Odarich Iryna

Publications (1)0 Total impact

• Article: μ-Peroxido-bis[acetonitrilebis(ethylenediamine)cobalt(III)] tetrakis(perchlorate)

  Khrystyna O. Regeta, Odarich Iryna, Svetlana V. Pavlova, Valentina A. Kalibabchuk, Haukka Matti
  [show abstract] [hide abstract]
  ABSTRACT: The title compound, [Co2(O2)(CH3CN)2(C2H8N2)4](ClO4)4, consists of centrosymmetric binuclear cations and perchlorate anions. Two CoIII atoms, which have a slightly distorted octahedral coordination, are connected through a peroxido bridge; the O—O distance is 1.476 (3) Å. Both acetonitrile ligands are situated in a trans position with respect to the O—O bridge. In the crystal, the complex cations are connected by N—H...O hydrogen bonds between ethylendiamine NH groups and O atoms from the perchlorate anions and peroxide O atoms.
  Acta Crystallographica Section E. 01/2010;