Publications (1)3.84 Total impact
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Article: Self-induced "electroclick" immobilization of a copper complex onto self-assembled monolayers on a gold electrode.
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ABSTRACT: We report the self-induced "electroclick" immobilization of the [Cu(II)(6-ethynyl-TMPA)(H(2)O)](2+) complex, by its simple electro-reduction, onto a mixed azidoundodecane-/decane-thiol modified gold electrode. The redox response of the grafted [Cu(II/I)(TMPA)] at the modified electrode is fully reversible indicating no Cu coordination change and a fast electron transfer.Dalton Transactions 11/2010; 39(48):11516-8. · 3.84 Impact Factor