P Salén, P van der Meulen,
H T Schmidt,
R D Thomas,
M Larsson,
R Feifel,
M N Piancastelli,
L Fang,
B Murphy,
T Osipov,
N Berrah,
E Kukk,
K Ueda,
J D Bozek,
C Bostedt,
S Wada,
R Richter,
V Feyer,
K C Prince
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ABSTRACT: We have performed x-ray two-photon photoelectron spectroscopy using the Linac Coherent Light Source x-ray free-electron laser in order to study double core-hole (DCH) states of CO2, N2O, and N2. The experiment verifies the theory behind the chemical sensitivity of two-site DCH states by comparing a set of small molecules with respect to the energy shift of the two-site DCH state and by extracting the relevant parameters from this shift.
Physical Review Letters 04/2012; 108(15):153003. · 7.37 Impact Factor