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ABSTRACT: In the title zwitterionic compound, C15H19NO2S, the six-membered heterocycle adopts a sofa conformation. The negative charge is delocalized along the carbonyl and enolate system on the ring and the positive charge is localized on the S atom. Two intermolecular C—H...O interactions help to establish the packing.
Acta Crystallographica Section E. 01/2011;
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ABSTRACT: The title compound, C23H17N3O3, has an E configuration with respect to the C=N bond. The dihedral angle between the two phenyl rings bonded to the hydrazine group is 86.45 (13)°. The furan ring makes dihedral angles of 3.4 (2) and 7.06 (13)°, respectively, with the methylidenehydrazine C=N—N plane and the benzene ring.
Acta Crystallographica Section E. 01/2010;
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ABSTRACT: In the crystal structure of the title compound, C26H22N4, the molecule is located on an inversion centre and shows an E configuration with respect to each C=N bond. The dihedral angle between the phenyl rings in the diphenylhydrazone group is 83.69 (11)°. These two rings make dihedral angles of 30.53 (15) and 84.53 (16)° with the central N—N=C—C=N—N dihydrazonoethane plane. Intermolecular C—H...π interactions are observed.
Acta Crystallographica Section E. 01/2010;
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ABSTRACT: In the title compound, C15H20O5S, the tetrahydrofuran ring shows an envelope conformation. The crystal packing is stabilized by an intermolecular O—H...O hydrogen bond, generating a ribbon structure along the a axis. Two weak intermolecular C—H...O interactions are also observed.
Acta Crystallographica Section E. 01/2009;
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ABSTRACT: In the title compound, C21H26N2O3, the morpholine ring has a chair conformation and the dihedral angle between the two phenyl rings is 59.0 (3)°. The crystal packing is stabilized by intermolecular O—H...O hydrogen bonds, generating a ribbon structure along the a axis. An intramolecular N—H...O contact is also present.
Acta Crystallographica Section E. 01/2009;