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The PXRD patterns of selected (TbxM1−x)2(1,4-bdc)3‧4H2O (M = Y, La, Gd; x = 0, 0.01, 0.1, 1) and the simulated XRD pattern of Tb2(1,4-bdc)3‧4H2O single-crystal structure were taken from ref. [35] (a) and unit cell volume (Vu.c.) concentration dependence refined for (TbxM1−x)2(1,4-bdc)3·4H2O (M = Gd, La, Y) (b).
Source publication
The structural features and luminescent properties of heterometallic Tb–Gd, Tb–La, and Tb–Y terephthalate metal–organic frameworks, namely (TbxM1−x)2(1,4-bdc)3∙4H2O (M = Gd, La, Y), were studied in detail in a wide concentration range (x = 0.001–1). The crystalline phase of synthesized compounds corresponds to Ln2(1,4-bdc)3·4H2O. The lifetime of 5D...
Contexts in source publication
Context 1
... powder X-ray diffraction (PXRD) patterns of the synthesized compounds (Tb x M 1−x ) 2 (1,4-bdc) 3 ·nH 2 O (M = Y, La, Gd) are shown in Figure 1a (main text) and Figure S1 (Supplementary Materials). The analysis of XRD patterns demonstrates that all synthesized compounds possess the Ln 2 (1,4-bdc) 3 ·4H 2 O crystalline phase (Ln = Ce-Yb) [35]. ...
Context 2
... powder X-ray diffraction (PXRD) patterns of the synthesized compounds (Tb x M 1−x ) 2 (1,4-bdc) 3 ·nH 2 O (M = Y, La, Gd) are shown in Figure 1a (main text) and Figure S1 (Supplementary Materials). The analysis of XRD patterns demonstrates that all synthesized compounds possess the Ln 2 (1,4-bdc) 3 ·4H 2 O crystalline phase (Ln = Ce-Yb) [35]. ...
Context 3
... powder X-ray diffraction (PXRD) patterns of the synthesized compounds (TbxM1−x)2(1,4-bdc)3·nH2O (M = Y, La, Gd) are shown in Figure 1a (main text) and Figure S1 (Supplementary Materials). The analysis of XRD patterns demonstrates that all synthesized compounds possess the Ln2(1,4-bdc)3·4H2O crystalline phase (Ln = Ce-Yb) [35]. ...
Context 4
... powder X-ray diffraction (PXRD) patterns of the synthesized compounds (TbxM1−x)2(1,4-bdc)3·nH2O (M = Y, La, Gd) are shown in Figure 1a (main text) and Figure S1 (Supplementary Materials). The analysis of XRD patterns demonstrates that all synthesized compounds possess the Ln2(1,4-bdc)3·4H2O crystalline phase (Ln = Ce-Yb) [35]. ...
Context 5
... unit cell volumes were calculated from unit cell parameters. We have found that Vegard's law is obeyed in the studied systems because unit cell volumes linearly depend on the Tb 3+ content (Figure 1b) [37]. Therefore, the (TbxM1−x)2(1,4-bdc)3·4H2O (M = Y, La, Gd) terephthalates can be considered as solid solutions in a whole concentration range. ...
Context 6
... unit cell volumes were calculated from unit cell parameters. We have found that Vegard's law is obeyed in the studied systems because unit cell volumes linearly depend on the Tb 3+ content (Figure 1b) [37]. Therefore, the (Tb x M 1−x ) 2 (1,4-bdc) 3 ·4H 2 O (M = Y, La, Gd) terephthalates can be considered as solid solutions in a whole concentration range. ...
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