Takashi Fujikawa

Chiba University, Tiba, Chiba, Japan

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Publications (189)261.71 Total impact

  • Chemical Physics Letters 07/2014; 608:152–156. · 2.15 Impact Factor
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    ABSTRACT: We have studied the surface and bulk plasmon losses associated with Li 1s photoemission. Here, full multiple scatterings of photoelectrons are taken into account before and after the plasmon losses within the quantum Landau formula that can describe overall features of the photoemission bands. We compared the depth profiles of the Li 1s single-loss spectra with full multiple scatterings and without elastic scatterings. They are strongly influenced by the elastic scatterings. The model accounting for the full multiple scatterings gives a rapidly decaying function of the depth because of the defocusing effects. Copyright © 2014 John Wiley & Sons, Ltd.
    Surface and Interface Analysis 04/2014; · 1.39 Impact Factor
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    ABSTRACT: We have measured C 1s photoelectron angular distributions (PADs) in coincidence with the CO+–O+ fragment ion pairs of CO2 molecules at the photoelectron energies of 85, 120 and 150 eV. The observed left–right asymmetric PADs have been well reproduced by our theoretical model taking into account the two degenerate zero-point bending vibrations. This leads to a conclusive result on the interpretation of such PADs; although it has been believed so far that they are the molecular frame, in fact they are the recoil frame.
    Journal of Physics B Atomic Molecular and Optical Physics 03/2014; 47(7):071002. · 2.03 Impact Factor
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    ABSTRACT: Nickel oxide is a p-type semiconductor with wide band gaps of 3–4 eV. The defects of O or Ni atoms are essential to explain some specific features of the semiconductors. The information of the local structure around Ni is important to clarify the conduction mechanism. We investigate the Ni K-edge X-ray absorption fine structure spectra of the nickel oxide thin films in order to obtain the structural information around Ni. For the X-ray absorption near edge structure (XANES) analyses, we apply a full multiple scattering theory. The experimental results suggest that the crystallinity of the thin films depends on the annealing temperature. The distances of Ni–O and Ni–Ni are 1.984 and 2.747 Å for the sample annealed at 100 °C and 2.084 and 2.947 Å for the sample annealed at 300 °C, respectively. Our multiple scattering calculations can satisfactorily explain the experimental result. Copyright © 2014 John Wiley & Sons, Ltd.
    Surface and Interface Analysis 03/2014; · 1.39 Impact Factor
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    ABSTRACT: We study the angular and energy dependence of surface and bulk plasmon losses accompanying deep core excitations in simple metals. Here full multiple scatterings of photoelectrons are taken into account before and after the plasmon losses within the quantum Landau formula, which can describe overall features of the photoemission bands. For example, multiple plasmon loss features can be calculated by use of the formula. Two simple metals, Al and Na, are studied here. The depth profiles of the plasmon losses are strongly influenced by the elastic scatterings. The model assuming single elastic scatterings overestimates the losses from deep emitters due to the forward focusing effects, whereas the model accounting for full multiple scatterings gives a much rapidly decaying function of the depth due to the defocusing effects and rich structures due to the photoelectron diffraction. The single elastic scattering approximation gives a poor result both for the depth profiles and for the loss spectra. The present multiple scattering calculations successfully explain the azimuthal dependence of the loss spectra, which reflect the local geometry around the emitters.
    12/2013; 89(4).
  • APPC12, Makuhari, Japan; 07/2013
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    ABSTRACT: We provide a molecular structure determination method, based on multiple-scattering x-ray photoelectron diffraction (XPD) calculations. This method is applied to our XPD data on several molecules having different equilibrium geometries. Then it is confirmed that, by our method, bond lengths and bond angles can be determined with a resolution of less than 0.1 Å and 10∘, respectively. Differently from any other scenario of ultrafast structure determination, we measure the two- or three-dimensional XPD of aligned or oriented molecules in the energy range from 100 to 200 eV with a 4π detection velocity map imaging spectrometer. Thanks to the intense and ultrashort pulse properties of x-ray free-electron lasers, our approach exhibits the most probable method for obtaining ultrafast real-time structural information on small to medium-sized molecules consisting of light elements, i.e., a “molecular movie.”
    Physical Review A 06/2013; 87(6). · 3.04 Impact Factor
  • Ming-Hui Shang, Takashi Fujikawa, Nubuo Ueno
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    ABSTRACT: Recoil effects in valence band X-ray photoelectron spectroscopy (XPS) are studied for both abbtrifluorostyrene and styrene molecular crystal systems. The gradual changes of XPS spectra excited by several photon energies are theoretically investigated within the tight-binding approximation and harmonic approximation of lattice vibrations, and have been explained in terms of not only atomic mass but also atomic orbital (AO) population. The recoil effect of valence band photoemission strongly depends on the population and partial photoionization cross section (PICS) of AOs as well as the mass of composite ion. In abb-trifluorostyrene F 2p dominant bands show the recoil shift close to free F atom recoil shift, and C 2s dominant bands show that to free C atom recoil shift, whereas the mixed bands of C and F give rise to the peak asymmetries due to their different recoil shifts. For these systems hydrogen contribution is negligibly small which is contrast to our previous results for the crystals composed of small organic molecules. We also discuss some potential uses of the recoil shifts for these systems.
    Analytical Chemistry 02/2013; · 5.82 Impact Factor
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    ABSTRACT: The spin-polarized electronic structures across the interface between single-layer graphene and a Ni(111) thin film are explored by employing depth-resolved X-ray absorption and magnetic circular dichroism spectroscopy with atomic layer resolution. The depth-resolved Ni L2,3-edge analysis clarifies that the Ni atomic layers adjacent to the interface show a transition of the spin orientation to the perpendicular one in contrast to the in-plane one in the bulk region. The C K-edge analysis reveals the intensification of the spin–orbit interactions induced by the π–d hybridization at the interface as well as out-of-plane spin polarization in the π band region of graphene. The present study indicates the importance of the interface design at the atomic layer level for graphene-based spintronics.
    Journal of Materials Chemistry 01/2013; 1:5533-5537. · 6.63 Impact Factor
  • Akihiro Koide, Takashi Fujikawa, Nobuyuki Ichikuni
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    ABSTRACT: We briefly review the basic theory and recent applications in the X-ray absorption fine structure (XAFS) spectroscopy. First we discuss a dressed one-electron XAFS formula starting from many-body scattering theory, where important many-body effects, intrinsic and extrinsic losses, and optical potential are naturally introduced. Next multiple scattering renormalization, and spherical wave effects are discussed. Phonon effects such as Debye-Waller factors are also discussed. Some interesting XAFS applications, in particular, ultrafast XAFS and XAFS applications to nano-particles are discussed in some detail.
    Journal of Electron Spectroscopy and Related Phenomena 01/2013; · 1.71 Impact Factor
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    ABSTRACT: 1s photoelectron angular distributions from fixed-in-space CO2, NO2, BF3 and CH3F molecules have been calculated by X-ray photoelectron diffraction (XPD) theory with muffin-tin-type molecular potential. For all the molecules, the calculated results show good agreements with those by density functional theory in the energy region ≳100 eV. Furthermore, for all the molecules experimental data on the angular distributions in such energy region are well reproduced by the XPD theory. These intensive studies lead to a rather general rule that the XPD theory is an adequate tool to describe high-energy photoelectron angular distributions for any single oriented molecules.
    Journal of Electron Spectroscopy and Related Phenomena 11/2012; 185(11):535–545. · 1.71 Impact Factor
  • Takashi Fujikawa, Katsumi Kaneko
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    ABSTRACT: We theoretically discuss X-ray absorption intensity in high-energy region far from the deepest core threshold to explain the morphology-dependent mass attenuation coefficient of some carbon systems, carbon nanotubes (CNTs), highly oriented pyrolytic graphite (HOPG) and fullerenes (C60). The present theoretical approach is based on the many-body X-ray absorption theory including the intrinsic losses (shake-up losses). In the high-energy region the absorption coefficient has correction term dependent on the solid state effects given in terms of the polarization part of the screened Coulomb interaction Wp. We also discuss the tail of the valence band X-ray absorption intensity. In the carbon systems C 2s contribution has some influence on the attenuation coefficient even in the high energy region at 20 keV.
    Journal of Electron Spectroscopy and Related Phenomena 11/2012; 185(11):509–511. · 1.71 Impact Factor
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    ABSTRACT: We measured molecular-frame photoelectron angular distributions (MFPADs) for a carbon 1s level of CO molecules in the kinetic energy range of up to 150 eV. X-ray photoelectron diffraction (XPD) theory was adopted to interpret the profiles of the MFPADs. Computational experiments within the framework of XPD theory were performed to demonstrate the emergence of interference effects between the direct photoelectron and scattered waves in the MFPAD profiles.
    Journal of Physics B Atomic Molecular and Optical Physics 09/2012; 45(19):194007. · 2.03 Impact Factor
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    ABSTRACT: In this work we have measured Co K- and L2,3-edge X-ray absorption near edge structure (XANES) and Co L2,3-edge X-ray magnetic circular dichroism (XMCD) spectra, and also carried out their calculations for C60Cox compounds. The observed XANES and XMCD are sensitive to the Co concentration. In the low density region (x = 1.0 − 1.5), one Co is surrounded by three C60 balls. The Co L2,3-edge XMCD analyses gives the spin magnetic moment on Co in the range 0.5–0.9μB.In the high density region (x = 4.0 − 4.3) calculated XANES for one of the proposed model, 4C604Co model, by Nakajima and Kaya give rather good agreement with the observed XANES, where a Co4 cluster is surrounded by four C60 balls. Fourier transformed extended X-ray absorption fine structure (EXAFS) is well explained by this model. In contrary to these results, the calculated XMCD spectrum for that high-symmetric model shows rather poor agreement with the observed spectrum. Lowering the symmetry, we can improve the agreement. The cluster density functional calculations for the 4C604Co model show that spin quintet (4μB) is in the lowest energy. Each Co has 1μB in ferromagnetic like order. The results also indicate that the band gap for the minority spin is smaller than that for the majority spin. This result provides us with fundamental information to understand the tunnel magnetoresistance (TMR) mechanism in those systems.
    Journal of Electron Spectroscopy and Related Phenomena 03/2012; 185(s 1–2):32–38. · 1.71 Impact Factor
  • M.-H. Shang, T. Fujikawa, N. Ueno
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    ABSTRACT: We discuss recoil effects from extended molecular orbitals in simple molecular crystals excited by high-energy X-ray photons. Because of Debye-Waller factors the interference effects between photoelectron waves emanatin from different atomic sites can be neglected, and the Gelius formula is safely used, which provides us with simple expression of photoemission bands. This formula can explain the recoil energy shift and energy dependence of the intensity of each level. We apply it to the photoemission bands from acetylene and diacetylene molecular crystals in the energy range from 125 to 1200 eV. Hydrogen recoil shift is much larger than carbon, however it is hard to observe recoil effect due to the hydrogen recoil because of its quite small photoionization cross section even in this intermediate energy region. Additionally, we expect that useful information which is obtained from the energy dependence of these bands: the C 2s and 2p components in each molecular orbital can be estimated roughly from the energy dependence.
    e-Journal of Surface Science and Nanotechnology 01/2012; 10:128.
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    ABSTRACT: Hard and soft x-ray photoelectron spectroscopy was performed for core and valence electrons in V3Si. The recoil effects on the photoelectron emission were observed not only in the case of the Si 2p core level, but also for the valence band, although such effects were not observed for the V 2p and V 3p core levels. The valence-band results are compared with the results of the theoretical model calculation based on the tight-binding cluster approximation and harmonic approximation for lattice vibrations. The Si 2p core-level results interpreted as due to the single nucleus recoil effects are consistent with the interpretation of those of the valence electrons calculated on these approximations. From the E-B dependence of the valence-band recoil shifts, useful information is obtained on the Si 3p partial density of states near the Fermi level.
    Physical review. B, Condensed matter 01/2012; 86(3). · 3.77 Impact Factor
  • ISSS-6, Funabori, Tokyo; 12/2011
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    ABSTRACT: We have synthesized nickel by means of pulsed laser ablation. A nickel disc was used for ablation with the focused output of fundamental harmonic from Nd:YAG laser. X-ray diffraction result shows that the synthesized nanoparticles are of pure metallic nickel with a face-centred cubic structure and the average particle size is 35 nm. The extended X-ray absorption fine structure (EXAFS) studies of pure nickel foil and the synthesized nanoparticles show similar structures. The position of the main peak is same in these nanoparticles with reference to the nickel foil. The only difference was observed in the reduction of the amplitude. The nearest-neighbour distance is similar as for pure nickel foil. The Debye–Waller factor is also similar. There is no trace of oxide and hydroxide in the EXAFS data, suggesting that the synthesized nanoparticles contain only nickel metal.
    Diamond Light Source Proceedings. 04/2011; 1.
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    ABSTRACT: Angular dependencies of ultraviolet photoelectron spectrum of transition metal-phthalocyanines (TM-Pcs), NiPc and CoPc, have been studied by using multiple-scattering theory to explore the electronic structure of the organometallic complexes influenced by central metal atom. The calculated angular distributions of photoelectrons for the highest occupied molecular orbital (HOMO: a1u) from the two single systems are nearly the same and represent well the experimental results obtained for the well-ordered monolayer on the highly oriented pyrolytic graphite substrate. The central metal atoms almost have no contribution on the HOMO distribution, which mainly comes from the carbon atoms of Pc ring. Moreover, the modification of the distribution for π orbital upon adsorption as well as the scattering effects of the central metal on the photoemission intensities are negligible for the major.
    J. Elect. Spect. Rel. Phenom. 01/2011; 84:261.
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    ABSTRACT: We study possible methods how to obtain imaging of magnetic atoms by use of photoelectron diffraction (PD). We have proposed a method to apply Daimon effect where forward focusing PD peaks are rotated; we use the difference of the PD intensities for different circular polarization but − is used for the – circular polarization only in the data handling. This technique allows us to obtain atomic image only of spin polarized atoms. In this work we further apply this technique to ferromagnetic and antiferromagnetic surface layers with in-plane magnetization adsorbed on a nonmagnetic layer.
    Journal of Physics Conference Series 06/2010; 235(1):012009.

Publication Stats

456 Citations
261.71 Total Impact Points

Institutions

  • 1996–2014
    • Chiba University
      • • Graduate School of Advanced Integration Science
      • • Graduate School of Science
      • • Department of Image and Materials Science
      • • Faculty of Science
      • • Department of Chemistry
      Tiba, Chiba, Japan
  • 2010
    • Nagoya University
      • Graduate School of Science
      Nagoya-shi, Aichi-ken, Japan
  • 2000–2007
    • Hirosaki University
      • Faculty of Science and Technology
      Khirosaki, Aomori Prefecture, Japan
  • 1987–2006
    • Yokohama National University
      Yokohama, Kanagawa, Japan
  • 2004
    • Saitama Institute of Technology
      Saitama, Saitama, Japan
  • 2001
    • Okayama University
      • Department of Physics
      Okayama, Okayama, Japan
  • 1993
    • Lund University
      • Department of Theoretical Physics
      Lund, Skåne, Sweden