Publications (2)8.02 Total impact
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Article: Pt/graphene-CNTs nanocomposite based electrochemical sensors for the determination of endocrine disruptor bisphenol A in thermal printing papers.
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ABSTRACT: A facile and green method was developed to synthesize the graphene-carbon nanotubes (Gr-CNTs) nanocomposite with a sandwich lamination structure. Pt nanoparticles were loaded on the as-synthesized Gr-CNTs nanocomposite to prepare an electrochemical sensor for determining bisphenol A (BPA) in thermal printing paper. The electrochemical behavior of BPA on the Pt/Gr-CNTs nanocomposite was investigated by cyclic voltammetry (CV) and chronocoulometry (CC). The direct determination of BPA was accomplished by using differential pulse voltammetry (DPV) under optimized conditions. The oxidation peak current was proportional to the BPA concentration in the range from 6.0 × 10(-8) to 1.0 × 10(-5) M and 1.0 × 10(-5) to 8.0 × 10(-5) M with a correlation coefficient of 0.987 and 0.998, respectively. The detection limit was 4.2 × 10(-8) M (S/N = 3). The fabricated electrode showed good reproducibility, stability and selectivity. The proposed method was successfully applied to determine BPA in thermal printing papers samples and the results were satisfactory.The Analyst 11/2012; · 4.23 Impact Factor -
Article: Simultaneous electrochemical determination of uric acid, xanthine and hypoxanthine based on poly(L-arginine)/graphene composite film modified electrode.
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ABSTRACT: Poly(l-arginine)/graphene composite film modified electrode was successfully prepared via a facile one-step electrochemical method and used for simultaneous determination of uric acid (UA), xanthine (XA) and hypoxanthine (HX). The electrochemical behaviors of UA, XA and HX at the modified electrode were studied by cyclic voltammetry and differential pulse voltammetry (DPV), and showed that the modified electrode exhibited excellent electrocatalytic activity toward the oxidation of the three compounds. The calibration curves for UA, XA and HX were obtained over the range of 0.10-10.0, 0.10-10.0 and 0.20-20.0 μM by DPV, respectively and the detection limits for UA, XA and HX were 0.05, 0.05 and 0.10 μM (S/N=3), respectively. With good selectivity and high sensitivity, the modified electrode has been applied to simultaneous determination of UA, XA and HX in human urine with satisfactory result.Talanta 05/2012; 93:320-5. · 3.79 Impact Factor