through using electrochemical techniques, scannin...
Article
The inhibition performance of two bisquinoline analogs, 3-bis((8-hydroxyquinolin-5-yl)methyl)thiourea (BQMT) and O-((8-hydroxyquinolin-5-yl)methyl)((8-hydroxyquinolin-5-yl)methyl)((8-hydroxyquinolin-5-yl)methyl) carbamothioate (QMHC), on carbon steel (CS) in 1M HCl have been assessed through using weight loss tests, electrochemical techniques, scan...
Article
Full-text available
Corrosion is among the challenges most industries face. Corrosion inhibitors are developed to fix the issues of corrosion in these industries. For this reason, the corrosion inhibitive properties on mild steel (MS) of two phenolic Schiff bases named (E)-4-(1-((3-hydroxyphenyl)imino)ethyl)benzene-1,3-diol (PSB1) and (E)-4-(1-(pyridin-2 ylimino)ethyl...
Article
The increase in energy has created a clear imbalance between the availability and usage of these resources, prompting the industry to resort to biofuels. The main objective of this study is to investigate the corrosion resistance of materials used as biofuel production reactors (stainless steel (SS), aluminium (Al), and copper (Cu)) during sunflowe...
Article
Full-text available
Activated carbon (AC) obtained from argan shell residue (ASR) was studied for the removal of the drug sofosbuvir from the liquid phase. The operating parameters including pH, adsorbent dosage, and sofosbuvir concentration were optimized with a Box Behnken design (B.B.D) using the response surface methodology (R.S.M.) approach. The results show a ma...
Article
The isoxazoline derivatives namely 3-phenylamino-5-(3′-methoxy-4′-hydroxyphenyl) isoxazoline (PAMHI), 3-phenylamino-5-(4′-methoxyphenyl)isoxazoline (PAMI) and 3-phenylamino-5-(4′-hydroxyphenyl)isoxazoline (PAHI) were synthesized and tested for their inhibition capacity against the mild steel (MS) corrosion in 1 M H2SO4. Their inhibition performance...
Article
The deposition rate, composition, morphology, and structure of electroless deposits Ni–Mo–P and Ni–Co–P plated at different concentrations of MoO42- and Co2+ from acidic tyrosine baths were conducted in this study. Electrochemical study of electroless Ni–Co–P coating was investigated. The deposition rate and the composition of Ni–Mo–P and Ni–Co–P c...
Article
The inhibition ability of a bipyrazole compound (L1) and its complex copper [Cu (Hbpz)3] (BF4)2] (C1) towards mild steel (MS) corrosion in HCl solution was studied at various concentrations and temperatures using weight loss (WL) potentiodynamic polarization curves (PPC), electrochemical impedance spectroscopy (EIS), scanning electron microscope (S...
Article
The mitigation impacts of two quinolin-8-ol-piperazine analogs 7-((4-(benzo[d][1,3]dioxol-5-ylmethyl)piperazin-1-yl)methyl)quinolin-8-ol (OPMQ) and 7-((4-benzylpiperazin-1-yl)methyl)quinolin-8-ol (BPMQ) on the C35E steel corrosion in 1 M HCl environment were examined by gravimetric, electrochemical, surface analysis, electrolyte analysis, as well a...
Article
Full-text available
This work presents the synthesis of Cu2CoSnS4 (CCTS) thin films by the co-electrodeposition technique of Cu-Co-Sn-S on the Fluorine doped Tin Oxide substrates (FTO), followed by a sulfurization for 1 h at 500°C under an argon flow. To study the effect of the electrodeposition potential on the structural, morphological and optical properties of CCTS...
Article
Two quinolin-8-ol derivatives, 5-(((1-azido-3-chloropropan-2-yl)oxy)methyl)quinolin-8-ol (ACQ) and 5-(((1,3-diazidopropan-2-yl)oxy)methyl)-quinolin-8-ol (DAQ), were prepared via the O-alkylation of 5-chloromethylquinolin-8-ol salts by azido alcohols under simple and mild conditions with good yields. The structures of ACQ and DAQ were characterized...
Article
In order to elaborate stoichiometric CuSbS2 and Cu12Sb4S13 (CAS) thin films by co-electrodeposition on FTO substrates, the copper concentration was varied between 0.015 M and 0.030 M at -0.98 mV co-electrodeposition potential (vs. saturated calomel electrode (SCE)). After a sulfurization step in a quartz tube at 410°C under an argon flow for 45 min...
Article
Two new synthesized bi-pyrazole-carbohydrazides, namely 1,1′-(propane-1,3-diyl)bis (5-methyl-1H-pyrazole-3-carbohydrazide) (P2PZ) and 1,1′-(oxy bis (ethane -2,1-diyl)) bis (5-methyl-1H-pyrazole-3- Carbohydrazide) (O2PZ) were evaluated as corrosion inhibitors for mild steel (MS) in 1.0 M HCl media. Comparative study of inhibitory action of P2PZ and...
Article
Heavy metal pollution is a public health problem that should prompt environmental protection authorities to provide appropriate solutions. The objective of this work concerns the liquid-solid extraction of Cadmium by the filtering resin of raw RB and modified RS reeds. The experimental study clarified the influence of some operating parameters. The...
Article
Full-text available
The preventing effect of novel triphenyl imidazole based on 8-hydroxyquinoline (HDiPIQ) on the corrosion attack of mild steel in 1 M HCl solution was investigated. Electrochemical impedance and potentiodynamic polarization measurements have been realized. Inhibitor concentration increase leads to a considerable shift in mild steel oxidization rate...
Article
In this present research work, new 8-hydroxyquinoline derivatives were synthesized and their molecular structures were confirmed by the ¹H-NMR, ¹³C-NMR, IR and elemental analysis. The antioxidant activity of the synthesized compounds is evaluated through their capacity to scavenge 2,2-di-phenyl-1-picrylhydrazyl (DPPH) free radicals. In addition, th...
Article
Full-text available
This study aims to synthesize new pyrrolic compounds derivatives of 8-hydroxyquinoline, explore the structure-activity relationship and the effect of the substituents carried by the pyrrole ring on their antibacterial properties. These compounds were characterized by IR, ¹H, ¹³C NMR and elemental analysis. The NMR predicted chemical shifts were det...
Article
In this work, the adsorption performance of methylene blue (MB) on rough R and Typha Latifolia RS was studied. On one hand, the effect of various parameters on the adsorption efficiency were studied knowing that the mass of the material, the adsorption time, the initial concentration and the pH of solution. All these different parameters influence...
Chapter
The phenomenon of corrosion is as old as the history of metals and it has been looked on as a menace that destroys metals and structures and turns beauty into a beast. In the new millennium, the demand for corrosion prevention has dramatically increased and now is an integral part of the engineering world. It may therefore be observed that corrosio...
Article
Full-text available
In this work the adsorption and corrosion inhibition conduct of chalcone oxime derivatives on carbon steel in 0.5 M sulfuric acid solution at various temperatures (293, 303, 313, and 323 K) were investigated through weight loss measurements, potentiodynamic polarization, and electrochemical impedance spectroscopy. Results reveal that CO–H and CO–OM...
Article
Full-text available
The present work aims to examine the link between biodiesel degradation and the corrosion behavior of the 307 L stainless steel used for its storage. Biodiesel was produced from soybean waste cooking oil (SWCO) by trans-esterification process based on a heterogeneous catalyst and methanol. 307 L stainless steel was used to assess the metal surface...
Article
In the present work, a newly synthesized compound, named ethyl 2-(3-methyl-2-oxo-1,2-dihydroquinoxalin-1-yl)acetate(EMOqA) was successfully synthesized and characterized using ¹H NMR, ¹³C NMR and FTIR spectroscopy. Single-crystal X-ray crystallography was used to establish the molecular and crystal structure of EMOqA, and CrystalExplorer was used t...
Article
Durable chitosan-based coating material used as a barrier for slow-release fertilizers in the agricultural soil. This approach decreases the intense usage of fertilizer and works on their accessibility for the plants' necessities. In present paper, the proposed coating material was prepared on the basis of chitosan-kaolinite composite (CS-Gl-K). Fo...
Article
Corrosion prevention in the food industry is a significant issue given the harsh conditions under which many production processes are performed. Therefore, we developed a methodology to test and analyze the novel type of green corrosion inhibitors for mild steel (M.S) in an acidic medium based on the Arabic gum (GA) variants from Morocco (GAMo), Ma...
Article
Full-text available
Under room temperature ultrasonic conditions, mixing the neutral 2,4,6-tri(pyridin-2-yl)-1,3,5-triazine (tptz) ligand with Ni(II) salt resulted in the preparation of a unique {[Ni(tptz)Cl(H2O)2]-[Ni(tptz)(H2O)3]}3Cl.5H2O complex with two different nickel(II) centers in a high yield. The crystal structure of {[Ni(tptz)Cl(H2O)2][Ni(tptz)(H2O)3]}3Cl.5...
Article
Full-text available
The extract of Fucus spiralis (FS) was tested as a corrosion inhibitor of carbon steel in a 1M HCl medium. The anti-corrosion properties were analyzed by gravimetric and electrochemical techniques such as potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS). The surface characterization of carbon steel submerged in th...
Article
Full-text available
B3LYP, B3PW91, CAM-B3LYP, HCTH, ωB97XD, and M06-2X are six hybrid correlation-exchange and meta-GGA functionals, with 6-31G(d,p) basis set for the H, C, N, O and Cl atoms and the LANL2DZ basis set for the Fe atom. Utilized to determine the most favorable to be applied with phenyltetrazole derivatives, namely: 5-phenyl-1H-tetrazole (Ph-T), 5-p-tolyl...
Article
The current study aimed to examine the quality of breast milk in Kenitra city (Morocco), regarding its levels of essential elements Iron (Fe), Copper (Cu), and Zinc (Zn) and heavy metals chromium (Cr), lead (Pb), and cadmium (Cd), besides carried out the inter-element correlation and investigated their association with some sociodemographic paramet...
Article
Origanum Compactum Benth Aqueous extract (OCAqE) have been analysed and investigated as green corrosion inhibitor for mild steel in acid solution (1 M HCl). The analysis of Origanum Compactum Benth Aqueous extract was performed using HPLC-UV-ELSD-MS. Electrochemical techniques, electrochemical impedance spectroscopy (EIS) and potentiodynamic polari...
Article
In this study, the antioxidant, antibacterial, antifungal, and insecticidal properties of the essential oils of Thymus algeriensis, Thymus broussonetii and Thymus vulgaris grown in Morocco were investigated. The results obtained will help complete the already published data on these types of plants, especially using untested bacterial and fungal st...
Article
The effect of tyrosine (C9H11NO3) as a new stabilizing agent on the composition and conditions of the electroless plating bath of the Ni-P alloy was studied. A comparative study with trisodium citrate, which is commonly used, as a stabilizing complexing agent revealed the effect of tyrosine in this study. Scanning electron microscopy (SEM) and X-Ra...
Article
B3LYP, B3PW91, CAM-B3LYP, HCTH, ωB97XD, and M06-2X are six hybrid correlation-exchange and meta-GGA functionals, with 6-31G(d,p) basis set for the H, C, N, O and Cl atoms and the LANL2DZ basis set for the Fe atom. Utilized to determine the most favorable to be applied with phenyltetrazole derivatives, namely: 5-phenyl-1H-tetrazole (Ph-T), 5-p-tolyl...
Article
Benzene-sulfonohydrazide (ECMMBSH) Schiff base has been made available in an excellent yield via reflux dehydrate of 4-methylbenzene-sulfonohydrazide with 9-ethyl-9H-carbazole-3-carbaldehyde in EtOH. The synthesis of the ECMMBSH was monitored via two main spectroscopic techniques FT-IR and UV-vis tools; ECMMBSH was characterized via MS, ¹H-NMR, FT-...
Article
Full-text available
The corrosion inhibition of newly synthesized Schiff base derivatives, namely (E)-3-(1-((2-aminophenyl)imino)ethyl)-4-hydroxy-6-methyl-2H-pyran-2-one (FMO), (E)-3-(1-((3-aminophenyl)imino)ethyl)-4-hydroxy-6-methyl-2H-pyran-2-one (FMM), and (E)-3-(1-((4-aminophenyl)imino)ethyl)-4-hydroxy-6-methyl-2H-pyran-2-one (FMP) was investigated for mild steel,...
Article
Triglycidyl ether triethoxy triazine (TGETET) epoxy resin cured by 1.6-diaminohexane (TGETET/DAH) and 4.4-diaminodiphenyl methane (TGETET/DDM) was investigated as potential anticorrosive coating for carbon steel in sodium chloride medium. Polarization curves (PC) and electrochemical impedance spectroscopy (EIS) results displayed the protective effi...
Article
Full-text available
The reaction of bidentate N-S-thione-Schiff base, (E)-benzyl 2-(1-(4-chlorophenyl)- ethylidene)hydrazinecarbodithioate, with Cu(NO3)2·3H2O produced a cis-Cu(II) complex. The molecular structure was confirmed and characterized by CHN-EA, FAB-MS, IR, and UV-Vis analyses. The XRD supported cis-isomer of the bis anionic bidentate N (azomethine) and S (...
Article
Full-text available
To diminish corrosion which leads to structural damages and to implement a green mitigator has induced the usage of aminothiazolyl coumarin derivatives to study mild steel (MS) corrosion using potentiodynamic polarization (PDP), electrochemical impedance spectroscopy (EIS), weight loss, atomic force microscopy (AFM), and electron microscopy with en...