Lab

Luís Mafra's Lab

Featured research (2)

The identification of acid and nonacid species at the external surface of zeolites remains a major challenge, in contrast with the much‐studied internal acid sites. Here, we show that the synthesis of zeolite ZSM‐5 samples with distinct particle sizes, combined with solid‐state NMR and computational studies of trimethylphosphine oxide (TMPO) adsorption, provides insight into the chemical species on the external surface of the zeolite crystals. 1 H‐ 31 P HETCOR NMR spectra of TMPO‐loaded zeolites exhibit a broad correlation peak at δ P ~ 35 ‐ 55 ppm and δ H ~ 5 ‐ 12 ppm assigned to external SiOH species. Pore‐mouth Brønsted acid sites exhibit 31 P and 1 H NMR resonances and adsorption energies close to those reported for internal acid sites interacting with TMPO. The presence of an external tricoordinate Al‐Lewis site interacting strongly with TMPO is suggested, resulting in 31 P resonances that overlap with the peaks usually ascribed to the interaction of TMPO with Brønsted sites.
Previous studies on CO2 adsorbents have mainly addressed the identification and quantification of adsorbed CO2 species in amine-modified porous materials. Investigation of molecular motion of CO2 species in confinement has not been explored in depth yet. This work entails a comprehensive study of molecular dynamics of the different CO2 species chemi- and physisorbed at amine-modified silica materials through the determination of the rotating frame spin−lattice relaxation times (T1ρ) by solid-state NMR. Rotational correlation times (τC) were also estimated using spin relaxation models based on the Bloch, Wangsness, and Redfield and the Bloembergen−Purcell−Pound theories. As expected, the τC values for the two physisorbed CO2 species are considerably shorter (32 and 20 μs) than for the three identified chemisorbed CO2 species (162, 62, and 123 μs). The differences in molecular dynamics between the different chemisorbed species correlate well with the structures previously proposed. In the case of the physisorbed CO2 species, the τC values of the CO2 species displaying faster molecular dynamics falls in the range of viscous liquids, whereas the species presenting slower dynamics exhibit T1ρ and τC values compatible with a CO2 layer of weakly interacting molecules with the silica surface. The values for chemical shift anisotropy (CSA) and 1H−13C heteronuclear dipolar couplings have also been estimated from T1ρ measurements, for each adsorbed CO2 species. The CSA tensor parameters obtained from fitting the relaxation data agree with the experimentally measured CSA values, thus showing that the theories are well suited to study CO2 dynamics in silica surfaces.

Lab head

Luís Mafra
Department
  • Department of Chemistry

Members (11)

Maria Filipa Ribeiro
  • University of Lisbon
Zhi Lin
  • University of Aveiro
Jeffrey Amelse
  • University of Aveiro
Mariana Sardo
  • University of Aveiro
Sofia M Bruno
  • University of Aveiro
Mirtha Lourenço
  • CICECO - Aveiro Institute of Materials
Ildefonso Marin-Montesinos
  • University of Aveiro
Marina Ilkaeva
  • University of Aveiro
Isabel S. Gonçalves
Isabel S. Gonçalves
  • Not confirmed yet
Martyn Pillinger
Martyn Pillinger
  • Not confirmed yet
Anabela A. Valente
Anabela A. Valente
  • Not confirmed yet
Rita Fonseca
Rita Fonseca
  • Not confirmed yet