- Osmium(II) Tethered Half-Sandwich Complexes: pH-dependent Aqueous Speciation and Transfer Hydrogenation in Cells

Hydrolysis of the Os–Cl bond for complexes 1–13. The bars represent the percentage of remaining open-tether chlorido complexes 1–13 over time in unbuffered D2O as determined by ¹H NMR. Equilibrium is mostly reached in the first 24 h. Complex 13 is fully hydrolysed from the first data recording (t ≤ 15 min upon dissolution)

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Reference

Osmium(II) Tethered Half-Sandwich Complexes: pH-dependent Aqueous Speciation and Transfer Hydrogenation in Cells - Scientific Figure on ResearchGate. Available from: https://www.researchgate.net/figure/Hydrolysis-of-the-Os-Cl-bond-for-complexes-1-13-The-bars-represent-the-percentage-of_fig5_352307476 [accessed 15 Jun 2025]

Caption

Hydrolysis of the Os–Cl bond for complexes 1–13. The bars represent the percentage of remaining open-tether chlorido complexes 1–13 over time in unbuffered D2O as determined by ¹H NMR. Equilibrium is mostly reached in the first 24 h. Complex 13 is fully hydrolysed from the first data recording (t ≤ 15 min upon dissolution)

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<a href="https://www.researchgate.net/figure/Hydrolysis-of-the-Os-Cl-bond-for-complexes-1-13-The-bars-represent-the-percentage-of_fig5_352307476"><img src="https://www.researchgate.net/publication/352307476/figure/fig5/AS:11431281182956423@1692637732340/Hydrolysis-of-the-Os-Cl-bond-for-complexes-1-13-The-bars-represent-the-percentage-of.tif" alt="Hydrolysis of the Os–Cl bond for complexes 1–13. The bars represent the percentage of remaining open-tether chlorido complexes 1–13 over time in unbuffered D2O as determined by ¹H NMR. Equilibrium is mostly reached in the first 24 h. Complex 13 is fully hydrolysed from the first data recording (t ≤ 15 min upon dissolution)"/></a>