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Single crystal structures: (a) APC‐electrolyte: Precipitated from THF solutions of: left: 0.4 m AlCl3 + 0.8 m PhMgCl, right: 0.25 m AlCl3 + 0.125 m PhMgCl, by Pour et al. (Created in Diamond 4.0 using published data).[49]; (b) Cation of the Mg(TFSI)2‐AlCl3‐MgCl2/DME electrolyte by Yang et al. Reproduced with permission.,[38] Copyright © 2021, American Chemical Society (c) [Mg2Cl3‐6THF][HMDSAlCl3] presented by Kim et al. Reproduced with permission.,[30] Springer Nature, Copyright © 2011, H. S. Kim, T. S. Arthur, G. D. Allred, J. Zajicek, J. G. Newman, A. E. Rodnyansky, A. G. Oliver, W. C. Boggess, J. Muldoon; (d) (C14H21O)MgCl‐MgCl2/DME obtained by Pan et al. (Created in Diamond 4.0 using published data).[50]
Source publication
Rechargeable magnesium batteries (RMBs) have the potential to provide a sustainable and long‐term solution for large‐scale energy storage due to high theoretical capacity of magnesium (Mg) metal as an anode, its competitive redox potential (Mg/Mg²⁺:−2.37 V vs. SHE) and high natural abundance. To develop viable magnesium batteries with high energy d...