M. Reichling

University of Utah, Salt Lake City, UT, United States

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Publications (158)350.81 Total impact

  • [show abstract] [hide abstract]
    ABSTRACT: By the growth of a 180 nm thick film on Si(111), we produce a metastable ceria surface with a morphology dominated by terraced pyramids with an oriented triangular base. Changes in the nanoscale surface morphology and local surface potential due to annealing at temperatures ranging from 300 K to 1150 K in the ultra-high vacuum are studied with non-contact atomic force microscopy and Kelvin probe force microscopy. As the surface is stable in the temperature range of 300 K to 850 K, it is most interesting for applications requiring regular steps with a height of one O-Ce-O triple layer.
    Applied Physics Letters 01/2014; 104(8):081910-081910-4. · 3.79 Impact Factor
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    ABSTRACT: The structural changes of a (111) oriented CeO2 film grown on a Si(111) substrate covered with a hex-Pr2O3(0001) interface layer due to post deposition annealing are investigated. X-ray photoelectron spectroscopy measurements revealing the near surface stoichiometry show that the film reduces continuously upon extended heat treatment. The film is not homogeneously reduced since several coexisting crystalline ceria phases are stabilized due to subsequent annealing at different temperatures as revealed by high resolution low energy electron diffraction and X-ray diffraction. The electron diffraction measurements show that after annealing at 660 °C the ι-phase (Ce7O12) is formed at the surface which exhibits a structure. Furthermore, a surface structure with a stoichiometry close to Ce2O3 is stabilized after annealing at 860 °C which cannot be attributed to any bulk phase of ceria stable at room temperature. In addition, it is shown that the fully reduced ceria (Ce2O3) film exhibits a bixbyite structure. Polycrystalline silicate (CeSixOy) and crystalline silicide (CeSi1.67) are formed at 850 °C and detected at the surface after annealing above 900 °C.
    Physical Chemistry Chemical Physics 09/2013; · 3.83 Impact Factor
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    ABSTRACT: Molecular self-assembly constitutes a versatile strategy for creating functional structures on surfaces. Tuning the subtle balance between intermolecular and molecule-surface interactions allows structure formation to be tailored at the single-molecule level. While metal surfaces usually exhibit interaction strengths in an energy range that favors molecular self-assembly, dielectric surfaces having low surface energies often lack sufficient interactions with adsorbed molecules. As a consequence, application-relevant, bulk insulating materials pose significant challenges when considering them as supporting substrates for molecular self-assembly. Here, the current status of molecular self-assembly on surfaces of wide-bandgap dielectric crystals, investigated under ultrahigh vacuum conditions at room temperature, is reviewed. To address the major issues currently limiting the applicability of molecular self-assembly principles in the case of dielectric surfaces, a systematic discussion of general strategies is provided for anchoring organic molecules to bulk insulating materials.
    Advanced Materials 08/2013; 25(29):3948-56. · 14.83 Impact Factor
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    ABSTRACT: The noise of the frequency-shift signal Δf in noncontact atomic force microscopy (NC-AFM) consists of cantilever thermal noise, tip-surface-interaction noise and instrumental noise from the detection and signal processing systems. We investigate how the displacement-noise spectral density d(z) at the input of the frequency demodulator propagates to the frequency-shift-noise spectral density d(Δ) (f) at the demodulator output in dependence of cantilever properties and settings of the signal processing electronics in the limit of a negligible tip-surface interaction and a measurement under ultrahigh-vacuum conditions. For a quantification of the noise figures, we calibrate the cantilever displacement signal and determine the transfer function of the signal-processing electronics. From the transfer function and the measured d(z), we predict d(Δ) (f) for specific filter settings, a given level of detection-system noise spectral density d(z) (ds) and the cantilever-thermal-noise spectral density d(z) (th). We find an excellent agreement between the calculated and measured values for d(Δ) (f). Furthermore, we demonstrate that thermal noise in d(Δ) (f), defining the ultimate limit in NC-AFM signal detection, can be kept low by a proper choice of the cantilever whereby its Q-factor should be given most attention. A system with a low-noise signal detection and a suitable cantilever, operated with appropriate filter and feedback-loop settings allows room temperature NC-AFM measurements at a low thermal-noise limit with a significant bandwidth.
    Beilstein Journal of Nanotechnology 01/2013; 4:32-44. · 2.37 Impact Factor
  • L Tröger, H H Pieper, M Reichling
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    ABSTRACT: We present the concept for a sample holder designed for mounting and heating of plate-like samples that is based on a clamping mechanism for easy handling. The clamping mechanism consists of a U-shaped bracket encompassing the sample support plate from the rear. Two spring wires are fixed in the walls of the bracket spanning the sample to secure it with only two point contacts. This enables the sample to freely expand or contract during heating and cooling. To accommodate for a large variety in sample size, shape, and quality, we introduce two designs differing in the generation of the clamping force: One pressing the sample against the spring wires, the other one pulling the spring wires onto the sample. Both designs yield an automatically even alignment of the sample during the mounting process to achieve an even load distribution and reliable fixation specifically for brittle samples. For high temperature treatment, the sample holders are enhanced by a resistive heating plate. As only the sample and a small fraction of the sample holder are heated, temperatures of 1300 °C are reached with only 8 W heating power. The sample support and heating components are mounted on a 11 mm × 13 mm base plate with a handle that can be transferred between the sample entry stage, the preparation stage, and surface science experiments in the ultra-high vacuum system.
    The Review of scientific instruments 01/2013; 84(1):013703. · 1.52 Impact Factor
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    ABSTRACT: Twisted few layer graphene (FLG) is highly attractive from an application point of view, due to its extraordinary electronic properties. In order to study its properties, we demonstrate and discuss three different routes to in situ create and identify (twisted) FLG. Single layer graphene (SLG) sheets mechanically exfoliated under ambient conditions on 6H-SiC(0001) are modified by (i) swift heavy ion (SHI) irradiation, (ii) by a force microscope tip and (iii) by severe heating. The resulting surface topography and the surface potential are investigated with non-contact atomic force microscopy (NC-AFM) and Kelvin probe force microscopy (KPFM). SHI irradiation results in rupture of the SLG sheets, thereby creating foldings and bilayer graphene (BLG). Applying the other modification methods creates enlarged (twisted) graphene foldings that show rupture along preferential edges of zigzag and armchair type. Peeling at a folding over an edge different from a low index crystallographic direction can result in twisted BLG, showing a similar height as Bernal (or AA-stacked) BLG in NC-AFM images. The rotational stacking can be identified by a significant contrast in the local contact potential difference (LCPD) measured by KPFM.
    Beilstein Journal of Nanotechnology 01/2013; 4:625-31. · 2.37 Impact Factor
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    ABSTRACT: We critically discuss the extraction of intrinsic cantilever properties, namely eigenfrequency f n , quality factor Q n and specifically the stiffness k n of the nth cantilever oscillation mode from thermal noise by an analysis of the power spectral density of displacement fluctuations of the cantilever in contact with a thermal bath. The practical applicability of this approach is demonstrated for several cantilevers with eigenfrequencies ranging from 50 kHz to 2 MHz. As such an analysis requires a sophisticated spectral analysis, we introduce a new method to determine k n from a spectral analysis of the demodulated oscillation signal of the excited cantilever that can be performed in the frequency range of 10 Hz to 1 kHz regardless of the eigenfrequency of the cantilever. We demonstrate that the latter method is in particular useful for noncontact atomic force microscopy (NC-AFM) where the required simple instrumentation for spectral analysis is available in most experimental systems.
    Beilstein Journal of Nanotechnology 01/2013; 4:227-33. · 2.37 Impact Factor
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    ABSTRACT: The surface morphology of CeO(2)(111) single crystals and silicon supported ceria films is investigated by non-contact atomic force microscopy (NC-AFM) and Kelvin probe force microscopy (KPFM) for various annealing conditions. Annealing bulk samples at 1100 K results in small terraces with rounded ledges and steps with predominantly one O-Ce-O triple layer height while annealing at 1200 K produces well-ordered straight step edges in a hexagonal motif and step bunching. The morphology and topographic details of films are similar, however, films are destroyed upon heating them above 1100 K. KPFM images exhibit uniform terraces on a single crystal surface when the crystal is slowly cooled down, whereas rapid cooling results in a significant inhomogeneity of the surface potential. For films exhibiting large terraces, significant inhomogeneity in the KPFM signal is found even for best possible preparation conditions. Applying X-ray photoelectron spectroscopy (XPS), we find a significant contamination of the bulk ceria sample with fluorine while a possible fluorine contamination of the ceria film is below the XPS detection threshold. Time-of-flight secondary ion mass spectroscopy (TOF-SIMS) reveals an accumulation of fluorine within the first 5 nm below the surface of the bulk sample and a small concentration throughout the crystal.
    Physical Chemistry Chemical Physics 10/2012; 14(44):15361-8. · 3.83 Impact Factor
  • H. H. Pieper, C. Barth, M. Reichling
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    ABSTRACT: The structure and polarity of step edges on cleaved CaF2(111) are investigated by non-contact atomic force microscopy (NC-AFM) and Kelvin probe force microscopy. Ledges produced by cleaving the crystal appear with two distinctly different polarities denoted as type I and type II arising from the sectioning of ledges with steps having different polarities. With respect to the stoichiometric terrace, the surface potential is slightly reduced at ledges predominately composed of type I steps, while the potential of ledges predominantly composed of type II steps is significantly higher (typically 100 mV). We propose that the positive potential of type II steps stems from low coordinated Ca2+ ions inducing a dipole at step edges and confirm this by atomically resolved NC-AFM images revealing the Ca2+ ion sub-lattice with repulsive-mode imaging contrast.
    Applied Physics Letters 07/2012; 101(5). · 3.79 Impact Factor
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    ABSTRACT: We present a versatile system for the preparation of oxide crystal surfaces in the ultra-high vacuum (UHV) at temperatures up to 1300 K. Thermal treatment is accomplished by direct current heating of a tantalum foil in contact with the oxide sample. The sample temperature is measured by a thermocouple at a position close to the crystal and its reading is calibrated against the surface temperature determined by a second thermocouple temporarily attached to the surface. The design of the sample holder is based on a transferable plate originally developed for a commercial UHV scanning probe microscope. The system is, however, also suitable for the use with electron spectroscopy or electron diffraction based surface analytical techniques. We present results for the high-temperature preparation of CeO(2)(111) surfaces with atomically flat terraces exhibiting perfect atomic order and cleanliness as revealed by non-contact atomic force microscopy (NC-AFM) imaging. NC-AFM imaging is, furthermore, used to demonstrate the temperature-controlled aggregation of gold atoms on the CeO(2)(111) surface and their evaporation at high temperatures.
    The Review of scientific instruments 05/2012; 83(5):055110. · 1.52 Impact Factor
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    ABSTRACT: Water molecules adsorbed on the CeO(2)(111) surface are investigated by non-contact atomic force microscopy (NC-AFM) at several tip-sample temperatures ranging between 10 and 300 K. Depending on the strength of the tip-surface interaction, they appear as triangular protrusions extended over three surface oxygen atoms or as small pits at hollow sites. During NC-AFM imaging with the tip being close to the surface, occasionally the transfer of molecules between tip and surface or the tip-induced lateral displacement of water molecules to equivalent surface lattice sites is observed. We report how this situation can be exploited to produce controlled lateral manipulations. A protocol to manipulate the water molecules between pre-defined neighbouring equivalent adsorption sites of the regular lattice as well as across a surface oxygen vacancy is demonstrated.
    Journal of Physics Condensed Matter 02/2012; 24(8):084010. · 2.36 Impact Factor
  • Jannis Lübbe, Lutz Doering, Michael Reichling
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    ABSTRACT: We demonstrate the non-destructive measurement of the stiffness of single-beam, monocrystalline silicon cantilevers with a trapezoidal cross-section and tips as used for atomic force microscopy from the knowledge of cantilever dimensions, eigenfrequencies and material parameters. This yields stiffness values with an uncertainty of ±25% as the result critically depends on the thickness of the cantilever that is experimentally difficult to determine. The uncertainty is reduced to ±7% when the measured fundamental eigenfrequency is included in the calculation and a tip mass correction is applied. The tip mass correction can be determined from the eigenfrequencies of the fundamental and first harmonic modes. Results are verified by tip destructive measurements of the stiffness with a precision instrument recording a force–bending curve yielding an uncertainty better than ±5%.
    Measurement Science and Technology 02/2012; 23(4):045401. · 1.44 Impact Factor
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    ABSTRACT: The morphology and thermal stability of Ni and Co nanoclusters grown by physical vapour deposition on a reconstructed (1120) surface of α-Al(2)O(3) is investigated using non-contact atomic force microscopy (NC-AFM). NC-AFM images reveal that the clean α-Al(2)O(3)(1120) substrate adopts a characteristic (12 × 4) reconstruction when prepared in vacuum at high temperature. Subsequent deposition of Ni and Co onto this substrate at room temperature facilitates the growth of well-ordered metal nanocluster arrays with a preferred inter-cluster distance determined by the (12 × 4) periodicity of the substrate surface. The order in the cluster arrangement remains intact even upon annealing the system to temperatures up to 500 °C indicating a high resistance against sintering. The reconstructed α-Al(2)O(3)(1120) surface can, therefore, serve as an appropriate insulating template for studies of size-dependent magnetic or catalytic effects in a well-defined ensemble of metallic nanoclusters.
    Physical Chemistry Chemical Physics 02/2012; 14(6):2092-8. · 3.83 Impact Factor
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    ABSTRACT: Tailored CeO2/Pr2O3 thin-film oxide heterostructures are of interest for model catalysis studies by surface science techniques. For this purpose, thin CeO2(111) films were grown by molecular beam epitaxy on hex-Pr2O3(0001)/Si(111) as well as on cub-Pr2O3(111)/Si(111) support systems. A comparative, rigorous structure investigation by reflection high-energy electron diffraction transmission electron microscopy and laboratory and synchrotron based x-ray diffraction is reported. It is found that twin-free, exclusively type-B oriented CeO2(111) films are obtained on both oxide supports. CeO2(111) films adopt the stacking sequence from the cub-Pr2O3(111) buffer, but the transfer of the stacking information is less evident in the case of hex-Pr2O3(0001) films. Ab initio calculations are applied to understand the unusual stacking behavior of the CeO2(111) on the hex-Pr2O3(0001)/Si(111) system. It is revealed that the type-B stacking configuration is the more favorable configuration by 8 eV/nm2 due to electronic and crystallographic factors.
    Physical review. B, Condensed matter 01/2012; 85(3).
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    Loji K Thomas, Nadine Diek, Uwe Beginn, Michael Reichling
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    ABSTRACT: Fibril structures are produced at a solvent-graphite interface by self-assembly of custom-designed symmetric and asymmetric amphiphilic benzamide derivatives bearing C(10) aliphatic chains. Scanning tunnelling microscopy (STM) studies reveal geometry-dependent internal structures for the elementary fibrils of the two molecules that are distinctly different from known mesophase bulk structures. The structures are described by building-block models based on hydrogen-bonded dimer and tetramer precursors of hydrazines. The closure and growth in length of building units into fibrils takes place through van der Waals forces acting between the dangling alkyl chains. The nanoscale morphology is a consequence of the basic molecular geometry, where it follows that a closure to form a fibril is not always likely for the doubly substituted hydrazine. Therefore, we also observe crystallite formation.
    Beilstein Journal of Nanotechnology 01/2012; 3:658-66. · 2.37 Impact Factor
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    ABSTRACT: Highest purity CaF2 single crystals are irreversibly modified when irradiated with millions of pulses of 193 nm light at fluences of 120 mJ/cm2. Mie theory explains the observed haze by attributing the wavelength dependent extinction and the ratio between absorption and scattering to metallic colloids with radii in the range of 20 to 30 nm and a fractional volume of up to 2.8·10-7. Non-contact scanning force microscopy (NC-AFM) measurements performed on a surface produced by in-vacuo cleavage reveals that laser irradiation additionally produces a 104 times higher volume density of colloids with a radius of 1 to 2 nm.
    Applied Physics Letters 12/2011; 99(26):261909-261909-3. · 3.79 Impact Factor
  • Andriy Borodin, Michael Reichling
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    ABSTRACT: The unreconstructed TiO(2)(110) surface is prepared in well-defined states having different characteristic stoichiometries, namely reduced (r-TiO(2), 6 to 9% surface vacancies), hydroxylated (h-TiO(2), vacancies filled with OH), oxygen covered (ox-TiO(2), oxygen adatoms on a stoichiometric surface) and quasi-stoichiometric (qs-TiO(2), a stoichiometric surface with very few defects). The electronic structure and work function of these surfaces and transition states between them are investigated by ultraviolet photoelectron spectroscopy (UPS) and metastable impact electron spectroscopy (MIES). The character of the surface is associated with a specific value of the work function that varies from 4.9 eV for h-TiO(2), 5.2 eV for r-TiO(2), 5.35 eV for ox-TiO(2) to 5.5 eV for qs-TiO(2). We establish the method for an unambiguous characterization of TiO(2)(110) surface states solely based on the secondary electron emission characteristics. This is facilitated by analysing a weak electron emission below the nominal work function energy. The emission in the low energy cut-off region appears correlated with band gap emission found in UPS spectra and is attributed to localised electron emission through Ti(3+)(3d) states.
    Physical Chemistry Chemical Physics 09/2011; 13(34):15442-7. · 3.83 Impact Factor
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    ABSTRACT: The resonance frequency and Q-factor of cantilevers typically used for non-contact atomic force microscopy (NC-AFM) are measured as a function of the ambient pressure varied from 10 −8 mbar to normal pressure. The Q-factor is found to be almost constant up to a pressure in the range of 10 −2 –10 −1 mbar and then decreases by about three orders of magnitude when increasing the pressure further to normal pressure. The decrease in the resonance frequency measured over the same pressure range amounts to less than 1% where a significant change is observed in the range of 10–10 3 mbar. The pressure dependence of the effective Q-factor and resonance frequency is approximated by analytical models accounting for different processes in the molecular and viscous flow regimes. By introducing a heuristic approach for describing the pressure dependence in the transition regime, we are able to well approximate the cantilever properties over the entire pressure range.
    Measurement Science and Technology 09/2011; 22(22):55501-6. · 1.44 Impact Factor
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    Felix Loske, Michael Reichling, Angelika Kühnle
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    ABSTRACT: Depending on the deposition order in coadsorption of C(60) and SubPc molecules on CaF(2) (111), distinctly different island morphologies can be obtained. We demonstrate that non-equilibrium processes can play a significant role in molecular structure formation and constitute a new route for complex molecular patterning of an insulating surface.
    Chemical Communications 08/2011; 47(37):10386-8. · 6.38 Impact Factor
  • Clemens Barth, Michael Reichling
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    ABSTRACT: Oxide materials are strongly represented in this anthology. No fewer than five chapters discuss structural properties of oxide surfaces (Chaps. 7, 9 and 10) or situations where oxides play an important role as substrates for the growth of clusters and molecules (Chaps. 9, 10, 12 and 13). Among the oxides, sapphire (α-Al2O3) is a prototype insulating crystal with innumerable applications in science, technology and industry [1]. Precise knowledge of its atomic surface structure is a prerequisite for understanding and controlling processes involved in many of these applications [2]. However, despite several attempts, atomic resolution imaging on sapphire with dynamic force microscopy [3] was successfully demonstrated only years after the technique had been developed for imaging other insulating surfaces (Chaps. 5 and 6).
    07/2011: pages 135-145;

Publication Stats

498 Citations
350.81 Total Impact Points

Institutions

  • 2013
    • University of Utah
      • Department of Physics and Astronomy
      Salt Lake City, UT, United States
  • 2004–2013
    • Universität Osnabrück
      Osnabrück, Lower Saxony, Germany
  • 2010–2011
    • Johannes Gutenberg-Universität Mainz
      • Institute of Physical Chemistry
      Mainz, Rhineland-Palatinate, Germany
    • Aarhus University
      • Department of Physics and Astronomy
      Aars, Region North Jutland, Denmark
  • 2000–2011
    • University of Technology Munich
      • Faculty of Chemistry
      München, Bavaria, Germany
  • 2006
    • Karlsruhe Institute of Technology
      • Physikalisches Institut
      Karlsruhe, Baden-Wuerttemberg, Germany
  • 1999–2005
    • University Hospital München
      München, Bavaria, Germany
    • University of Latvia
      • Institute of Solid State Physics
      Riga, Riga, Latvia
  • 1988–2001
    • Freie Universität Berlin
      • Department of Physics
      Berlín, Berlin, Germany
  • 1992
    • Friedrich-Schiller-University Jena
      • Department of Optics and Quantum Electronics
      Jena, Thuringia, Germany