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| Sampling sites in Santiago, Chile. (A) B Park (L. tulipifera); (B) VM Avenue (L. tulipifera); and (C) V Avenue (Platanus sp). Red dots identify individuals sampled at each site.
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Anthropogenic volatile organic compounds (AVOCs) represent the third largest contribution in gaseous emissions in the urban and peri-urban region of Santiago, the capital of Chile. Some of these compounds are toxic or mutagenic, cause serious damage to human health, and decrease plant growth and development. There is little international informatio...
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... sites of sampling sites were selected: two with similar high vehicle traffic and a third in an urban park, as explained below and shown in Figure 1. At the first site, samples of welldeveloped sunny leaves and directly exposed to high vehicle traffic (operational speed of 26.5 km/h, UOCT, 2019) were taken from twenty individuals of L. tulipifera (n = 20) along Vicuña Mackenna avenue (VM Avenue) in the La Florida commune. ...
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The use of volatile organic compounds (VOCs) produced by microorganisms for the biological control of plant diseases has attracted much attention in recent years. In this study, the antifungal activity and identity of VOCs produced by Rahnella aquatilis JZ-GX1 isolated from the rhizosphere soil of pine were determined and analyzed. The effect of th...
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... To quantify the impact of AVOCs retained on leaf surfaces on tropospheric O 3 formation, estimators of photochemical reactivity, such as propylene equivalents (Prop-equiv) and Ozone Formation Potential (OFP), are commonly used. These parameters help assess the contribution of AVOCs to atmospheric chemistry by measuring their reaction with OH radicals and other reactive species [43]. ...
... The elimination of O 3 -generating precursors (AVOC) was established as a quantifiable parameter, expressed in terms of Prop-equiv and the OFP. Based on the compounds retained in foliar material, their O 3 formation capacities are determined, thus providing a representative estimate of the tree species' potential to mitigate tropospheric O 3 formation[43]. ...
Tropospheric ozone (O3) and other pollutants significantly affect Chile’s Metropolitan Region, posing risks to human health. As a secondary pollutant and a major photochemical oxidant, O3 formation is driven by anthropogenic volatile organic compounds (AVOCs) from the residential and transport sectors, the main sources of gaseous emissions. This study evaluated the AVOC capture capacity of leaf material from two tree species, Quillaja saponaria (native species) and Robinia pseudoacacia (exotic species), as potential urban biomonitors. Leaf samples were collected near nine SINCA official monitoring stations and the Antumapu University Campus, stored frozen, and analyzed by HS-SPME-GC/MSD for AVOC quantification. Photochemical reactivity and O3 formation potential were assessed using equivalent propylene concentration (Prop-Equiv) and Ozone Formation Potential (OFP) methods. The results showed that both species captured atmospheric AVOCs, confirming their role as bioindicators. However, Q. saponaria adsorbed significantly higher AVOC concentrations and exhibited greater tropospheric O3 formation potential than R. pseudoacacia. Given the AVOC adsorption capacity of both tree species, they could be used as biomonitors for styrene and also as a biomonitor for toluene in the case of Q. saponaria. This research highlights the importance of selecting tree capacity to improve urban air quality.
... However, there is growing evidence that the removal of PM is one of the positive effects of urban forests (Dzierzanowski et al., 2011;Manes et al., 2016;Nowak et al., 2018;Song et al., 2015), among other effects such as providing primary productivity of vegetation (Costanza et al., 2007;Roeland et al., 2019) or removing gases (Araya et al., 2019;Nowak et al., 2018;Viecco et al. 2018). Indeed, the leaves' surface and stems adsorb or absorb significant amounts of air pollutants. ...
Airborne particulate matter is a serious threat to human health, especially in fast-growing cities. In this study, we carried out a magnetic and elemental study on tree leaves used as passive captors and urban dust from various sites in the city of Santiago, Chile, to assess the reliability of magnetic and elemental measurements to characterize particulate matter pollution from vehicular origin. We found that the magnetic susceptibility and saturation isothermal remanent magnetization measured on urban tree leaves is a good proxy for tracing anthropogenic metallic particles and allow controlling the exposure time for particulate matter collection, in agreement with other studies carried out in large cities. Similar measurements on urban soil can be influenced by particles of detritic (natural) origin, and therefore, magnetic measurements on tree leaves can help to identify hotspots where fine particles are more abundant. Elemental particle-induced X-ray emission analysis of tree leaves showed the presence of a number of elements associated with vehicular emissions, in particular Cu, Zn, Fe, K and S which are present at every site, and As, Se, V, Ni, Sr, Zr, Mo and Pb identified at some sites. We observed a correlation between magnetic parameters and the concentrations of S and Br as well as Cu to a smaller extent. Moreover, this study shows the importance of selecting carefully the tree species as well as the location of trees in order to optimize phytoremediation.
The adverse effects of urbanized areas’ growth might be mitigated by the multiple ecosystem services that urban green infrastructure provides. However, the design and composition of such infrastructure is still a hotly debated issue, mainly considering the challenges associated with the use of exotic plant species. To assess if there is a clear association between the species’ origin and ecosystem services or ecosystem disservices, an in-depth systematic literature review was carried out based on a bibliometric approach to assess the panorama of the scientific perspective. Based on the results, a detailed analysis was performed for the urban green infrastructure of five European Mediterranean cities, where management and expansion of the urban green infrastructure might act as tools to mitigate climate change and biodiversity loss. Urban green infrastructure benefits to urban areas and its composition must consider the balance between services and disservices provided by plant species. Data analysis shows that disservices are not exclusively related to exotic species, revealing that plant species selection based on their origin represents a biased approach, as it often disregards the higher capacity of some exotic species to thrive under continuous pressure and disturbance, along with relevant and highly valued cultural services provided. Since exotic species are commonly used, ecosystems formed can be seen as experiments to support decisions, allowing new approaches to planning, designing, and maintaining urban green infrastructure.
Shijiazhuang, the city with the worst air quality in China, is suffering from severe ozone pollution in summer. As the key precursors of ozone generation, it is necessary to control the Volatile Organic Compounds (VOCs) pollution. To have a better understanding of the pollution status and source contribution, the concentrations of 117 ambient VOCs were analyzed from April to August 2018 in an urban site in Shijiazhuang. Results showed that the monthly average concentration of total VOCs was 66.27 ppbv, in which, the oxygenated VOCs (37.89%), alkanes (33.89%), and halogenated hydrocarbons (13.31%) were the main composite on. Eight major sources were identified using Positive Matrix Factorization modeling with an accurate VOCs emission inventory as inter-complementary methods revealed that the petrochemical industry (26.24%), other industrial sources (15.19%), and traffic source (12.24%) were the major sources for ambient VOCs in Shijiazhuang. The spatial distributions of major industrial activities emissions were identified by using geographic information statistics system, which illustrated the VOCs was mainly from the north and southeast of Shijiazhuang. The inverse trajectory analysis using Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) and Potential Source Contribution Function (PSCF) clearly demonstrated the features of pollutant transport to Shijiazhuang. These findings can provide references for local governments regarding control strategies to reduce VOCs emissions.
