María J Iglesias

Publications (2)16.08 Total impact

• Article: Synthesis and characterization of a coupled binuclear Cu(I)/Cu(III) complex.

  Jesús García-López, Víctor Yañez-Rodríguez, Laura Roces, Santiago García-Granda, Ana Martínez, Alfredo Guevara-García, German R Castro, Félix Jiménez-Villacorta, María J Iglesias, Fernando López Ortiz
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  ABSTRACT: The synthesis through reaction of a C(alpha),C(ortho) dilithiated phosphazene with CuBr and structural characterization of the first example of a binuclear mixed valence [Cu(I)(N(2))/Cu(III)(C(4))] complex showing a metal-metal bond, as well as its applications in cyclopropanation and oxidation reactions, are described.
  Journal of the American Chemical Society 08/2010; 132(31):10665-7. · 9.91 Impact Factor
• Article: Unprecedented asymmetric induction through configurationally stable lithium N-(alpha-methylbenzyl)phosphinamides. A new entry to enantiomerically pure gamma-aminophosphinic acids and esters.

  Ignacio Fernández, Gloria Ruiz Gómez, Ignacio Alfonso, María J Iglesias, Fernando López Ortiz
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  ABSTRACT: The first examples of configurationally stable N-benzyl-N-phosphinoyl carbanions are described. Their applications to the synthesis of homochiral gamma-aminophosphinic acids and esters via highly enantioselective dearomatising reactions are shown.
  Chemical Communications 12/2005; · 6.17 Impact Factor