Publications (389)1015.64 Total impact
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ABSTRACT: We report differential and integral cross sections for electronic excitation of methanol by lowenergy electron impact. Cross sections were measured for the four lowestlying excited states at incident electron energies from 9 to 20 eV and at scattering angles from 5° through 130°. The measured cross sections were normalized against previously reported elastic scattering data determined using the relative flow method. Corresponding crosssection calculations were carried out using the complex Kohn variational method within a 7channel closecoupling scheme and using the Schwinger multichannel method within an 11channel closecoupling scheme.Journal of Physics B Atomic Molecular and Optical Physics 06/2015; 48(11). DOI:10.1088/09534075/48/11/115208 · 1.92 Impact Factor  Physical Review A 05/2015; 91(5). DOI:10.1103/PhysRevA.91.053410 · 2.99 Impact Factor
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ABSTRACT: We report a combined experimental and theoretical investigation of dissociative electron attachment (DEA) to the nucleobase uracil. Using ion momentum imaging experiments employing a DEA reaction microscope we have measured 3dimensional momentum distributions of specific anionic fragments following DEA to uracil by 6 eV electrons. From the measured anion fragment kinetic energy we determine the possible dissociation pathways and the total kinetic energy release. We employ electronic structure and electron scattering calculations to determine the probability for electron attachment in the molecular frame. Combining these calculations with the imaging measurements, we reveal several key features of the coupled electronic and nuclear dynamics of DEA.Journal of Physical Chemistry Letters 10/2014; 5(21):3854–3858. DOI:10.1021/jz501907d · 6.69 Impact Factor  [Show abstract] [Hide abstract]
ABSTRACT: Normalized experimental differential and integral cross sections for vibrationally elastic scattering of lowenergy electrons from isobutanol (C4H9OH) are presented. The differential cross sections are measured at incident energies from 1 to 100 eV and scattering angles from 5 degrees to 130 degrees. These cross sections are compared to earlier experimental and theoretical results for isobutanol and nbutanol, as well as to results for smaller alcohols and for alkanes. Further comparisons are made with calculated cross sections for isobutylamine (C4H9NH2) and for smaller amines, including ethylamine (C2H5NH2), dimethylamine (CH3NHCH3), the two C3H7NH2 isomers npropylamine and isopropylamine, and ethylene diamine (NH2C2H4NH2). The calculated cross sections are obtained using the Schwinger multichannel method. The comparisons illuminate the role of molecular structure in determining the angular distribution of resonantly scattered electrons.Physical Review A 09/2014; 90(3):032708. DOI:10.1103/PhysRevA.90.032708 · 2.99 Impact Factor  [Show abstract] [Hide abstract]
ABSTRACT: We report results of the application of a fully ab initio approach for simulating timeresolved molecularframe photoelectron angular distributions around conical intersections in CS2. The technique employs wave packet densities obtained with the multiple spawning method in conjunction with geometry and energydependent photoionization matrix elements. The robust agreement of these results with measured molecularframe photoelectron angular distributions for CS2 demonstrates that this technique can successfully elucidate, and disentangle, the underlying nuclear and photoionization dynamics around conical intersections in polyatomic molecules.Physical Review Letters 03/2014; 112(11):113007. DOI:10.1103/PhysRevLett.112.113007 · 7.73 Impact Factor  [Show abstract] [Hide abstract]
ABSTRACT: We report differential and integral cross sections for excitation of the 3B1, 1B1, 3A2, 1A2, 3A1 and 1A1 states of H2O by 9–20 eV electrons. The measurements are taken by conventional differential electron energy loss spectroscopy techniques, while the calculations employ the Schwinger multichannel method within a tenchannel approximation. The new data are compared with previous experimental and theoretical results. The present measurements and calculations agree reasonably well both with each other and with prior theoretical efforts but show discrepancies with prior measurements. Reasons for those discrepancies are considered and discussed.Journal of Physics B Atomic Molecular and Optical Physics 05/2013; 46(12):125201. DOI:10.1088/09534075/46/12/125201 · 1.92 Impact Factor  Physical Review A 04/2013; 87(4). DOI:10.1103/PhysRevA.87.049902 · 2.99 Impact Factor
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ABSTRACT: We report results from a combined experimental and computational study of lowenergy electron interactions with acetaldehyde in the gas phase. Differential cross sections for elastic electron scattering were measured at selected incident energies from 1 to 50 eV, while corresponding firstprinciples calculations were carried out up to 30 eV. Integral and momentumtransfer cross sections were derived from the angledifferential data. The role of resonances in the scattering is examined and comparison is made to previous results for acetaldehyde and for its analogs, formamide and formic acid.Physical Review A 01/2013; 87(1). DOI:10.1103/PhysRevA.87.012710 · 2.99 Impact Factor  [Show abstract] [Hide abstract]
ABSTRACT: In order to understand and optimize processes occurring during the ignition of plasma and its consequences in postdischarge for an internal combustion engine, especially considering the spark plug, we have produced in this work some basic information necessary to modeling spark ignition in alcohol fuelled engines. Total cross sections of electron scattering by methanol and ethanol molecules in the energy range from 60 to 500 eV are reported, using the linear transmission method based on the BeerLambert law to first approximation. Aditionally to that, measurements and calculations of differential cross sections for elastic lowenergy (rotationally unresolved) electron scattering were also discussed, for impact energies of 1, 2, 5, 10, 15, 20, 30, 50, and 100 eV and for scattering angles of 5°130°. The measurements were obtained using the relative flow method with an aperture source, and calculations using two different implementations of the Schwinger multichannel method, one that takes all electrons into account and is adapted for parallel computers, and another that uses pseudopotentials and considers only the valence electrons.Journal of Physics Conference Series 11/2012; 388(1):2014. DOI:10.1088/17426596/388/1/012014  [Show abstract] [Hide abstract]
ABSTRACT: New experimental and theoretical data are presented for excitation of the 3B1 and 1B1 states of water by lowenergy (915 eV) electron impact.Journal of Physics Conference Series 11/2012; 388(5):2056. DOI:10.1088/17426596/388/5/052056  [Show abstract] [Hide abstract]
ABSTRACT: We present absolute experimental cross sections for elastic scattering, vibrational excitation by electron impact and for dissociative electron attachment to 1,3butadiyne, as well as calculations of the elastic cross sections.Journal of Physics Conference Series 11/2012; 388(5):2082. DOI:10.1088/17426596/388/5/052082  [Show abstract] [Hide abstract]
ABSTRACT: We report experimental and theoretical (Schwinger MultiChannel method with polarization effects) differential crosssections (DCS) for low energy elastic electron scattering from tetrahydrofuran. The data are for incident energies from 0.75 to 30eV and the experimental scattering angles range from 10^o to 130^o. Agreement between theory and experiment is very good across the range of this data. Comparisons with previous experiments is also very good in general. We will also report DCSs for vibrational excitation of this target for energies up to 15eV and similar scattering angles.  [Show abstract] [Hide abstract]
ABSTRACT: Pyrazine (C4H4N2) is a model molecule for studying electron interactions with nucleases. Also pyrazine is an ideal target, due to its high symmetry (D2h), for theoreticians to investigate electron collisions with complex DNA/RNA bases. In this work we present absolute elastic differential cross sections and elastic excitation functions for scattering of lowenergy electrons by pyrazine measured using a crossed electrontarget beam apparatus at the Australian National University. A comparison is also made between pyrazine cross sections with previously measured pyrimidine and benzene cross sections. Since all those molecules are similar in structure and considered as analogues to nucleobases, we intend to discuss similarities and differences in electron scattering results between three molecules. 
Article: Excitation of the \tilde{a}\,^3B_1 and \tilde{A}\,^1B_1 states of H2O by lowenergy electron impact
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ABSTRACT: We report measured and calculated differential crosssections for inelastic scattering of lowenergy electrons by water leading to excitation of the dissociative (1b1 → 4a1) 1, 3B1 states. The measurements were taken using conventional energyloss spectroscopy at incident energies of 9, 10, 12, 15, and 20 eV for scattering angles from 10° to 130°. The calculations were carried out using the Schwinger multichannel method, with a Borndipole correction applied in the singlet excitation channel. Integral excitation cross sections for the \tilde{a}\,^3B_1 and \tilde{A}\,^1B_1 states are also derived from the differential cross section results.Journal of Physics B Atomic Molecular and Optical Physics 10/2012; 45(20):1001. DOI:10.1088/09534075/45/20/201001 · 1.92 Impact Factor  [Show abstract] [Hide abstract]
ABSTRACT: We report experimental and theoretical (Schwinger MultiChannel method, with polarization effects) for electron scattering from acetaldehyde. The incident energies range from 1eV to 30eV and scattering angles from 10 to 130^o. The experimental method used a moveable aperture source with the relative flow method. Comparisons between theory and experiment will be presented.  [Show abstract] [Hide abstract]
ABSTRACT: We explore the application of a quantum vibrational wavepacket dynamics formulation of femtosecond energy and angleresolved photoelectron spectroscopy to the study of nuclear and electron dynamics. The formulation incorporates geometry and energydependent photoionization matrix elements and is well suited for studies of nonadiabatic dynamics where nuclear and electronic degrees of freedom are coupled. In this paper we explore two aspects of angleresolved pump–probe photoelectron spectroscopy, using NO2 and NaI as examples. The first is a refinement of femtosecond photoelectron spectroscopy in which the time derivative of the velocity map image is seen to more readily characterize the nuclear wavepacket dynamics in nonadiabatic regions. The other is an analysis to extract the effects of electronicstate fluctuation from subfemtosecond scale photoelectron dynamics. Within the framework of the Born–Huang (Oppenheimer) expansion where the total wavefunction is expressed in products of stationarystate electronic wavefunctions and timedependent nuclear wavepackets, we seek to identify how the effect of electron dynamics might be manifested in principle.Journal of Physics B Atomic Molecular and Optical Physics 09/2012; 45(19):194006. DOI:10.1088/09534075/45/19/194006 · 1.92 Impact Factor  [Show abstract] [Hide abstract]
ABSTRACT: Cross sections for elastic scattering of lowenergy electrons by tetrahydrofuran, a prototype for the furanose ring found in the backbone of DNA, have been measured and calculated over a wide energy range, with an emphasis on energies below 6 eV, where previous data are scarce. The measurements employ a thinaperture version of the relativeflow method, while the calculations employ the Schwinger multichannel method with an extensive treatment of polarization effects. Comparisons with earlier results, both experimental and theoretical, are presented and discussed. A proper accounting for the strong permanent electric dipole of tetrahydrofuran is found to be essential to obtaining reliable cross sections, especially at energies below 5 eV.Physical Review A 05/2012; 85(5). DOI:10.1103/PhysRevA.85.052717 · 2.99 Impact Factor  [Show abstract] [Hide abstract]
ABSTRACT: We review applications of the Schwinger multichannel method to lowenergy electron collisions with polyatomic molecules of biological interest. After briefly describing the method, its implementation, and its strengths and limitations, we turn to a discussion of specific molecular systems, with an emphasis on studies related to radiation damage to DNA mediated by secondary electrons. Throughout, we situate our results in the context of calculated and experimental data on electron scattering, dissociative attachment, and other relevant processes.  [Show abstract] [Hide abstract]
ABSTRACT: We present results of measurements and calculations of elastic electron scattering from pyrimidine in the energy range 3–50 eV. Absolute differential and integral elastic cross sections have been measured using a crossed electronmolecule beam spectrometer and the relative flow technique. The measured cross sections are compared with results of calculations using the wellknown Schwinger variational technique and an independentatom model. Agreement between the measured differential cross sections and the results of the Schwinger calculations is good at lower energies but less satisfactory at higher energies where inelastic channels that should be open are kept closed in the calculations.Physical Review A 12/2011; 84(6). DOI:10.1103/PhysRevA.84.062702 · 2.99 Impact Factor  [Show abstract] [Hide abstract]
ABSTRACT: We report measured and calculated cross sections for elastic scattering of lowenergy electrons by isopropanol (propan2ol). The experimental data were obtained using the relative flow technique with helium as the standard gas and a thin aperture as the collimating target gas source, which permits use of this method without the restrictions imposed by the relative flow pressure conditions on helium and the unknown gas. The differential cross sections were measured at energies of 1.5, 2, 3, 5, 6, 8, 10, 15, 20, and 30 eV and for scattering angles from 10∘ to 130∘. The cross sections were computed over the same energy range employing the Schwinger multichannel method in the staticexchange plus polarization approximation. Agreement between theory and experiment is very good. The present data are compared with previously calculated and measured results for npropanol, the other isomer of C3H7OH. Although the integral and momentum transfer cross sections for the isomers are very similar, the differential cross sections show a strong isomeric effect: In contrast to the fwave behavior seen in scattering by npropanol, dwave behavior is observed in the cross sections of isopropanol. These results corroborate our previous observations in electron collisions with isomers of C4H9OH.Physical Review A 10/2011; 84(4). DOI:10.1103/PhysRevA.84.042702 · 2.99 Impact Factor
Publication Stats
7k  Citations  
1,015.64  Total Impact Points  
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Institutions

2014

National Research Council Canada
Ottawa, Ontario, Canada


1967–2014

California Institute of Technology
 • Arthur Amos Noyes Laboratory of Chemical Physics
 • Division of Chemistry and Chemical Engineering
 • Gates and Crellin Laboratories of Chemistry
Pasadena, California, United States


2010

California State University, Fullerton
 Department of Physics
Fullerton, California, United States


2007

University of Chicago
 Department of Chemistry
Chicago, Illinois, United States


2000

University of Minnesota Duluth
 Department of Chemistry and Biochemistry
Duluth, Minnesota, United States


1994

Louisiana State University
 Department of Chemistry
Baton Rouge, Louisiana, United States


1993

University of Waterloo
 Department of Chemistry
Ватерлоо, Ontario, Canada


1976–1993

Pasadena City College
Pasadena, Texas, United States


1988

Los Alamos National Laboratory
 Theoretical Division
ЛосАламос, California, United States


1986

Texas A&M University
 Department of Chemistry
College Station, Texas, United States


1981

Bielefeld University
Bielefeld, North RhineWestphalia, Germany
