Jiannong Chen

Publications (2)5.79 Total impact

• Article: Synergy of glutathione, dithiothreitol and N-acetyl-L-cysteine self-assembled monolayers for electrochemical assay: sensitive determination of arsenic(III) in environmental and drinking water.

  Lingxin Chen, Na Zhou, Jinhua Li, Zhaopeng Chen, Chunyang Liao, Jiannong Chen
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  ABSTRACT: A simple and efficient electrochemical assay based on self-assembled monolayers (SAMs) was developed for the highly sensitive determination of arsenic(III) in water samples. The synergy of glutathione (GSH), dithiothreitol (DTT) and N-acetyl-L-cysteine (NAC) mixed SAMs enhanced the detection specificity and sensitivity of As(III) in water samples, resulting from the immobilization of a large number of As(III) moieties on the gold electrode surface via As-O and As-S linkages. After accumulating As(III), anodic stripping voltammetry (ASV) was performed, and linear sweep voltammetry (LSV) was employed for signal recording. Several main voltammetric parameters were optimized as follows: supporting electrolyte, 1 mol L(-1) HCl; deposition potential, -0.35 V; deposition time, 150 s. A good linear relationship (R = 0.9980) was attained between the concentration of the As(III) standard and peak current, in the range of 3-100 μg L(-1). The limit of detection (LOD) of this sensing system was determined to be 0.5 μg L(-1) at a signal-to-noise ratio of 3. A variety of common coexistent ions in water samples were examined, showing no obvious interferences on the As(III) determination. The amenability of this method to the analyses of water samples was also investigated. High recovery of 90.5% with the precision of 5.1% at spiked 10 μg L(-1), and low LOD of 0.3 μg L(-1) were obtained in seawater. The synergy effect of GSH, DTT and NAC provided the possibility for the rapid and sensitive LSV determination of As(III) in complicated water samples.
  The Analyst 09/2011; 136(21):4526-32. · 4.23 Impact Factor
• Article: Propagation and transformation of flat-topped multi-Gaussian beams in a general nonsymmetrical apertured double-lens system.

  Jiannong Chen
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  ABSTRACT: On the basis of expanding a hard-edged aperture function as a finite sum of complex Gaussian functions, an approximate analytical expression for the propagation of an input complex amplitude distribution passing through a general nonsymmetrical apertured double-lens system is derived. Then, the propagation result for two-dimensional flat-topped multi-Gaussian beams is given. It is shown that the apertured Lohmann's symmetrical double-lens system for fractional Fourier transform is a special case of the general apertured double-lens system. The numerical calculation, graphical illustration, and some discussions for the transformation of the two-dimensional flat-topped multi-Gaussian beam in apertured Lohmann's symmetrical double-lens systems are also presented.
  Journal of the Optical Society of America A 02/2007; 24(1):84-92. · 1.56 Impact Factor