-
[show abstract]
[hide abstract]
ABSTRACT: Nanoscale particles of the general formula MFe<sub>2</sub>O<sub>4
</sub> (M=Co, Mn, Fe) were synthesized in reverse micelles of
twin-tailed anionic bis(2-ethylhexyl) sodium sulfosuccinate (AOT) in
isooctane. The size of the particles was controlled by adjusting the
AOT/water molar ratio. Particle sizes were confirmed using XRD and
uniformity was determined by SEM. Magnetic measurements, carried out
using a SQUID Susceptometer, indicated superparamagnetic behavior. FC
and ZFC demagnetization experiments indicate blocking temperatures of 46
K, 30 K, and 7 K for for MFe<sub>2</sub>O<sub>4</sub> M=Co, Mn, Fe
respectively. Below blocking temperatures, the nanoparticles demonstrate
hysteresis with coercivities of H<sub>c</sub>=6000G, 3800G, and 500G for
the Co, Mn, and Fe ferrites
IEEE Transactions on Magnetics 08/1998; · 1.36 Impact Factor
-
[show abstract]
[hide abstract]
ABSTRACT: Magnetic and magnetotransport properties have been studied in
nanocomposites (EuS)-Co and (EuS)-Ag prepared by mechanical alloying.
For (EuS)<sub>70</sub>Co<sub>30</sub>, the large negative
magnetoresistance (~50%) found at 20 K, just above the Curie temperature
(T<sub>c</sub>) of EuS, arises from the suppression of spin fluctuation
in EuS. Below T<sub>c</sub>, the positive magnetoresistance (~15%),
which is uncharacteristic of ferromagnetic semiconductors, is probably
due to defect-induced magnetic fluctuation. On the other hand,
(EuS)<sub>70</sub>Ag<sub>30</sub>, where nonmagnetic silver replaces
cobalt, exhibits negative magnetoresistance below T<sub>c</sub>, which
is possibly related to the spin dependent scattering commonly seen in
GMR materials. While (EuS)<sub>70</sub>Co<sub>30</sub> shows
semiconducting conductivity, (EuS)<sub>70</sub>Ag<sub>30</sub> is
metallic. Reentrant spin glass behavior has been observed in EuS-Ag
system, where the rise of antiferromagnetic coupling is due to the
defects and disorder caused by mechanical milling
IEEE Transactions on Magnetics 08/1998; · 1.36 Impact Factor
-
MMM-Intermag Conference, 1998. Abstracts., The 7th Joint; 02/1998