Vladimir N Shibaev

Publications (1)2.03 Total impact

• Article: Chemical synthesis of polyprenyl sialyl phosphate, a probable biosynthetic intermediate of bacterial polysialic acid.

  Anna M Shpirt, Leonid O Kononov, Sergey D Maltsev, Vladimir N Shibaev
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  ABSTRACT: Using reaction of moraprenyl phosphate with the known N-acetylsialyl chloride and the novel N,N-diacetylsialyl (Neu5Ac(2)) chloride α- and β-anomers of polyprenyl sialyl phosphate were synthesized for the first time. The α-selectivity dramatically increased when Neu5Ac(2) chloride was used as the glycosyl donor.
  Carbohydrate research 10/2011; 346(18):2849-54. · 2.03 Impact Factor