[Show abstract][Hide abstract] ABSTRACT: Two new green fluorescence poly(propyleneamine) dendrimers from second generation, comprising eight 1,8-naphthalimide signaling units in their periphery have been synthesized and investigated. Тheir photophysical characteristics have been determined in organic solvents of different polarity. Particular attention has been paid to the spectral characteristics of the solid dendrimer films. The photostability of the dendrimers has also been studied.
[Show abstract][Hide abstract] ABSTRACT: The synthesis of two polyconjugated graft copolymers based on a poly(fluorene-phenylene) backbone and polystyrene side chains is described here. The two different approaches followed, ATRP growth of side chains from a preformed conjugated backbone and “click” connection of well-defined polymeric chains to the backbone, led to different results in terms of solubility and material properties. While the ATRP method seems to be responsible of a partially cross-linked and nonsoluble copolymer, the “click” approach provides a graft copolymer, which is completely soluble, showing atypical spectroscopic properties that are here elucidated.
[Show abstract][Hide abstract] ABSTRACT: A dipyrromethane functionalized monomer; 5-(4-tert-butylphenyl)dipyrromethane (BPDP) was synthesized. The structure of the monomer was characterized by nuclear magnetic resonance (1H NMR and 13C NMR) and Fourier transform infrared (FTIR) spectroscopies. Electrochemical polymerization of BPDP was performed in acetonitrile (AN)/LiClO4. The resulting conducting polymer was characterized by FTIR spectroscopy and electrical conductivity measurements. Spectroelectrochemical behavior and switching ability of P(BPDP) film were investigated by UV–Vis spectroscopy. P(BPDP) revealed color changes between yellow and blue in the reduced and oxidized states, respectively. In order to investigate electrochromic properties and stability of the P(BPDP) in electrochromic device (ECDs) application, dual type polymer ECD based on P(BPDP) and poly(ethylene dioxythiophene) (PEDOT) were constructed. Spectroelectrochemistry, switching ability and stability of the devices were investigated by UV–Vis spectroscopy and cyclic voltammetry.
European Polymer Journal 08/2008; 44(8):2567-2573. DOI:10.1016/j.eurpolymj.2008.06.027 · 3.24 Impact Factor
[Show abstract][Hide abstract] ABSTRACT: Polyaniline (PANI) nanotubes were prepared by oxidative polymerization of aniline in the presence of two structure-directing
agents—salicylic acid (SA) and sodium dodecyl sulfate (SDS). When using only SA, mainly aggregated nanotube dendrites or coral-like
structures have been obtained. Addition of a very small amount of the surfactant SDS, much less than the critical micelle
concentration, results in substantial reduction of the aggregated nanotube morphology on the account of isolated PANI nanotubes,
which is the favorable structure from the point of view of further modification. In order to make the isolated nanotubes water
dispersible, their surface was modified by complex formation (non-covalent grafting) with hydrophilic poly(ethylene oxide)-block-poly(acrylic acid) copolymer. These water-dispersible PANI nanotubes might be good candidates for some biochemical and biomedical
[Show abstract][Hide abstract] ABSTRACT: The positron lifetime spectroscopy (PLS), a non-destructive characterization method, utilizes positronium (Ps; an electron–positron bound state) as a probe and measures its lifetime in polymer free volumes. For the first time the free volumes have been estimated by PLS in polyaniline (PANI) complexes with various inorganic and organic acids. It was found that the o-Ps lifetime increases and the intensity decreases with increasing ionic radius of the counter-ions in PANI complexes. Obviously, larger counter anions result in enhanced mean size of the voids corresponding to the free volume in the bulk polymer.Electrical conductivity has been measured by conventional four-probe technique. The glass transition temperature and temperature of removal of the absorbed water have been determined by using differential scanning calorimetry. It was established fairly well correlation of the mentioned polymer parameters with the o-Ps lifetime and the free volume of PANI complexes, respectively. The greater free-volume results in a decrease of conductivity, glass transition temperature and temperature of removal of the absorbed water.
[Show abstract][Hide abstract] ABSTRACT: The electrical conductivity behavior of polyaniline–poly(ethylene‐co‐vinyl acetate) (PANI–EVA) blends was variable and dynamic during their storage. It was shown that the apparent concentration of the intrinsically conductive polymer at which a conductivity jump of the blends occurs (Φc) is not a constant value over time. The electrical conductivity of the films of low PANI content (below 2.5 wt.%) increased by several (ca. 5) orders of magnitude. It was found that the PANI phase undergoes a flocculation process subsequently resulting in the formation of conductive pathways and a continuous network. Besides, the shape of percolation curves was found to change during storage of the films. Decreased conductivity deviations were registered for blends of low PANI content (
Journal of Macromolecular Science Part C Polymer Reviews 08/2007; 44(4):311-350. DOI:10.1081/MC-200033680 · 3.77 Impact Factor
[Show abstract][Hide abstract] ABSTRACT: The melting behavior of solid-state chlorinated polyethylene
samples of various average molar mass has been studied by employing the differential
scanning calorimetry method. Both the thermal and thermodynamic characteristics
of the as-prepared chlorinated powdery polymer samples were found to be essentially
different, compared to those of the melt-crystallized ones. The changes in
the corresponding values depended mainly on the content of the comonomer units
such as chloromethylene and dichloromethylene groups and their distribution
along the polymer chains. Therefore, it can be assumed that the order of the
polymer crystals arrangement is disturbed in the course of both the chlorination
process and the subsequent melt crystallization.
Journal of Thermal Analysis and Calorimetry 08/2006; 85(2). DOI:10.1007/s10973-005-7296-1 · 2.21 Impact Factor
[Show abstract][Hide abstract] ABSTRACT: Summary Electrically conductive composites containing high density polyethylene (HDPE) and polyaniline (PANI) - dodecylbenzenesulfonic acid (DBSA) complex were prepared in situ by bulk oxidative polymerization of aniline (ANI) in presence of DBSA. Their thermal behaviour and crystallinity parameters were studied for the first time by using differential scanning calorimetry (DSC). It was found that the presence of the conductive complex does not affect the crystalline structure of the matrix polymer neither during in situ polymerization of ANI in powdered HDPE nor upon heating of HDPE/PANI·DBSA composite up to 180°C followed by fast cooling.
Journal of Thermal Analysis and Calorimetry 07/2005; 81(1):3-8. DOI:10.1007/s10973-005-0736-0 · 2.21 Impact Factor
[Show abstract][Hide abstract] ABSTRACT: Crystallinity parameters and changes in the crystalline morphology with temperature of an electrically conductive composite containing ultrahigh molecular mass polyethylene (UHMMPE) and polyaniline (PANI) doped with dodecylbenzenesulfonic acid (DBSA) are studied for the first time by using differential scanning calorimetry and wide-angle X-ray diffraction. It is found that during the melting of UHMMPE crystals PANI partially penetrates in the amorphous phase of the matrix polymer. Since the composite is found to be thermally stable up to ca. 270°C, it can be suggested that it would be processable without loosing conductivity at temperatures much higher than the melting temperature of UHMMPE.
Journal of Thermal Analysis and Calorimetry 01/2004; 75(3). DOI:10.1023/B:JTAN.0000027170.83289.f2 · 1.60 Impact Factor
[Show abstract][Hide abstract] ABSTRACT: Statistical copolymers of styrene and acrylonitrile, covering a wide range of compositions, were synthetized by emulsion polymerization conducted to both low and high conversion. The weight-average molecular weights of the copolymers were determined by light scattering and correlated with intrinsic viscosities measured in methyl ethyl ketone and/or dimethyl formamide solutions. The copolymers polymerized in emulsion are suggested to consist of macromolecules with long chain branching.Statistische Styren-Acrylnitril-Copolymere wurden durch Emulsionspolymerisation in einem breiten Bereich der Zusammensetzung sowohl bei niedrigen als auch bei hohen Umsätzen hergestellt. Die Massenmittel der relativen Molekülmassen der Copolymere wurden mittels Lichtstreuung ermittelt und mit den in Methylethylketon- bzw. Dimethylformamid-Lösungen gemessenen Grenzviskositätszahlen in Beziehung gebracht. Es wird gefolgert, daß die in Emulsion polymerisierten Copolymere aus Makromolekülen mit Langkettenverzweigungen bestehen.
[Show abstract][Hide abstract] ABSTRACT: Polyaniline (PAni) coatings are synthesized polymerizing aniline chemically, by oxidation in presence of (NH4)2S2O8, and electrochemically, by using a pulse potentiostatic procedure. Both types of PAni coatings are compared with respect to their potentiodynamic behavior, electrochemical stability and surface morphology. Additional comparison is made by investigating the electrocrystallisation of copper. The chemically and electrochemically PAni coatings exhibit different surface morphologies but nevertheless show identical redox behavior and stability with respect to multiple cycling. The different PAni morphologies have a marked influence on the metal crystallization process, the chemical coatings allowing for an easier copper nucleation and growth.
Thin Solid Films 01/2003; 441(1):44-49. · 2.13 Impact Factor
[Show abstract][Hide abstract] ABSTRACT: The long-term environmental ageing of conductive composite films containing ethylene-co-vinyl-acetate (EVA) copolymer and
a complex of polyaniline (PANI) and dodecylbenzenesulfonic acid (DBSA) was studied by using differential scanning calorimetry
(DSC). We assume that both phase separation and crosslinking of PANI main chains occur in the systems. On the other hand,
the competition between PANI–DBSA complex self-organization and crystallization of EVA matrix result in structural changes
and formation of continuous conductive network, responsible for significantly increased (ca five orders of magnitude) electrical
conductivity of the aged films.
Journal of Thermal Analysis and Calorimetry 01/2002; 68(1):159-168. DOI:10.1023/A:1014949021329 · 2.21 Impact Factor
[Show abstract][Hide abstract] ABSTRACT: Thermostability and structure transformations upon heating of composite systems consisting of a microporous polyethylene film and a conducting polyaniline (PANI) layer have been investigated by thermogravimetry (TG), differential thermal analysis (DTA), differential scanning calorimetry (DSC), and wide-angle X-ray scattering (WAXS). Microporous polyethylene films were prepared by melt extrusion with subsequent annealing, uniaxial extension, and thermofixation. Polyaniline layers were formed by polymerizing aniline from solution in situ or by deposition of colloidal polyaniline dispersion on the polyethylene film surface. Composite systems have been found to demonstrate a considerably lower shrinkage upon heating than microporous polyethylene substrates. It has been discovered from DTA, DSC, and WAXS data that oriented phases in the polyethylene melt are formed in composite systems at melting temperature of polyethylene support. Oriented state in polyethylene melt is maintained at heating of composite samples up to the temperatures exceeding polyethylene melting point at several tens degrees.
[Show abstract][Hide abstract] ABSTRACT: A structural study of conductive composite films consisting of ethylene-co-vinylacetate (EVA) copolymer, polyaniline (PANI)
and dodecylbenzenesulfonic acid (DBSA), a part of which being complexed with PANI, was performed by using differential scanning
calorimetry (DSC) and presented for the first time. An additional crystalline phase is formed during the film formation by
thickening EVA chain-folded lamellae with participation of‘free’ DBSA molecules at lower net PANI content (up to 5 mass%)
and of both ‘free’ and complexed DBSA molecules (up to 7.5 mass%). At higher PANI content PANI-DBSA complex starts to form
its own crystals and at 17.5 mass% of PANI mixed crystals of EVA with ‘free’ DBSA alkyl chains are preferably formed. It is
also found that the Fox' equation correlating the glass transition temperature of a miscible blend system with its composition
can be actually used in estimating the miscibility of EVA/PANI blends no matter the presence of DBSA.
Journal of Thermal Analysis and Calorimetry 01/2001; 66(2):415-422. DOI:10.1023/A:1013182532152 · 2.21 Impact Factor