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ABSTRACT: A dual-electrode voltammetric/amperometric detector for flow-injection systems is described. The detector provides qualitative voltammetric information without the charging currents associated with scanning the potential. Selectivity is enhanced relative to direct voltammetric detection at a single electrode because only chemically reversible redox couples are detected. A preliminary evaluation with hexacyanoferrate(III) and ascorbic acid is presented.
Analytica Chimica Acta.