Publications (1)4.6 Total impact
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Article: Extending the range of neutral N-donor ligands available for metal catalysts: N-[1-alkylpyridin-4(1H)-ylidene]amides in palladium-catalyzed cross-coupling reactions.
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ABSTRACT: N-[1-Alkylpyridin-4(1H)-ylidene]amides (PYAs) are a new class of easily prepared, neutral N-donor ligands that share some features in common with N-heterocyclic carbenes. They are strongly electron-donating toward metal centers, and a palladium(II) complex of one of these ligands has been shown to successfully catalyze both the Heck-Mizoroki and Suzuki-Miyaura cross-coupling reactions.Inorganic Chemistry 09/2011; 50(21):10522-4. · 4.60 Impact Factor
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Institutions
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2011
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University of Auckland
- School of Chemical Sciences
Auckland, Auckland, New Zealand
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