Publications (3)16.17 Total impact
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Article: Cu(II)-promoted transformations of α-thienylcarbinols into spirothienooxindoles: regioselective halogenation of dienyl sulfethers containing electron-rich aryl rings.
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ABSTRACT: Under the promotion of Cu(II) salts, the α-thienylcarbinols with an N-phenyl carbonyl group at the other α-position are converted into three different ranges of spirothienooxindoles involving dearomatizing Friedel-Crafts reaction. In addition, the unprecedented regioselective CuX(2)-mediated C-H functionalization/halogenation of dienyl sulfether containing electron-rich aryl rings is presented.The Journal of Organic Chemistry 06/2012; 77(14):6365-70. · 4.45 Impact Factor -
Article: A novel entry to functionalized benzofurans and indoles via palladium(0)-catalyzed arylative dearomatization of furans.
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ABSTRACT: A novel entry to functionalized benzofurans and indoles from furans in moderate to good yields has been developed. This protocol involves palladium(0)-catalyzed dearomatizing intramolecular arylation of the furan ring, formation of a π-allylic palladium complex, furan ring opening, and a β-hydride elimination sequence.Organic Letters 02/2012; 14(4):1098-101. · 5.86 Impact Factor -
Article: Facile synthesis of 3a,6a-dihydro-furo[2,3-b]furans and polysubstituted furans involving dearomatization of furan ring via electrocyclic ring-closure.
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ABSTRACT: A facile and atom-economic method for the synthesis of 3a,6a-dihydro-furo[2,3-b]furan derivatives and polysubstituted furans starting from furylcarbionls has been developed. This protocol involved a domino Claisen rearrangement/dearomatizing electrocyclic ring-closure/aromatizing electrocyclic ring-opening sequence.Organic Letters 01/2012; 14(2):616-9. · 5.86 Impact Factor
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Institutions
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2012
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South China University of Technology
- Department of Chemical Engineering
Guangzhou, Guangdong Sheng, China
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