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    ABSTRACT: Visible light induced semiconductor photocatalysis has received a great attention in recent years due to the contamination of water bodies. In the present study, we have reported the photo catalytic degradation of a toxic organic dye, malachite green using a ZnO doped Dy2O3 photo catalyst under Visible light irradiation. The nanocrystalline photocatalyst was prepared by a precipitation method employing the respective nitrates and sodium carbonate as precursors and were characterized by FT-IR, XRD, UV-Vis DRS, FE-SEM and AFM analysis. The experimental results proved that the prepared photo catalyst were crystalline, nanosized and highly active in the visible region. The UV-Vis DRS results suggested that the band gap was 3.1 eV for the prepared photo catalyst. The photodegradation efficiency of malachite green was analyzed by various experimental parameters namely pH, catalyst dosage, variation of substrate concentration and effect of electrolyte addition. The photo degradation process followed a pseudo first order kinetics and was continuously monitored by UV-Visible spectrophotometer. The degradation of malachite green was above 99% within 1 hr of Visible light irradiation employing the doped photocatalyst, whereas pristine metal oxide possessed only 67% and pristine lanthanide oxide possessed activity which was only due to photolysis. A plausible mechanism for the generation of OH radicals and the pathway for MG dye degradation has been proposed in this study. The experimental results clearly shows that nanocrystalline semiconductor doped lanthanide oxides are highly active under visible light irradiations may find wider applications in environmental remediation technologies.
    No preview · Article · Jun 2015 · Journal of Saudi Chemical Society
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    ABSTRACT: Here we report the preparation of collagen-poly(dialdehyde) guar gum based hybrid functionalized scaffolds covalently immobilized with platelet derived growth factor - BB for tissue engineering applications. Poly(dialdehyde) guar gum was synthesized from selective oxidation of guar gum using sodium periodate. The synthesized poly(dialdehyde) guar gum not only promotes crosslinking of collagen but also immobilizes the platelet derived growth factor through imine bonds. The covalent crosslinking formed in collagen improves thermal, swelling and biodegradation properties of the hybrid scaffolds. The prepared hybrid scaffolds show 3D interconnected honeycomb porous structure when viewed under a microscope. The release of immobilized platelet derived growth factor was seen up to 13th day of incubation thereby proving its sustained delivery. The developed hybrid scaffold leads to a quantum increase in NIH 3T3 fibroblast cell density and proliferation thereby demonstrating its potential for tissue engineering applications.
    No preview · Article · Dec 2014 · Carbohydrate Polymers
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    ABSTRACT: The present study emphasizes the biosurfactant mediated anthracene degradation by a marine alkaliphile Bacillus licheniformis (MTCC 5514). The isolate, MTCC 5514 degraded >95% of 300 ppm anthracene in an aqueous medium within 22 days and the degradation percentage reduced significantly when the concentration of anthracene increased to above 500 ppm. Naphthalene, naphthalene 2-methyl, phthalic acid and benzene acetic acid are the products of degradation identified based on thin layer chromatography, high performance liquid chromatography, gas chromatography and mass analyses. It has been observed that the degradation is initiated by the biosurfactant of the isolate for solubilization through micellation and then the alkali pH and intra/extra cellular degradative enzymes accomplish the degradation process. Encoding of genes responsible for biosurfactant production (licA3) as well as catabolic reactions (C23O) made with suitable primers designed. The study concludes in situ production of biosurfactant mediates the degradation of anthracene by B. licheniformis.
    Full-text · Article · Oct 2014 · Biotechnology Reports


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Top publications last week by reads

Journal of molecular graphics & modelling 01/2014; 49C:25-37. DOI:10.1016/j.jmgm.2013.12.008
53 Reads
Carbohydrate Polymers 12/2015; 141. DOI:10.1016/j.carbpol.2015.12.074
24 Reads

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See how the RG Scores of researchers from Central Leather Research Institute are distributed.