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Common solid and liquid desiccant materials

Common solid and liquid desiccant materials

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This paper reviews the current research and advances in humidity control for residential and commercial buildings. Desiccant and hygroscopic buffering zones are summarized. System types, performances and challenges are presented to help the reader select the best cooling dehumidification system for his application or project. More emphasis is put o...

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... are different types of solid desiccants such as silica gels, lithium chloride (LiCl), and molecular sieves ( ). Figure 1 summarizes some common solid and liquid desiccant materials 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 3 used for humidity control purposes. Solid desiccants are usually embedded in a wheel or other means that allow the desiccant material to be in contact with two air streams, as shown in Figure 2. Figure 2 represents a typical rotating wheel dehumidifier where a solid desiccant is contained inside the packing of the wheel. ...
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... liquid desiccant materials, as shown in Figure 1, include lithium and chloride based solutions such as LiCl, LiBr, CaCl 2 , NaCl, tri-ethylene glycol and mixtures of the pre-mentioned liquid desiccants. The performance of liquid desiccant systems is controlled by the effectiveness and operation of the dehumidifier and the regenerator. ...
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... designs for direct contact dehumidifier-regenerator systems are presented in this paper including packed bed, spray tower and falling film types. In the packed bed dehumidifier, shown in Figure In an adiabatic packed bed, shown in Figure 10(a), the temperature of the desiccant solution changes as it flows through the dehumidifier-regenerator due to the heat transfer with the air stream and due to phase change which accompanies the moist transfer. In an internally cooled/heated "isothermal" packed bed, shown in Figure 10(b), the solution is continuously cooled/heated by a third fluid. ...
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... the packed bed dehumidifier, shown in Figure In an adiabatic packed bed, shown in Figure 10(a), the temperature of the desiccant solution changes as it flows through the dehumidifier-regenerator due to the heat transfer with the air stream and due to phase change which accompanies the moist transfer. In an internally cooled/heated "isothermal" packed bed, shown in Figure 10(b), the solution is continuously cooled/heated by a third fluid. This fluid could be water. ...
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... are three configurations associated with falling film dehumidifiers: cross flow, parallel flow, and counter flow. These configurations are shown in Figure 11 ( Abdel-Salam et al., 2016). 534 535 536 537 538 539 540 541 542 543 544 545 546 547 548 549 550 551 552 553 554 555 556 557 558 559 560 561 562 563 564 565 566 567 568 569 570 571 572 573 574 575 576 577 578 579 580 581 582 583 584 585 586 587 588 ...
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... for converting solar radiation into useful energy for usage in the air-conditioning or cooling processes are summarized in Figure 12. Solar regeneration systems are very effective over the long 710 711 712 713 714 715 716 717 718 719 720 721 722 723 724 725 726 727 728 729 730 731 732 733 734 735 736 737 738 739 740 741 742 743 744 745 746 747 748 749 750 751 752 753 754 755 756 757 758 759 760 761 762 763 764 765 766 767 14 term as they provide sustainable and renewable energy sources. ...
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... 2007, Henning presented a solar driven solid desiccant system as shown in Figure 14. The solid desiccant adsorption was utilized for both adsorption cooling and adsorption dehumidification. ...
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... solid desiccant adsorption was utilized for both adsorption cooling and adsorption dehumidification. As shown in Figure 14, as the exhaust air is released out to the atmosphere, it exchanges energy and absorbs the moist from the incoming supplied air. The incoming fresh air is dehumidified in the rotating dehumidifying wheel, precooled in the heat recovery exchanger, then humidified before being cooled further down, during summer time, to the desired temperature using a cooling chiller. ...
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... also concluded that the mass flow rate of air can improve the COP when increased, but this will limit its outlet temperature and, thus, recommended a balance between the system COP and the leaving temperature of air ( Dai et al., 2002). Figure 14. Solar driven solid desiccant system (Henning, 2007) (Ge et al., 2010) simulated a solar driven two-stage rotary desiccant cooling system. ...
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... Liu et al., 2010) investigated liquid desiccant systems that control humidity independent of the supply air temperature similar to the system shown in Figure 15. The results showed that the required chilled water temperature by the system was increased from 7 ˚C to 17˚C17˚C due to the removal of the latent load from the chiller. ...
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... mathematical model for a liquid desiccant dehumidifier that dehumidifies a space independent of the air cooling systems was developed by (Keniar et al., 2015). The liquid desiccant regeneration was 829 830 831 832 833 834 835 836 837 838 839 840 841 842 843 844 845 846 847 848 849 850 851 852 853 854 855 856 857 858 859 860 861 862 863 864 865 866 867 868 869 870 871 872 873 874 875 876 877 878 879 880 881 882 883 884 885 16 integrated with a solar energy source as shown in Figure 15. Membrane technology was not investigated as part of this research, but rather the membrane was assumed to be permeable for water vapor only and not for liquid desiccant. ...
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... developed mathematical model was validated by conducting experimental testing. The developed model was used to compare the performance of the system shown in Figure 15 against a conventional AC system. An improvement of 10% in the dehumidification effectiveness was achieved. ...
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... initial cost of the system needed a payback period of 7 years and 8 months compared to conventional AC systems operating under the same conditions. Figure 15. Schematic of the separate dehumidification system integrated with renewable solar energy ( Keniar et al., 2015) ( Angrisani et al., 2015) investigated the dependence of a hybrid liquid desiccant system, operating with a silica gel desiccant rotating wheel and a small regenerator, on several parameters such as outdoor air and regeneration temperatures, outdoor humidity ratio, desiccant wheel rotational speed, and air and liquid desiccant flowrates. ...
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... membrane can be permeable or semi-permeable allowing the passage of water vapor only with no mass transfer. Figure 16 shows a liquid to air membrane technology that is a semi-permeable membrane. It allows the transfer of water vapor but not any liquid. ...
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... allows the transfer of water vapor but not any liquid. Usually, the flat plate "liquid-to-air membrane energy exchange" (LAMEE) consists of several air and solution channels that are separated by semi permeable membranes as shown in Figure 16b. Figure 16a shows a microscopic view of the membrane. ...
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... the flat plate "liquid-to-air membrane energy exchange" (LAMEE) consists of several air and solution channels that are separated by semi permeable membranes as shown in Figure 16b. Figure 16a shows a microscopic view of the membrane. This membrane is characterized by: 1) low vapor diffusion resistance, as low as 97 seconds per meter, that improves the dehumidification process, 2) high liquid penetration pressure that prevents the transfer of any desiccant droplets from the desiccant solution to the air channels, and 3) high modulus of elasticity which decreases the deflection of the membrane and, thus, reduces the flow mal-distribution in the air and desiccant channels. ...
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... Huang et al., 2016) conducted experimental and numerical analysis for an internally cooled membrane-based liquid desiccant arranged in cross-flow with air. Water was allowed to flow vertically and formed falling films, similar to those shown in Figure 11. Air and the desiccant solution were separated by selective permeable membrane. ...
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... 2015) developed foil-like membranes for dehumidification processes as shown in Figure 17. This metal foil-like membrane consists of a paper-thin, porous metal sheet coated with a layer of water-loving molecules. ...

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