What is acidic component that is present in crude oil ? How is crude oil acidic in nature?
Crude oil consists of different components such as kinds of paraffin, naphthenes, aromatics, asphaltenes, and waxes. Which of these components contribute towards the acidic nature of crude oil?
I would like to mention that naphthenic acids (NA) belong to a large group of carboxylic acids, with alkyl, aromatic, hetero aromatic etc groups and their various combinations. The composition of NA can vary, depending upon the source of crude petroleum and its level / duration of ageing.
The main components of petroleum are paraffins (i.e. alkanes), naphthenes (i.e. cycloalkanes), aromatics (benzene derivatives & the like), waxes(main one is paraffin wax which is called eicosane C20H42) , and residuals (e.g. asphalt). None of these are acidic or contribute to acidity. The weak acids in petroleum are organic & they are the famous ones mentioned in the answer of professor Ajay Mandal but they are minor components in the total bulk of crude petroleum.
Since the diesel products from paraffin-based Daqing crude oil showed low sensitivity to certain commercial diesel pour point depressant (PPDs) that resulted from the high content of paraffin, certain poly-acrylic acid derivatives (PADE) with COOR, COOH, CONHR, and COO−NH3+R groups by molecular design on the mechanics of diesel; PPDs were synthesiz...
Economic loss due to wax precipitation in oil exploitation and transportation has reached several billion dollars a year recently. Development of a model for better understanding of the process of wax precipitation is therefore very important to reduce the loss. In this paper, a new thermodynamic model for predicting phase equilibriums of crude oil...
Comb-type (maleic acid alkylamides-co-α-octadecene) copolymers (MACs) assemble with long-chain n-paraffins and asphaltenes by the hydrophobic alkyl branches and polar groups, respectively, and improve flowability of crude oils upon cooling. Their effects on the crystallization of paraffins from model oils were studied by rheology, optical microscop...