Hyuck Mo Lee

Korea Advanced Institute of Science and Technology, Sŏul, Seoul, South Korea

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Publications (163)373.55 Total impact

  • Source
    Hyoung Gyu Kim · Hyuck Mo Lee ·
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    ABSTRACT: We developed a modified potential energy surface following three assumptions and verified that the most stable motion of a single particle with extreme speed in a modified potential energy surface is identical to the atomic model of hydrogen. Significant three equations are found regarding the stable motions of more than two particles. These equations are in good agreement with the motion of protons and neutrons, and one can arrange the periodic table successfully using these three equations.
  • Changsoo Lee · Na Rae Kim · Jahyun Koo · Yung Jong Lee · Hyuck Mo Lee ·
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    ABSTRACT: In this work, we synthesized uniform Cu-Ag core-shell nanoparticles using a facile two-step process that consists of thermal decomposition and galvanic displacement methods. The core-shell structure of these nanoparticles was confirmed through characterization using transmission electron microscopy, energy-dispersive spectroscopy, and x-ray diffraction. Furthermore, we investigated the oxidation stability of the Cu-Ag core-shell nanoparticles in detail. Both qualitative and quantitative x-ray photoelectron spectroscopy analyses confirm that the Cu-Ag core-shell nanoparticles have considerably higher oxidation stability than Cu nanoparticles. Finally, we formulated a conductive ink using the synthesized nanoparticles and coated it onto glass substrates. Following the sintering process, we compared the resistivity of the Cu-Ag core-shell nanoparticles with that of the Cu nanoparticles. The results of this study clearly show that the Cu-Ag core-shell nanoparticles can potentially be used as an alternative to Ag nanoparticles because of their superior oxidation stability and electrical properties.
    Nanotechnology 11/2015; 26(45):455601. DOI:10.1088/0957-4484/26/45/455601 · 3.82 Impact Factor
  • Kihoon Bang · Kihyun Shin · Myung Shin Ryu · Soonho Kwon · Hyuck Mo Lee ·

    Catalysis Today 11/2015; DOI:10.1016/j.cattod.2015.09.040 · 3.89 Impact Factor
  • Jaewon Chang · Sung K. Kang · J.-H. Lee · K.-S. Kim · Hyuck Mo Lee ·
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    ABSTRACT: Sn whiskers are becoming a serious reliability issue in Pb-free electronic packaging applications. Sn whiskers are also observed in connector parts of electronics as well as on electroplated surface finishes. Sn whiskers found in connector parts are known to behave differently from the typical Sn whiskers reported on electroplated Sn surfaces. In this study, Sn whiskers on plastically deformed Sn-rich films were investigated to understand their growth behavior to establish mitigation strategies for Sn-rich films used in connectors. Therefore, a microhardness indentation technique was applied to plastically deform electroplated matte Sn samples, followed by temperature/humidity (T/H) testing (30°C, dry air). Each sample was examined by scanning electron microscopy at regular time intervals up to 4000 h. Various morphologies of Sn whiskers on plastically deformed matte Sn films were observed, and their growth statistics and kinetics are analyzed in terms of the plating conditions and plastic deformation by using transmission electron microscopy, x-ray diffraction, and the focused ion-beam technique. Sn whiskers were observed on plastically deformed regions of thin (2-μm) and thick (10-μm) matte Sn films, regardless of the current density applied. Plastic deformation was found to promote whisker formation on matte Sn films. A high density of dislocations and newly formed fine Sn subgrains were observed in deformed grains. In addition, the recrystallized grains and Cu6Sn5 intermetallic compound grew further with increasing time. Finally, a growth mechanism for deformation-induced Sn whiskers is proposed based on a recrystallization model combined with the formation of Cu6Sn5.
    Journal of Electronic Materials 10/2015; 44(10):3486-3499. DOI:10.1007/s11664-015-3921-3 · 1.80 Impact Factor
  • Source
    Jahyun Koo · Changsoo Lee · Sung Jea Hong · Keun-Soo Kim · Hyuck Mo Lee ·
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    ABSTRACT: It is important to develop Pb-free solder alloys suitable for automotive use instead of traditional Sn–Pb solder due to environmental regulations (e.g., Restriction of Hazardous Substances (RoHS)). Al addition has been spotlighted to enhance solder properties. In this study, we investigated the microstructural change of Sn–0.5Cu wt.% based Pb-free solder alloys with Al addition (0.01–0.05 wt.%). The small amount of Al addition caused a remarkable microstructural change. The Al was favored to form Cu–Al intermetallic compounds inside the solder matrix. We identified the Cu–Al intermetallic compound as Cu33Al17, which has a rhombohedral structure, using EPMA and TEM analyses. This resulted in refined Cu6Sn5 networks in the Sn–0.5Cu based solder alloy. In addition, we conducted thermal analysis to confirm its stability at a high temperature of approximately 230 °C, which is the necessary temperature range for automotive applications. The solidification results were substantiated thermodynamically using the Scheil solidification model. We can provide criteria for the minimum aluminum content to modify the microstructure of Pb-free solder alloys.
    Journal of Alloys and Compounds 08/2015; 650. DOI:10.1016/j.jallcom.2015.08.003 · 3.00 Impact Factor
  • Source
    Hyoung Gyu Kim · Hyuck Mo Lee ·

  • Na Rae Kim · Kihyun Shin · Inyu Jung · Moonsub Shim · Hyuck Mo Lee ·
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    ABSTRACT: A simple oleylamine-based thermal decomposition process using different time steps for precursor injection was used to obtain bimetallic Ag–Cu nanoparticles with a narrow size distribution. Experimental and theoretical studies were carried out to demonstrate that these bimetallic nanoparticles are less prone to oxidation. The calculated energy trends for O2 adsorption on the nanoparticles show that the adsorption energy declines rapidly when more than six O2 molecules are present, indicating that O2 is rarely adsorbed on Ag–Cu nanoparticles. Electron transfer from Cu to Ag within these bimetallic nanoparticles allows far better resistance to oxidation than monometallic Cu nanoparticles.
    The Journal of Physical Chemistry C 11/2014; 118(45):26324-26331. DOI:10.1021/jp506069c · 4.77 Impact Factor
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    ABSTRACT: Backside illumination complementary metal oxide semiconductor image sensors (BSI CISs) represent an advanced technology that produces high-quality image sensors. However, BSI CISs are limited by high dark signals and noise signals on the backside. To address these problems, backside junctions are commonly used. High-dose backside junctions effectively reduce dark signals and noise signals. The depth of the implantation profile is a key factor in determining the junction depth. A laser thermal annealing process is conducted only near the surface to the activation, and thus broader doping profiles are limitations to be activation of dopants. Changing the dopant from B to BF2 can decrease the implant projected range. However, there are abnormal activation rates for BF2 in applications involving laser thermal annealing processes for shallow junctions. Although the need for BF2 is increasing, a mechanism for its slow activation and low activation rates has not yet been confirmed. Here, we identify the mechanism by which BF2 undergoes low activation after a melting threshold temperature and explain why this phenomenon occurs. In addition, we confirm a condition that provides high activation rates of BF2 and show the reduction of dark signals and noise signals at the high density BSI CISs.
    Journal of Electronic Materials 11/2014; 43(11). DOI:10.1007/s11664-014-3336-6 · 1.80 Impact Factor
  • Source
    Sang Chul Yeo · Yu Chieh Lo · Ju Li · Hyuck Mo Lee ·
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    ABSTRACT: Ammonia (NH3) nitridation on an Fe surface was studied by combining density functional theory (DFT) and kinetic Monte Carlo (kMC) calculations. A DFT calculation was performed to obtain the energy barriers (Eb) of the relevant elementary processes. The full mechanism of the exact reaction path was divided into five steps (adsorption, dissociation, surface migration, penetration, and diffusion) on an Fe (100) surface pre-covered with nitrogen. The energy barrier (Eb) depended on the N surface coverage. The DFT results were subsequently employed as a database for the kMC simulations. We then evaluated the NH3 nitridation rate on the N pre-covered Fe surface. To determine the conditions necessary for a rapid NH3 nitridation rate, the eight reaction events were considered in the kMC simulations: adsorption, desorption, dissociation, reverse dissociation, surface migration, penetration, reverse penetration, and diffusion. This study provides a real-time-scale simulation of NH3 nitridation influenced by nitrogen surface coverage that allowed us to theoretically determine a nitrogen coverage (0.56 ML) suitable for rapid NH3 nitridation. In this way, we were able to reveal the coverage dependence of the nitridation reaction using the combined DFT and kMC simulations.
    The Journal of Chemical Physics 10/2014; 141(13):134108. DOI:10.1063/1.4896610 · 2.95 Impact Factor
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    ABSTRACT: The exemption clause for Pb-containing automobile parts in the RoHS (Restriction of Hazardous Substances) legislation will expire in a few years. Therefore, there is an urgent need to develop new Pb-free solder alloys that are suitable for automobiles. To improve the properties of the Pb-free solders used in automobiles that are consistently exposed to high temperatures and vibrations, we investigated the effects of minor alloying additions of chromium, calcium and palladium and examined the various properties of the resulting Sn–0.7Cu solders. We then investigated the new intermetallic compounds observed after the addition of chromium. In addition, we conducted thermal analysis to confirm the stability of the alloys at temperatures of approximately 230 °C. The wettability and interfacial reactions between the solder alloys and the Cu under bump metallurgy are discussed. Furthermore, to evaluate the mechanical properties of the developed solder alloys, tensile tests were conducted. We confirmed that our minor alloying strategy enhances the strength and hardness of solder alloys without decreasing their melting temperatures.
    Journal of Alloys and Compounds 09/2014; 608:126–132. DOI:10.1016/j.jallcom.2014.03.194 · 3.00 Impact Factor
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    ABSTRACT: Although the reaction results of numerous iron-based Fischer–Tropsch synthesis catalysts containing various promoters have been reported, the research on their theoretical foundation is still insufficient. In the present work, highly activated K-doped χ-Fe5C2/charcoal nanocatalysts were designed using calculations based on density functional theory (DFT), and then prepared using a melt-infiltration process and a subsequent incipient-wetness method of K precursors. The catalyst at K/Fe = 0.075 in an atomic ratio that bears small iron carbide nanoparticles of 18 nm showed the highest activity (1.54 × 10−4 molCO gFe−1 s−1) and the best hydrocarbon yield (1.41 × 10−3 gHC gFe−1 s−1), as well as a good selectivity for gasoline-range (C5–C12) hydrocarbon products in the high-temperature Fischer–Tropsch reaction.
    07/2014; 2(35). DOI:10.1039/C4TA02413C
  • Sang Chul Yeo · Sang Soo Han · Hyuck Mo Lee ·
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    ABSTRACT: Catalytic decomposition of ammonia (NH3) is a promising chemical reaction in energy and environmental applications. Density functional theory (DFT) calculations were performed to clarify the detailed catalytic mechanism of NH3 decomposition on an Fe(100) surface. Specifically, the elementary steps of the mechanism were calculated for the general dehydrogenation pathway of NH3. The adsorption of two types of ammonia dimers (2NH3), locally adsorbed NH3 and hydrogen-bonded NH3, were then compared, revealing that locally adsorbed NH3 is more stable than hydrogen-bonded NH3. By contrast, the dehydrogenation of dimeric NH3 results in a high energy barrier. Moreover, the catalytic characteristics of NH3 decomposition on a nitrogen (N)-covered Fe surface must be considered because the recombination of nitrogen (N2) and desorption have an extremely high energy barrier. Our results indicate that the catalytic characteristics of the NH3 decomposition reaction are altered by N coverage of the Fe surface. This study primarily focused on energetic and electronic analysis. Finally, we conclude that Fe is an alternative catalyst for the decomposition of NH3 in COx-free hydrogen production.
    The Journal of Physical Chemistry C 03/2014; 118(10):5309–5316. DOI:10.1021/jp410947d · 4.77 Impact Factor
  • Jaewon Chang · Sung K. Kang · Jae-ho Lee · Keun-Soo Kim · Hyuck Mo Lee ·

  • Jaewon Chang · Sung K. Kang · Jae-Ho Lee · Keun-Soo Kim · Hyuck Mo Lee ·
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    ABSTRACT: Sn whiskers are becoming a serious reliability issue in Pb-free electronic packaging applications. Among the numerous Sn whisker mitigation strategies, minor alloying additions to Sn have been proven effective. In this study, several commercial Sn and Sn-Ag baths of low-whisker formulations are evaluated to develop optimum mitigation strategies for electroplated Sn and Sn-Ag. The effects of plating variables and storage conditions, including plating thickness and current density, on Sn whisker growth are investigated for matte Sn, matte Sn-Ag, and bright Sn-Ag electroplated on a Si substrate. Two different storage conditions are applied: an ambient condition (30°C, dry air) and a high-temperature/high-humidity condition (55°C, 85% relative humidity). Scanning electron microscopy is employed to record the Sn whisker growth history of each sample up to 4000 h. Transmission electron microscopy, x-ray diffraction, and focused ion beam techniques are used to understand the microstructure, the formation of intermetallic compounds (IMCs), oxidation, the Sn whisker growth mechanism, and other features. In this study, it is found that whiskers are observed only under ambient conditions for both thin and thick samples regardless of the current density variations for matte Sn. However, whiskers are not observed on Sn-Ag-plated surfaces due to the equiaxed grains and fine Ag3Sn IMCs located at grain boundaries. In addition, Sn whiskers can be suppressed under the high-temperature/high-humidity conditions due to the random growth of IMCs and the formation of thick oxide layers.
    Journal of Electronic Materials 10/2013; 43(1):533-. DOI:10.1007/s11664-013-2800-z · 1.80 Impact Factor
  • Na Rae Kim · Inyu Jung · Yun Hwan Jo · Hyuck Mo Lee ·
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    ABSTRACT: To control the optical properties of Cu2O for a variety of application, we synthesized Cu2O in nanoscale without other treatments. Cu2O nanoparticles with an average size of 2.7 nm (sigma < or = 3.7%) were successfully synthesized in this study via a modified thermal decomposition process. Copper (II) acetylacetonate was used as a precursor, and oleylamine was used as a solvent, a surfactant and a reducing agent. The oleylamine-mediated synthesis allowed for the preparation of Cu2O nanoparticles with a narrower size distribution, and the nanoparticles were synthesized in the presence of a borane tert-butylamine (BTB) complex, where BTB was a strong co-reducing agent together with oleylamine. UV-vis spectroscopy analysis suggest that band gap energy of these Cu2O particles is enlarged from 2.1 eV in the bulk to 3.1 eV in the 2.7-nm nanoparticles, which is larger than most other reported value of Cu2O nanoparticles. Therefore, these nanoparticles could be used as a transparent material because of transformed optical property.
    Journal of Nanoscience and Nanotechnology 09/2013; 13(9):6027-32. DOI:10.1166/jnn.2013.7649 · 1.56 Impact Factor
  • Kihyun Shin · Da Hye Kim · Hyuck Mo Lee ·
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    ABSTRACT: Intensive research on oxygen reduction reaction (ORR) catalysts has been undertaken to find a Pt substitute or reduce the amount of Pt. Ag nanoparticles are potential Pt substitutes; however, the weak oxygen adsorption energy of Ag prompted investigation of other catalysts. Herein, we prepared AgCu bimetallic nanoparticle (NP) systems to improve the catalytic performance and compared the catalytic performance of Ag, Cu, AgCu (core-shell), and AgCu (alloy) NP systems as new catalyst by investigating the adsorption energy of oxygen and the activation energy of oxygen dissociation, which is known to be the rate-determining step of ORR. By analyzing HOMO-level isosurfaces of metal NPs and oxygen, we found that the adsorption sites and the oxygen adsorption energies varied with different configurations of NPs. We then plotted the oxygen adsorption energies against the energy barrier of oxygen dissociation to determine the catalytic performance. AgCu (alloy) and Cu NPs exhibited strong adsorption energies and low activation-energy barriers. However, the overly strong oxygen adsorption energy of Cu NPs hindered the ORR.
    ChemSusChem 06/2013; 6(6). DOI:10.1002/cssc.201201001 · 7.66 Impact Factor
  • Sung K. Kang · Jaewon Chang · Jae-Ho Lee · Keun-Soo Kim · Hyuck Mo Lee ·
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    ABSTRACT: Sn whiskers are becoming a serious reliability problem in microelectronics where Pb-free solder technology is being implemented with pure Sn or Sn-rich alloys. Numerous investigations have been performed to understand the whisker growth mechanisms and thereby to mitigate Sn whisker growth. Among many Sn whisker mitigation strategies, minor alloying additions to Sn have been found to be quite effective. One challenge in evaluating Sn whisker growth is a time-consuming aging test, such as 4000 h testing condition recommended by the JEDEC-JESD201A standard. In this study, several commercial Sn and Sn-Ag baths of low whisker formulations are evaluated. The effects of plating variables and aging conditions on Sn whisker growth are investigated with matte Sn, matte Sn-Ag, and bright Sn-Ag electroplated on a Cu/Ni/Si substrate. The layer thickness and current density are the major plating variables studied. Two different storage conditions are applied; an ambient condition (30°C/dry air), and a high temperature/humidity condition (55°C/85%RH). In addition, the effect of plastic deformation on Sn whisker growth is investigated as an acceleration method for Sn whisker testing. Microhardness indentation technique is applied to electroplated Sn and Sn-Ag samples to plastically deform them before T/H testing. Each sample is examined by SEM at a regular time interval up to 4000 h. Various morphologies of Sn whiskers are observed and their growth statistics are analyzed in terms of plating conditions, plastic deformation and T/H testing conditions. Plastic deformation is found to significantly accelerate Sn whisker growth both in pure Sn and Sn-Ag samples. The method of plastic deformation can be employed to shorten the time-consuming Sn whisker growth testing.
    Electronic Components and Technology Conference (ECTC), 2013 IEEE 63rd; 05/2013
  • Sang Chul Yeo · Sang Soo Han · Hyuck Mo Lee ·
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    ABSTRACT: We report first-principles calculations of adsorption, dissociation, penetration, and diffusion for the complete nitridation mechanism of nitrogen molecules on a pure Fe surface (bcc, ferrite phase). The mechanism of the definite reaction path was calculated by dividing the process into four steps. We investigated various reaction paths for each step including the energy barrier based on the climb image nudged elastic band (CI-NEB) method, and the complete reaction pathway was computed as the minimum energy path (MEP). The adsorption characteristics of nitrogen (N) and molecular nitrogen (N2) indicate that nitrogen atoms and molecules are energetically favorable at the hollow sites on pure Fe(100) and (110). The dissociation of the nitrogen molecule (N2) was theoretically supported by electronic structure calculations. The penetration of nitrogen from the surface to the sub-surface has a large energy barrier compared with the other steps. The activation energy calculated for nitrogen diffusion in pure bcc Fe was in good agreement with the experimental results. Finally, we confirmed the rate-determining step for the full nitridation reaction pathway. This study provides fundamental insight into the nitridation mechanism for nitrogen molecules in pure bcc Fe.
    Physical Chemistry Chemical Physics 03/2013; 15(14). DOI:10.1039/c3cp44367a · 4.49 Impact Factor
  • Inyu Jung · Kihyun Shin · Na Rae Kim · Hyuck Mo Lee ·
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    ABSTRACT: Acetic acid (AA) has been employed to reduce the surface capping ligands of Ag nanoparticles (NPs) for the fabrication of low-temperature-processable and highly conductive Ag ink. The ligand reduction of the Ag NPs was achieved using a one-step method, in which oleylamine (OA)-capped Ag NPs were immersed in AA for different durations (1, 2, 3, 5 and 10 h). The weight of the total capping ligand was reduced from 12.1 wt% to 2.3 wt% by 10 h AA immersion. According to in situ transmission electron microscopy (TEM) and electrical resistivity, the ligand-reduced Ag NPs were cured at a much lower temperature (approximately 100 °C) and showed better electrical performance than OA-capped NPs under the same conditions. To investigate the reason for this enhancement of the electrical properties, we characterized the surface chemistry of the Ag NPs by Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS), which revealed that the surface capping ligand was exchanged from the OA to the acetate ion. In addition, the adsorption energy of the ligand was increased by the ligand exchange, which was studied using density functional theory (DFT) calculations. DFT was effective in explaining the adsorption of each ligand on Ag NPs and indicated that the ligand can be exchanged by AA immersion.
    02/2013; 1(9):1855-1862. DOI:10.1039/C2TC00450J
  • Sung K Kang · Jaewon Chang · Jaeho Lee · Keun-Soo Kim · Hyuck Mo Lee ·

Publication Stats

3k Citations
373.55 Total Impact Points


  • 1991-2014
    • Korea Advanced Institute of Science and Technology
      • Department of Materials Science and Engineering
      Sŏul, Seoul, South Korea
  • 2010
    • Sungkyunkwan University
      • Department of Chemistry
      Sŏul, Seoul, South Korea
  • 2005
    • Samsung Advanced Institute of Technology
      Usan-ri, Gyeonggi-do, South Korea