Philippe Grosshans

Publications (6)26.22 Total impact

• Article: Molecular tectonics: design of enantiomerically pure helical tubular crystals with controlled channel size and orientation.

  Mei-Jin Lin, Abdelaziz Jouaiti, Philippe Grosshans, Nathalie Kyritsakas, Mir Wais Hosseini
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  ABSTRACT: The combination of four enantiomerically pure organic tectons composed of a rigid chiral backbone bearing two terminal pyridyl coordinating sites with ZnSiF(6) behaving as an infinite pillar leads to the formation of tubular 2-D enantiomerically pure helical channels with controlled size and orientation.
  Chemical Communications 07/2011; 47(27):7635-7. · 6.17 Impact Factor
• Source

  Available from: François Riobé

  Article: Bis(tetrathiafulvalenes) with aromatic bridges: electron delocalization in the oxidized species through EPR and theoretical studies.

  François Riobé, Narcis Avarvari, Philippe Grosshans, Helena Sidorenkova, Théo Berclaz, Michel Geoffroy
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  ABSTRACT: A series of bis(TTF) donors containing aromatic linkers between the two TTF units has been synthesized in order to investigate on the electronic structure of the oxidized species from an experimental and theoretical point of view. A mono(TTF)-pyridine compound has been also prepared and characterized by single-crystal X-ray diffraction analysis. Oxidation of a solution of 2,6-bis(TTF)-pyridine (TTF-Pyr-TTF) or of 1,3-bis(TTF)-benzene (TTF-Bz-TTF) in CH(2)Cl(2) with less than 0.1 equivalent of [Cp(2)Fe][PF(6)] gives rise to a seven-line EPR spectrum consistent with the hyperfine structure calculated by DFT for the corresponding radical monocation. Increasing the proportion of oxidant leads to a four-line hyperfine structure, similar to the quartet pattern observed after oxidation of mono(TTF)-pyridine (Pyr-TTF) or mono(TTF)-benzene (Bz-TTF). In good accordance with the very weak value of J calculated by DFT for the dicationic biradicals these four-line spectra are attributed to [2,6-bis(TTF)-pyridine](2+) and [1,3-bis(TTF)-benzene](2+). Similar experimental results are obtained for 1,4-bis(TTF)-benzene. In this case, however, electrochemical oxidation leads to the monoradical at low potential and to the diradical at higher potential, while only the diradical could be observed by electrochemical oxidation of 2,6-bis(TTF)-pyridine or of 1,3-bis(TTF)-benzene.
  Physical Chemistry Chemical Physics 09/2010; 12(33):9650-60. · 3.57 Impact Factor
• Source

  Available from: François Riobé

  Article: Mono- and bis(tetrathiafulvalene)-1,3,5-triazines as covalently linked donor-acceptor systems: structural, spectroscopic, and theoretical investigations.

  François Riobé, Philippe Grosshans, Helena Sidorenkova, Michel Geoffroy, Narcis Avarvari
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  ABSTRACT: Reaction of 2,4,6-trichloro-1,3,5-triazine with lithiated tetrathiafulvalene (TTF) in stoichiometric conditions, followed by treatment with sodium methanolate, provides mono- and bis(TTF)-triazines as new covalently linked (multi)donor-acceptor systems. Single-crystal X-ray analyses reveal planar structures for both compounds, with formation of peculiar segregated donor and acceptor stacks for the mono(TTF)-triazine compound, while mixed TTF-triazine stacks establish in the case of the bis(TTF) derivative. Cyclic voltammetry measurements show reversible oxidation of the TTF units, at rather low potential, with no splitting of the oxidation waves in the case of the dimeric TTF, whereas irreversible reduction of the triazine core is observed. Intramolecular charge transfer is experimentally evidenced through solution electronic absorption spectroscopy. Time-dependent DFT calculations allow the assignment of the charge transfer band to singlet transitions from the HOMO of the donor(s) to the LUMO of the acceptor. Solution EPR measurements correlated with theoretical calculations were performed in order to characterize the oxidized species. In both cases the spectra show very stable radical species and contain a triplet of doublet pattern, in agreement with the coupling of the unpaired electron with the three TTF protons. The dication of the bis(TTF)-triazine is paramagnetic, but no spin-spin exchange interaction could be detected.
  Chemistry 12/2008; 15(2):380-7. · 5.93 Impact Factor
• Source

  Available from: unige.ch

  Article: [CpNi(diselenolene)] neutral radical complexes: electron paramagnetic resonance and density functional theory investigations.

  Philippe Grosshans, Prashant Adkine, Helena Sidorenkova, Mitsushiro Nomura, Marc Fourmigué, Michel Geoffroy
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  ABSTRACT: 77Se-enriched CpNi(bds) (bds = 1,2-benzenediselenolate), has been synthesized and its g tensor and 77Se hyperfine tensors have been obtained from its frozen solution electron paramagnetic resonance (EPR) spectrum. These parameters are consistent with those calculated by density functional theory (DFT); it is shown that 10% of the spin is localized on each selenium and that the direction associated to the maximum 77Se couplings is aligned along the gmin direction, perpendicular to the Ni(bds) plane. EPR measurements and DFT calculations are also carried out on the 77Se enriched complex CpNi(dsit) as well on the two dithiolene analogues CpNi(bdt) and CpNi(dmit). The optimized structures of the isolated CpNi(bds) and CpNi(bdt) complexes have been used to generate the idealized dimers (bds)NiCp...CpNi(bds) and (bdt)NiCp...CpNi(bdt) characterized by Cp...Cp overlap. The exchange parameters J calculated at the DFT level for these systems are in reasonable accord with the experimental values. The influence of the geometry of the dimer on its magnetic properties is assessed by calculating the variation of J as a function of the relative orientation of the two Ni(diselenolene) or Ni(dithiolene) planes.
  The Journal of Physical Chemistry A 06/2008; 112(17):4067-73. · 2.95 Impact Factor
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  Available from: unige.ch

  Article: ESR/DFT study of bis-iminophosphorane cation radicals.

  Adil Matni, Leila Boubekeur, Philippe Grosshans, Nicolas Mézailles, Gérald Bernardinelli, Pascal Le Floch, Michel Geoffroy
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  ABSTRACT: Bis-iminophosphoranes containing various types of linkers between two R3P==N moieties were electrochemically oxidized at controlled potential in situ in the electron spin resonance (ESR) cavity. For linkers constituted of phenylenes, conjugated phenylenes or merely a dicyanoethylenic bond, this oxidation led to well-resolved ESR spectra which were characterized by their g values and by their 1H, 14N and 31P isotropic hyperfine constants. These coupling constants agree with those calculated by DFT for the corresponding cation radicals. Experimental and theoretical results clearly indicate that in these species the unpaired electron is mostly delocalized on the bridge and on the nitrogen atoms while the spin density on the phosphorus atoms is particularly small. Cyclic voltammetry and ESR spectra show that the nature of the bridge between the two iminophosphoranes considerably influences the oxidation potential of the compound as well as the stability of the radical cation. Information about the conformation of the precursor containing two Ph3P==N moieties separated by a --C(CN)==C(CN)--group was obtained from its crystal structure.
  Magnetic Resonance in Chemistry 01/2008; 45(12):1011-7. · 1.44 Impact Factor
• Article: Molecular tectonics: from enantiomerically pure sugars to enantiomerically pure triple stranded helical coordination network.

  Philippe Grosshans, Abdelaziz Jouaiti, Véronique Bulach, Jean-Marc Planeix, Mir Wais Hosseini, Jean-François Nicoud
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  ABSTRACT: The self-assembly between a bis-monodentate tecton based on two pyridine units connected to an enantiomerically pure isomannide stereoisomer and HgCl2 leads to the formation of an enantiomerically pure triple stranded helical infinite coordination network which was structurally characterised by X-ray diffraction on single crystal.
  Chemical Communications 07/2003; · 6.17 Impact Factor