Phosphorus, sulfur, and silicon and the related elements (Phosphorus Sulfur Silicon Relat Elem)

Publisher: Taylor & Francis

Current impact factor: 0.56

Impact Factor Rankings

2016 Impact Factor Available summer 2017
2014 / 2015 Impact Factor 0.561

Additional details

5-year impact 0.61
Cited half-life 9.30
Immediacy index 0.18
Eigenfactor 0.00
Article influence 0.10
ISSN 1026-7719

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Taylor & Francis

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Publications in this journal

  • [Show abstract] [Hide abstract]
    ABSTRACT: An efficient protocol was developed for the synthesis of N-sulfonylimines under environment-friendly conditions. Ultrasonic energy was employed to obtain the desired products in excellent yields with high purity under solvent- and catalyst-free conditions. The synthesis of new N-sulfonylimines was accomplished from various N-sulfonamides and benzaldehyde. The structures of the synthesized compounds are confirmed by elemental analysis as well as by 1H, 13C NMR spectral data, IR and MS.
    No preview · Article · Jan 2016 · Phosphorus, sulfur, and silicon and the related elements
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    ABSTRACT: This survey is mainly concerned with selected reactions of 2,3-dichloro-1,4-naphthoquinone (DHNQ), 3,4,5,6-tetrachloro-1,2-benzoquinone (o-CHL), 2,3,5,6-tetrachloro-1,4-benzoquinone (p-CHL) and 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) as π-deficient quinones which are used or offer potential use for sulfur heterocyclic synthesis. Reaction of various donors with the π-deficient quinones are studied, especially those via charge-transfer complex formation.
    No preview · Article · Jul 2014 · Phosphorus, sulfur, and silicon and the related elements
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    ABSTRACT: This work is devoted to the influence of some impuritiesonthe phosphogypsumduringthe manufactureofwet process phosphoricacidbythe sulfuric acid. This process produces phosphoric acid and calcium sulfatethat containimpurities such ascopper, zinc and cadmiumwhich constitute an obstaclewhen their content exceeds the recommended maximum threshold. The remove these impurities totally or partially, the contribution of chemometrics iscompulsory.The methodology is based on the modeling and optimizationin order to carryoutthe optimumof the production of a purephosphoric acid. To achieve this, wehave determinedthe influentfactors likethe pH and the temperature.
    No preview · Article · Sep 2013 · Phosphorus, sulfur, and silicon and the related elements
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    ABSTRACT: Sodium copper (II) arsenate Na7Cu4(AsO4)5 has been grown by conventional high-temperature, solid-state methods in molten-salt media. It was characterized by single crystal X-ray diffraction (XRD), thermal analysis (DTA–TGA), scanning electron microscopy (SEM), semi-quantitative energy dispersive spectroscopy analysis (EDS) and by vibrational spectroscopy. Na7Cu4(AsO4)5 exhibits a three-dimensional framework built up of CuO5, CuO4 and AsO4 polyhedra, with intersecting channels in which the Na+ cations are located. The three dimensional cohesion of the framework results from Cu–O–As bridges. CuO5 and CuO4 polyhedra are elongated due to the Jahn-Teller effect, where as AsO4 tetrahedra are almost regular. This new structural model is validated by the charge distribution (CD) analysis. The infrared and Raman spectra confirmed the presence of AsO4 tetrahedra.
    No preview · Article · Sep 2013 · Phosphorus, sulfur, and silicon and the related elements
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    ABSTRACT: A computational study based on density functional theory (DFT) calculations were performed to investigate the influence of arsenic doping (As-doping) on the electronic and structural properties of the (6,0) zigzag silicon carbide nanotube (SiCNT) as a n-semiconductor. We extended the DFT calculation to predict the electronic structure properties of As-doped silicon carbide nanotubes, which are very important for production of solid-state devices and other applications. The study of the optimized structures, NMR parameters, electronic properties, and quantum molecular descriptors of the AsSi and AsC models show that the AsSi model is a better n-semiconductor from AsC model in production of solid-state devices.
    No preview · Article · Jun 2013 · Phosphorus, sulfur, and silicon and the related elements
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    ABSTRACT: Leading from our work in asymmetric alkene synthesis it was discovered that the alkenylatio of aldehydes with phosphonates proceeds smoothly at room temperature in the absence of Lewis acidusing triethylamine as the base if the reaction is carried out at a pressure of 8 kbar. Based on this protoco a new domino process was developed, combining the HWE reaction with a Heck coupling, thus allowing the one pot synthesis of trisubstituted alkenes.
    No preview · Article · Jun 2013 · Phosphorus, sulfur, and silicon and the related elements
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    ABSTRACT: A two-step synthesis for 2,6-bis[(diphenyl)-N,N-diethylcarbamoylmethylphosphine oxide]pyridine N-oxide (3) from 2,6-bis[(diphenylphosphinoyl)methyl]pyridine is reported along with coordination chemistry with Dy(III) and Yb(III). Crystal structure determinations for the ligand 3S,S and 1:1 complexes [Dy(3R,S)(NO3)3]·(Me2CO) and [Yb(3R,S)(NO3)3]·(Me2CO) are described. In these complexes, the pentafunctional ligand 3 coordinates in a tridentate NOPOPO chelate mode.
    No preview · Article · May 2013 · Phosphorus, sulfur, and silicon and the related elements
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    ABSTRACT: To develop a series of bio-active heterocycles in minimum number of steps, 3-methyl-4-(substituted phenyl)-1-phenyl-4,8-dihydropyrazolo[4′,3′:5,6′pyrano[2,3-d]pyrimidine-5,7(1H,6H)-dithione 2(a-j), 4-(4-substituted phenyl)-5-imino-3-methyl-1,6-diphenyl-4,5,6,8-tetrahydropyrazolo[4′,3′:5,6′pyrano[2,3-d]pyrimidine-7(1H)-thione 3(a-j) and N-[4-(substituted phenyl)-3-methyl-1-phenyl-7-thioxo-1,4,7,8-hexahydropyrazolo[4′,3′:5,6]pyrano[2,3-d]pyrimidine-5-yl]thiourea 4(a-j) have been synthesized from amino nitrile functionality 1(a-j). The structures of the compounds were elucidated by IR, 1H NMR, elemental analysis and some representative 13C NMR and mass spectra. All the title compounds were screened for antimicrobial and antitubercular activities, while some representative compounds were tested for antioxidant activity. Out of synthesized compounds, compounds 1j (4-CH3), 2d (4-F), 4c (4-OH) and 4i (3-Br) exhibited maximum inhibition against M. Tuberculosis H37Rv. Compound 3c (4-OH) revealed elevated efficacy against all tested bacterial strain, while compounds 1i (3-Br), 2c (4-OH) and 3h (3-NO2) were found efficacious against C. albicans as compared to standard drugs.
    No preview · Article · May 2012 · Phosphorus, sulfur, and silicon and the related elements
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    ABSTRACT: Substitution reactions of the complex [Pt(dien)H2O]2+ (where dien = diethylentriamine or 1,5-diamino-3-azapentane) with sulfur-containing L-cystine have been studied in a 1.0 × 10−1 mol dm−3 aqueous perchlorate medium at various temperatures (298–323 K) and 4.45 ≤ pH ≤ 2.15 using UV-vis spectroscopy. The products obtained have been characterized by their infrared and 1H NMR datasets at various pH levels and temperatures. From infrared and 1H NMR data, products have indicated that [Pt(dien)H2O]2+ reacted with L-cystine forming a Pt–S bond at low pH. At high pH, a product complex through the Pt–N bond has been formed. All rate constants have been evaluated from nonlinear double exponential plots. The activation parameters ΔH# and ΔS# have been determined using the Eyring equation. The products, SNi, and reversible rate constants have been evaluated. Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file. GRAPHICAL ABSTRACT
    No preview · Article · Aug 2011 · Phosphorus, sulfur, and silicon and the related elements