E. W. Collings

The Ohio State University, Columbus, Ohio, United States

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Publications (301)387.37 Total impact

  • G.Z. Li, M.D. Sumption, E.W. Collings
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    ABSTRACT: Significantly enhanced critical current density (Jc) for MgB2 superconducting wires can be obtained following the advanced internal Mg infiltration (AIMI) route. But unless suitable precautions are taken, the AIMI-processed MgB2 wires will exhibit incomplete MgB2 layer formation, i.e. reduced superconductor core size and hence suppressed current-carrying capability. Microstructural characterization of AIMI MgB2 wires before and after the heat treatment reveals that the reaction mechanism changes from a “Mg infiltration-reaction” at the beginning of the heat treatment to a “Mg diffusion-reaction” once a dense MgB2 layer is formed. A drastic drop in the Mg transport rate from infiltration to diffusion causes the termination of the MgB2 core growth. To quantify this process, a two-stage kinetic model is built to describe the MgB2 layer formation and growth. The derived kinetic model and the associated experimental observations indicate that fully reacted AIMI-processed MgB2 wires can be achieved following the optimization of B particle size, B powder packing density, MgB2 reaction activation energy and its response to the additions of dopants.
    Acta Materialia 09/2015; 96. DOI:10.1016/j.actamat.2015.06.013 · 3.94 Impact Factor
  • M Majoros, M D Sumption, E W Collings, N J Long
    Superconductor Science and Technology 08/2015; 28(8). DOI:10.1088/0953-2048/28/8/089601 · 2.80 Impact Factor
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    G Z Li, ⇑ Sumption, E W Collings
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    ABSTRACT: Significantly enhanced critical current density (J c) for MgB 2 superconducting wires can be obtained following the advanced internal Mg infiltration (AIMI) route. But unless suitable precautions are taken, the AIMI-processed MgB 2 wires will exhibit incomplete MgB 2 layer formation, i.e. reduced superconduc-tor core size and hence suppressed current-carrying capability. Microstructural characterization of AIMI MgB 2 wires before and after the heat treatment reveals that the reaction mechanism changes from a ''Mg infiltration-reaction'' at the beginning of the heat treatment to a ''Mg diffusion-reaction'' once a dense MgB 2 layer is formed. A drastic drop in the Mg transport rate from infiltration to diffusion causes the termination of the MgB 2 core growth. To quantify this process, a two-stage kinetic model is built to describe the MgB 2 layer formation and growth. The derived kinetic model and the associated experimental observations indicate that fully reacted AIMI-processed MgB 2 wires can be achieved following the optimization of B particle size, B powder packing density, MgB 2 reaction activation energy and its response to the additions of dopants.
    Acta Materialia 06/2015; 96:66-71. · 3.94 Impact Factor
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    IEEE Transactions on Applied Superconductivity 06/2015; 25(3):1-6. DOI:10.1109/TASC.2014.2385932 · 1.32 Impact Factor
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    X. Xu, M. Majoros, M.D. Sumption, E.W. Collings
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    ABSTRACT: For many accelerator magnets field quality at the bore is a critical requirement for which reason it is necessary to fully characterize the persistent-current magnetization of strands of the kind under consideration for these magnets. The magnetization of a strand is generally measured in a magnetometer. However, certain effects can differentiate such measurements from the true magnetizations of strands in magnets. This report focuses on persistent-current magnetization: 1) measured by vibrating-sample magnetometer on segments of strand extracted from a section of heat treated $hbox{Nb}_{3}hbox{Sn} $ cable as functions of angle of the applied field, and 2) calculated as function of applied transport current. It is found that the magnetization of a strand in a cable increases by $sim$10% as the field applied to the cable is shifted from edge-on to face-on, and that the difference between the current-on and current-off magnetizations is not significant until close to the operational field of a magnet.
    IEEE Transactions on Applied Superconductivity 06/2015; 25(3):1-4. DOI:10.1109/TASC.2014.2375818 · 1.32 Impact Factor
  • IEEE Transactions on Applied Superconductivity 06/2015; 25(3):1-1. DOI:10.1109/TASC.2015.2390628 · 1.32 Impact Factor
  • M Majoros, M D Sumption, E W Collings, N J Long
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    ABSTRACT: A Roebel cable, one twist pitch long, was modified from its as-received state by soldering copper strips between the strands to provide inter-strand connections enabling current sharing. Various DC transport currents (representing different percentages of its critical current) were applied to a single strand of such a modified cable at 77 K in a liquid nitrogen bath. Simultaneous monitoring of I–V curves in different parts of the strand as well as in its interconnections with other strands was made using a number of sensitive Keithley nanovoltmeters in combination with a multi-channel high-speed data acquisition card, all controlled via LabView software. Current sharing onset was observed at about 1.02 of strand I c. At a strand current of 1.3I c about 5% of the current was shared through the copper strip interconnections. A finite element method modeling was performed to estimate the inter-strand resistivities required to enable different levels of current sharing. The relative contributions of coupling and hysteretic magnetization (and loss) were compared, and for our cable and tape geometry, and at dB/dt = 1 T s−1, and our inter-strand resistance of 0.77 mΩ, (enabling a current sharing of 5% at 1.3I c ) the coupling component was 0.32% of the hysteretic component. However, inter-strand contact resistance values of 100–1000 times smaller (close to those of NbTi and Nb3Sn based accelerator cables) would make the coupling components comparable in size to the hysteretic components.
    Superconductor Science and Technology 05/2015; 28(5). DOI:10.1088/0953-2048/28/5/055010 · 2.80 Impact Factor
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    ABSTRACT: Described are the results of magnetization loss measurements made at 77 K on several YBCO conductor-on-round-core (CORC) cables in ac magnetic fields of up to 80 mT in amplitude and frequencies of 50 to 200 Hz, applied perpendicular to the cable axis. The cables contained up to 40 tapes that were wound in as many as 13 layers. Measurements on the cables with different configurations were made as functions of applied ac field amplitude and frequency to determine the effects of their layout on ac loss. In large scale devices such as e.g. Superconducting Magnetic Energy Storage (SMES) magnets, the observed ac losses represent less than 0.1% of their stored energy.
    Superconductor Science and Technology 12/2014; 27(12). DOI:10.1088/0953-2048/27/12/125008 · 2.80 Impact Factor
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    ABSTRACT: A series of MgB2 superconducting composite strands co-doped with Dy2O3 and C were prepared via an advanced internal Mg infiltration (AIMI) route. The transport properties and MgB2 layer growth were studied in terms of the Dy2O3 doping level, reaction temperature, and reaction time. Transport studies showed that both critical current densities, Jcs, and irreversibility fields, Birrs, were increased with Dy2O3 doping. The highest layer Jc was 1.35 × 10^5 A/cm2 at 4.2 K, 10 T, 30 % higher than that of the best AIMI wires without Dy2O3 doping. The highest “non-barrier” Jc reached 3.6 × 10^4 A/cm2 at 4.2 K, 10 T, which was among the best results reported so far. The improvements were even more pronounced at higher temperatures where the field at which the layer Jc reached 10^4 A/cm2 was pushed out by 0.9 T at 20 K, 1.2 T at 25 K, and 1.4 T at 30 K. While little or no enhancement in Birr was seen at 10 K and 15 K, the increases in Jc at higher temperatures were consistent with observed increases in Birr of 17% at 20 K, 44% at 25 K, and 400% at 30 K. Also, there were some indications that the reaction and layer growth of MgB2 was enhanced by Dy2O3 doping.
    Applied Physics Letters 09/2014; 105(11):112603. DOI:10.1063/1.4896259 · 3.52 Impact Factor
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    X Xu, M D Sumption, E W Collings
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    ABSTRACT: The impacts of heat treatment (HT) temperature and Ti doping on low-field flux jumping and 12 T Jc of high-performance internal-Sn, distributed barrier (Nb-Ta)3Sn strands have been explored. It was found that higher HT temperatures could suppress low-field flux jumps by not only reducing the Jc (B) curve slope, but also increasing the heat capacity and decreasing the dJc /dT. A metric, Jc,3 T/Jc,12 T (the ratio of 3 T to 12 T Jc ), was used to describe the slope of the Jc (B) curve. In addition, an analytical equation was derived to predict the amplitude of a flux jump. The Jc (B) curves were further analyzed in the form of Kramer plots to extract the irreversibility field, Birr, and the maximum bulk pinning forces, Fp,max. The variations of Birr, Fp,max and grain size, d, with HT and Ti doping were also analyzed. Fp,max initially increasing linearly with 1/d, saturated at small values of d, possibly because the grains became columnar.
    Superconductor Science and Technology 08/2014; 27(9):095009. DOI:10.1088/0953-2048/27/9/095009 · 2.80 Impact Factor
  • M A Susner, M D Sumption, A Takase, E W Collings
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    ABSTRACT: In an investigation of possible atomic substitution for the Mg site in MgB2, superconducting thin films were deposited by pulsed laser deposition using MgB2 and ZrB2 targets. The resulting c-axis-oriented thin films contained various concentrations of Zr. The structural, chemical, and superconductive properties of these films were investigated. ZrB2 additions were found to increase the a lattice parameter; STEM-based chemical analysis showed Zr to be present within the grains. The superconducting critical temperature was suppressed for the heavily-doped samples. These observations are strong evidence for the substitution of Zr for Mg in the Mg sublattice of MgB2.
    Superconductor Science and Technology 06/2014; 27(7):075009. DOI:10.1088/0953-2048/27/7/075009 · 2.80 Impact Factor
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    ABSTRACT: A dc transport current was applied to the strands of a Roebel cable at 77 K in liquid nitrogen bath. The inter-strand contact resistance was measured. It was modified either by applying a pressure on the cable at 77 K in liquid nitrogen bath or using different soldering patterns between the strands of the cable. Magnetization ac losses were measured in frequency range 50-200 Hz in applied magnetic field 4-70 mT perpendicular to the broader face of the cable to test the inter-strand contact resistance effect. High stability and very low level of coupling losses were observed in the cables even with the lowest inter-strand resistances.
    IEEE Transactions on Applied Superconductivity 06/2014; 24(3):1-5. DOI:10.1109/TASC.2013.2283472 · 1.32 Impact Factor
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    ABSTRACT: A series of high-performing continuous-tube-filling-forming-fabricated (CTFF) powder-in-tube-type (PIT) MgB2 strands have been prepared, with critical current densities, Jcs, higher than 1.30×105 A/cm2 and n-values above 30 at 4.2 K, 5 T. The transport Jcs and corresponding n-values of a selected sample C1 were reported at temperatures, T, of 4.2-30 K and magnetic fields, B, of 0-12 T. The Jc - B data were fitted by Eisterer's percolation model and the temperature dependences of the fitting parameters were analyzed. The n - Jc curves showed a power law relationship n∞Jcm, also previously observed in state-of-the-art monocore MgB2 wires. Further analysis revealed that, like monofilamentary wires, the n(B, T) of this multifilamentary strand can also be estimated for all B and T based on the results of transport voltage-current (V- I) measurements made at one arbitrarily chosen temperature.
    IEEE Transactions on Applied Superconductivity 06/2014; 24(3):1-5. DOI:10.1109/TASC.2013.2288915 · 1.32 Impact Factor
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    ABSTRACT: One of the goals of the Large Hadron Collider Accelerator Research Program (LARP) is to demonstrate the feasibility of Nb3Sn technology for a proposed luminosity upgrade based on large aperture high gradient quadrupole (HQ) magnets. For such magnets, field quality at the bore is a critical requirement for which reason the parasitic magnetization of the windings must be reduced to manageable limits. In other words, it is necessary to minimize 1) the static intrastrand persistent-current magnetization of the cable and 2) the cable's coupling magnetization caused by coupling currents passing through interstrand contact resistance during field ramping. This report focuses on persistent-current magnetization as measured by vibrating-sample magnetometry on pieces of strand removed from a section of heat treated HQ cable.
    IEEE Transactions on Applied Superconductivity 06/2014; 24(3):1-5. DOI:10.1109/TASC.2013.2286860 · 1.32 Impact Factor
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    ABSTRACT: In this paper, we report the properties of two tube type Ta doped Nb3Sn strands: one strand was additionally Ti doped by way of a Sn-Ti alloy core, and the other had high Cu/Sn ratio within the filaments. Higher irreversibility field (Birr) was obtained on the quaternary strand with respect to the (Nb-7.5 wt.%Ta)3Sn strand. High Cu/Sn ratio decreased the amount of coarse grain formation, but also degraded the layer Jc of the tube type strand by depressing the Sn content in the fine grain (FG) layer. A new type of strand, the subelement of which is composed of seven bare Cu-Sn cored Nb tube filaments, was designed with the aim to reduce the unreacted Nb area fractions. The test results of the first experimental strand are reported. The unreacted Nb ratio is reduced relative to normal tube type strands and the FG area fraction is improved. The unique structure of this strand makes it also possible to improve the stoichiometry of FG and reduce the effective diameter (deff) .
    IEEE Transactions on Applied Superconductivity 06/2014; 24(3):1-4. DOI:10.1109/TASC.2013.2291159 · 1.32 Impact Factor
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    ABSTRACT: We have used high-pressure, high-temperature synthesis at 1500-1700 °C and 10 MPa to create homogeneously C-substituted MgB2 from a B4C + Mg mixture. X-ray diffraction analysis showed large peak-shifts consistent with a decrease in the a lattice parameter for the B4C-derived MgB2 as compared to an undoped sample (0.033-0.037 Å, depending on the sample). Microstructural investigation showed a three-phase mixture in the B4C-derived ingots: MgB2-xCx (with 0.178 < x < 0.195), MgB2C2, and Mg. The carbon concentration determined from the lattice parameter shift (5.95 at. %) matched well with the calorimetrically derived concentration of 5.3-5.8 at. % C. Furthermore, the carbon content measured by electron probe micro-analysis was shown to be 6.2 ± 1.3 at. %. Finally, we performed bulk specific heat measurements to determine the homogeneity of C-doping in the MgB2. The width of the Tc distribution for the C-doped MgB2 was only 3-6 K with a full-width half maximum (FWHM) of 1.4 K, compared to a width of 2.5 K and a FWHM of 0.65 for an undoped sample. The consistency of these three measurements on a large-grained homogeneous material is unambiguously supportive of C-substitution.
    Applied Physics Letters 03/2014; 104(16). DOI:10.1063/1.4871578 · 3.52 Impact Factor
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    X. Xu, M. Sumption, X. Peng, E. W. Collings
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    ABSTRACT: In this letter we demonstrate that if oxygen can be properly supplied to (Nb-Zr)-Sn wires, ZrO2 precipitates will form during the heat treatment, refining the Nb3Sn grain size markedly. Here, a Nb3Sn subelement was fabricated in which Nb-1Zr alloy was used, and oxygen was supplied via SnO2 powder. The results showed that such a design could supply sufficient oxygen to internally oxidize the Zr in the Nb-1Zr alloy, and that the sample reacted at 650 {\deg}C had grain sizes of ~45 nm, less than half the size of the grains in present Nb3Sn conductors. Magnetic measurements showed that the peak of the pinning force vs. field (Fp-B) curve was shifted to ~0.3Birr (the irreversibility field).
    Applied Physics Letters 02/2014; 104(8). DOI:10.1063/1.4866865 · 3.52 Impact Factor
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    ABSTRACT: We have studied thermodynamic phase stability in the Mg–B system through use of a high-pressure, high-temperature apparatus consisting of a large pressure vessel and an RF induction heater. The incongruent melting temperature for MgB2 was found to be ∼1450 °C at 10 MPa using thermal analysis data applied to both MgB2 powder samples and Mg/B mixtures. The experimental temperature is ∼300 °C lower than temperatures shown in calculated phase diagrams of the Mg–B system at the same pressure and the discrepancy demonstrates the need for further experimental investigations of phase stability in binary Mg–B and ternary Mg–B–X systems. In this study C (as an impurity in boron) was found to have a large effect on the peritectic temperature, with a relatively small (0.7 wt% C) impurity concentration resulting in a ∼40 °C elevation of the peritectic temperature. Along with morphological characterization, XRD and EPMA analyses were used to identify phases and confirm the peritectic transformation in the Mg–B phase diagram.
    Thermochimica Acta 01/2014; 576:27–35. DOI:10.1016/j.tca.2013.11.027 · 2.11 Impact Factor
  • IEEE Transactions on Applied Superconductivity 01/2014; DOI:10.1109/TASC.2014.2372614 · 1.32 Impact Factor

Publication Stats

2k Citations
387.37 Total Impact Points

Institutions

  • 1992–2014
    • The Ohio State University
      • Department of Materials Science and Engineering
      Columbus, Ohio, United States
  • 2007
    • University of Cambridge
      Cambridge, England, United Kingdom
    • University of Wollongong
      • Institute for Superconducting and Electronic Materials
      Wollongong, New South Wales, Australia
  • 2005–2007
    • Kagoshima University
      Kagosima, Kagoshima, Japan
  • 2001
    • Lawrence Berkeley National Laboratory
      • Nuclear Science Division
      Berkeley, California, United States
  • 1997
    • Tokai University
      Hiratuka, Kanagawa, Japan
  • 1995
    • Universiteit Twente
      Enschede, Overijssel, Netherlands
  • 1968–1995
    • Battelle Memorial Institute
      • Department of Physics
      Columbus, Ohio, United States
  • 1969–1991
    • Iowa State University
      Ames, Iowa, United States
  • 1972–1976
    • Wichita State University
      Wichita, Kansas, United States