E. Gayon

Publications (3)6.97 Total impact

• Article: Gold catalyzed propargylic substitutions: Scope and synthetic developments

  O. Debleds, E. Gayon, E. Vrancken, J.M. Campagne
  [show abstract] [hide abstract]
  ABSTRACT: This personal account summarizes our recent developments in gold-catalyzed direct substitutions on propargylic (allylic, benzylic) alcohols, with various nucleophiles (and bi-nucleophiles) based on the σ- and/or π-acidity of gold(III) complexes. Synthetic developments are also briefly described.
  Beilstein Journal of Organic Chemistry 01/2011; 7:866. · 2.52 Impact Factor
• Article: AVersatile Iron-Catalyzed Protocol for the One-Pot Synthesis of Isoxazoles or Isoxazolines from the Same Propargylic Alcohols

  O. Debleds, E. Gayon, E. Ostaszuk, E. Vrancken, J.M. Campagne
  [show abstract] [hide abstract]
  ABSTRACT: The use N-sulfonyl-protected hydroxylamines as bi-nucleophiles in iron-catalyzed propargylic substitutions allows the selective one-pot synthesis of four classes of substituted isoxazoles or isoxazolines from the same propargylic alcohols (21 examples) by simply tuning the nature of the base.
  Chemistry - A European Journal. 01/2010; 16:12207.
• Article: Highly Diastereoselective Baldwin Rearrangement of Isoxazolines into cis-Acylaziridines

  E. Gayon, O.Debleds, M. Nicouleau, F.Lamaty, A. van der Lee, E. Vrancken, J.M. Campagne
  The Journal of Organic Chemistry 01/2010; 75:6050. · 4.45 Impact Factor