M. Puchalski

Missouri University of Science and Technology, Rolla, MO, USA

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Publications (4)0 Total impact

  • Article: Quantum Electrodynamic Corrections to the g Factor of Helium P States
    M. Puchalski, U. D. Jentschura
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    ABSTRACT: The Lande g factor describes the response of an atomic energy level to an external perturbation by a uniform and constant magnetic field. In the case of many-electron systems, the leading term is given by the interaction mu_B*(L+2S.B), where L and S are the orbital and spin angular momentum operators, respectively, summed over all electrons. For helium, a long-standing experimental-theoretical discrepancy for P states motivates a reevaluation of the higher-order terms which follow from relativistic quantum theory and quantum electrodynamics (QED). The tensor structure of relativistic corrections involves scalar, vector, and symmetric and anti-symmetric tensor components. We perform a tensorial reduction of these operators in a Cartesian basis, using an approach which allows us to separate the internal atomic from the external degrees of freedom (magnetic field) right from the start of the calculation. The evaluation proceeds in a Cartesian basis of helium eigenstates, using a weighted sum over the magnetic projections. For the relativistic corrections, this leads to a verification of previous results obtained using the Wigner-Eckhart theorem. The same method, applied to the radiative correction (Bethe logarithm term) leads to a spin-dependent correction which is different for singlet versus triplet P states. Theoretical predictions are given for singlet and triplet 2P and triplet 3P states and compared to experimental results where available.
    09/2012;
  • Article: Thermal correction to the molar polarizability of a Boltzmann gas
    U. D. Jentschura, M. Puchalski, P. J. Mohr
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    ABSTRACT: Metrology in atomic physics has been crucial for a number of advanced determinations of fundamental constants. In addition to very precise frequency measurements, the molar polarizability of an atomic gas has recently also been measured very accurately. Part of the motivation for the measurements is due to ongoing efforts to redefine the International System of Units (SI), for which an accurate value of the Boltzmann constant is needed. Here we calculate the dominant shift of the molar polarizability in an atomic gas due to thermal effects. It is given by the relativistic correction to the dipole interaction, which emerges when the probing electric field is Lorentz transformed into the rest frame of the atoms that undergo thermal motion. While this effect is small when compared to currently available experimental accuracy, the relativistic correction to the dipole interaction is much larger than the thermal shift of the polarizability induced by blackbody radiation.
    Phys. Rev. A. 12/2011; 84(6).
  • Article: Blackbody-radiation correction to the polarizability of helium
    M. Puchalski, U. D. Jentschura, P. J. Mohr
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    ABSTRACT: The correction to the polarizability of helium due to blackbody radiation is calculated near room temperature. A precise theoretical determination of the blackbody radiation correction to the polarizability of helium is essential for dielectric gas thermometry and for the determination of the Boltzmann constant. We find that the correction, for not too high temperature, is roughly proportional to a modified hyperpolarizability (two-color hyperpolarizability), which is different from the ordinary hyperpolarizability of helium. Our explicit calculations provide a definite numerical result for the effect and indicate that the effect of blackbody radiation can be excluded as a limiting factor for dielectric gas thermometry using helium or argon.
    Phys. Rev. A. 04/2011; 83(4).
  • Source
    Article: Black-Body Radiation Correction to the Polarizability of Helium
    M. Puchalski, U. D. Jentschura, P. J. Mohr
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    ABSTRACT: The correction to the polarizability of helium due to black-body radiation is calculated near room temperature. A precise theoretical determination of the black-body radiation correction to the polarizability of helium is essential for dielectric gas thermometry and for the determination of the Boltzmann constant. We find that the correction, for not too high temperature, is roughly proportional to a modified hyperpolarizability (two-color hyperpolarizability), which is different from the ordinary hyperpolarizability of helium. Our explicit calculations provide a definite numerical result for the effect and indicate that the effect of black-body radiation can be excluded as a limiting factor for dielectric gas thermometry using helium or argon.
    03/2011;

Institutions

  • 2011
    • Missouri University of Science and Technology
      • Department of Physics
      Rolla, MO, USA