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ΔfH O for isomers with 11 atoms and current astronomical status

ΔfH O for isomers with 11 atoms and current astronomical status

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Conference Paper
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The study unravels the dynamic interplay of energy, stability, and abundance, providing profound insights into the composition of the interstellar medium. This investigation promises to unveil the underlying principles shaping the celestial tapestry of astrochemistry. High-level quantum chemical calculations provide accurate enthalpies of formation...

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Quantum chemical calculations were carried out to quantitatively understand the origin of the Felkin–Anh(–Eisenstein) model, widely used to rationalize the π-facial stereoselectivity in the nucleophilic addition reaction to carbonyl groups directly attached to a stereogenic center. To this end, the possible approaches of cyanide to both (S)-2-pheny...