Diamond coating is an alternative solution due to the fact that most diamonds are electrical insulators but extremely efficient thermal conductors. The Al2O3 layer on Al surface may not be fully insulating when the layer thickness is thin. It also reduce thermal conductivity at the same time.
Anodization of the aluminum block may be the most appropriate solution for insulation. However take into account that there will be some volume expansion. In most applications it shouldn't be a problem but if you have tight tolerances you may need to take that into account. Besides, thermal conductivity and thermal expansion of aluminum oxide are diferent from that of aluminum. Take this into account for your application.
With regard to the procedure, in industry it is quite common to perform anodization in sulfuric acid due to its high transparency. The quality standards in industry specify a thickness of aluminum oxide of 20 microns (which could take around 4 h under mild anodization conditions) but for electrical insulation you would need much much less (a few nanometers might do the work but I would recomment some microns if the block may be subject to scratching).
Typical parameters for sulfuric acid anodization are 0.3M sulfuric acid in water, 20V as the applied potential and a cold bath at 5 ºC.
Al2O3, the aluminum oxide is a bad conductor electricity, hence let the block get rusted, thicker the layer better will be the electricity insulation, paint it with aluminum oxide . Thickness of which depends on the voltage to be applied......
Anodization of the aluminum block may be the most appropriate solution for insulation. However take into account that there will be some volume expansion. In most applications it shouldn't be a problem but if you have tight tolerances you may need to take that into account. Besides, thermal conductivity and thermal expansion of aluminum oxide are diferent from that of aluminum. Take this into account for your application.
With regard to the procedure, in industry it is quite common to perform anodization in sulfuric acid due to its high transparency. The quality standards in industry specify a thickness of aluminum oxide of 20 microns (which could take around 4 h under mild anodization conditions) but for electrical insulation you would need much much less (a few nanometers might do the work but I would recomment some microns if the block may be subject to scratching).
Typical parameters for sulfuric acid anodization are 0.3M sulfuric acid in water, 20V as the applied potential and a cold bath at 5 ºC.
Is the same concept applicable for Aluminum nitride?
According to my information it has more conductivity(thermally) than aluminum but acts as electrical insulator. I want to use it as a body for the heater i want to design which will be subjected to 750w above condition.
Well, I haven't worked with AlN but certainly it should work better for heater applications than alumina thanks to its higher thermal conductivity. However, you should check if this AlN layer has good adhesion with the Al beneath since peeling off would destroy the insulation. But I guess that if you use direct nitridation on the aluminum block you will have no problem as it would grow from the Al present in your block. Also, I would expect some volume expansion using this method.
Since I haven't work with this material I can't really help with the process, but I would advice you also to have some microns of AlN on your Al block to provide scratch-resistant electrical insulation.
An alternative if you have access to the technology and your design is primarily driven by the thermal conductivity of the insulating layer would be to apply a CVD diamond coating to the block. Best available thermal conductor, Electrical Insulator, High scratch resistance, but a more expensive process than anodization, or nitriding As with other coating systems you will need to do some research on bond strength to the aluminum and relative thermal expansion of the aluminum and coating materials. These two considerations may be the downside for this solution.
I hope by CVD you mean chemical vapor deposition. my system is subjected to water based experiment i.e water will be in contact, If i am not wrong CVD loses it strength over a time on action of water.
In order to reduce the winding temperature furthest, we adopted the method of adding micron-grade filler to ET-90 base resin, and prepared three kinds of modified highthermal conductivity adhesive specimens (H-Class). At the same time, four kinds of performance tests (water-absorption, adhesive-strength, breakdown-strength, thermalconductivity) had...
The paper deals with the models for estimating the life of electrical insulation under multiple stress conditions. In a first approach, simple models, the inverse-power law and the exponential, are considered for electrical aging; they are combined with the Arrhenius model to find the life equation of insulating materials under temperature and volt...
We reported, for the first time, the fracture toughness of aluminum nitride ceramics at cryogenic temperatures. The fracture toughness increased from 3.98±0.19 to 4.59±0.28 MPa m1/2 with the decreasing temperature from 293 to 77 K. Increasing fraction of transgranular fracture (from 7.3% at 293 K to 14.5% at 77 K) was proposed as a governing mechan...