Publications (2)12.34 Total impact
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Article: The fluorine gauche effect. Langmuir isotherms report the relative conformational stability of (+/-)-erythro- and (+/-)-threo-9,10-difluorostearic acids.
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ABSTRACT: (+/-)-Erythro- and (+/-)-threo-9,10-difluorostearic acids, which differ only by a stereogenic interconversion of a single C-F bond, have significantly different conformational stabilities.Chemical Communications 07/2002; · 6.17 Impact Factor -
Article: Extreme enantiomeric discrimination of fluoroalkanes using deuterium NMR in chiral liquid crystalline media.
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ABSTRACT: The enantiomeric assay of fluoroalkanes using 2H-NMR in a chiral liquid crystalline medium is demonstrated, and at its limit the enantiomers of [5-(2)H]-5-fluorodecane were successfully resolved.Chemical Communications 05/2002; · 6.17 Impact Factor
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Institutions
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2002
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University of St Andrews
- Centre for Biomolecular Sciences
Saint Andrews, SCT, United Kingdom
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