Publications (7)13.96 Total impact
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Article: The impact of compaction, moisture content, particle size and type of bulking agent on initial physical properties of sludge-bulking agent mixtures before composting.
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ABSTRACT: This study aimed to experimentally acquire evolution profiles between depth, bulk density, Free Air Space (FAS), air permeability and thermal conductivity in initial composting materials. The impact of two different moisture content, two particle size and two types of bulking agent on these four parameters was also evaluated. Bulk density and thermal conductivity both increased with depth while FAS and air permeability both decreased with it. Moreover, depth and moisture content had a significant impact on almost all the four physical parameters contrary to particle size and the type of bulking agent.Bioresource technology 03/2012; 114:428-36. · 4.25 Impact Factor -
Article: Characterization and modelling of the heat transfers in a pilot-scale reactor during composting under forced aeration.
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ABSTRACT: The paper focused on the modelling of the heat transfers during composting in a pilot-scale reactor under forced aeration. The model took into account the heat production and the transfers by evaporation, convection between material and gas crossing the material, conduction and surface convection between gas and material in bottom and upper parts of the reactor. The model was adjusted thanks to the measurements practised during fifteen composting experiments in which five organic wastes were, each, composted under three constant aeration rates. Heat production was considered proportional to oxygen consumption rate and the enthalpy per mole oxygen consumed was assumed constant. The convective heat transfer coefficients were determined on basis of the continuous measurements of the temperatures of both the lid and the bottom part of the reactor. The model allowed a satisfying prediction of the temperature of the composting material. In most cases, the mean absolute discard between the experimental and the simulated temperatures was inferior to 2.5°C and the peaks of temperature occurred with less than 8h delay. For the half of the experiments the temperature discard between the simulated peak and the experimental one was inferior to 5°C. On basis of the calculation of a stoichiometric production of water through oxidation of the biodegradable organic matter, the simulation of water going out from material as vapour also allowed a rather satisfying prediction of the mass of water in final mixture. The influence of the aeration rate on every type of heat loss was characterized. Finally, the model was used to evaluate the impacts on material temperature caused by the change of the insulation thickness, the ambient temperature, take the lid away, the increase or the decrease of the mass of waste to compost.Waste Management 01/2012; 32(6):1091-105. · 2.43 Impact Factor -
Article: Comparison of five organic wastes regarding their behaviour during composting: part 2, nitrogen dynamic.
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ABSTRACT: This paper aimed to compare household waste, separated pig solids, food waste, pig slaughterhouse sludge and green algae regarding processes ruling nitrogen dynamic during composting. For each waste, three composting simulations were performed in parallel in three similar reactors (300 L), each one under a constant aeration rate. The aeration flows applied were comprised between 100 and 1100 L/h. The initial waste and the compost were characterized through the measurements of their contents in dry matter, total carbon, Kjeldahl and total ammoniacal nitrogen, nitrite and nitrate. Kjeldahl and total ammoniacal nitrogen and nitrite and nitrate were measured in leachates and in condensates too. Ammonia and nitrous oxide emissions were monitored in continue. The cumulated emissions in ammonia and in nitrous oxide were given for each waste and at each aeration rate. The paper focused on process of ammonification and on transformations and transfer of total ammoniacal nitrogen. The parameters of nitrous oxide emissions were not investigated. The removal rate of total Kjeldahl nitrogen was shown being closely tied to the ammonification rate. Ammonification was modelled thanks to the calculation of the ratio of biodegradable carbon to organic nitrogen content of the biodegradable fraction. The wastes were shown to differ significantly regarding their ammonification ability. Nitrogen balances were calculated by subtracting nitrogen losses from nitrogen removed from material. Defaults in nitrogen balances were assumed to correspond to conversion of nitrate even nitrite into molecular nitrogen and then to the previous conversion by nitrification of total ammoniacal nitrogen. The pool of total ammoniacal nitrogen, i.e. total ammoniacal nitrogen initially contained in waste plus total ammoniacal nitrogen released by ammonification, was calculated for each experiment. Then, this pool was used as the referring amount in the calculation of the rates of accumulation, stripping and nitrification of total ammoniacal nitrogen. Separated pig solids were characterised by a high ability to accumulate total ammoniacal nitrogen. Whatever the waste, the striping rate depended mostly on the aeration rate and on the pool concentration in biofilm. The nitrification rate was observed as all the higher as the concentration in total ammoniacal nitrogen in the initial waste was low. Thus, household waste and green algae exhibited the highest nitrification rates. This result could mean that in case of low concentrations in total ammoniacal nitrogen, a nitrifying biomass was already developed and that this biomass consumed it. In contrast, in case of high concentrations, this could traduce some difficulties for nitrifying microorganisms to develop.Waste Management 11/2009; 30(3):415-25. · 2.43 Impact Factor -
Article: Comparison of five organic wastes regarding their behaviour during composting: part 1, biodegradability, stabilization kinetics and temperature rise.
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ABSTRACT: This paper aims to compare household waste, separated pig solids, food waste, pig slaughterhouse sludge and green algae regarding their biodegradability, their stabilization kinetics and their temperature rise during composting. Three experiments in lab-scale pilots (300 L) were performed for each waste, each one under a constant aeration rate. The aeration rates applied were comprised between 100 and 1100 L/h. The biodegradability of waste was expressed as function of dry matter, organic matter, total carbon and chemical oxygen demand removed, on one hand, and of total oxygen consumption and carbon dioxide production on the other. These different variables were found closely correlated. Time required for stabilization of each waste was determined too. A method to calculate the duration of stabilization in case of limiting oxygen supply was proposed. Carbon and chemical oxygen demand mass balances were established and gaseous emissions as carbon dioxide and methane were given. Finally, the temperature rise was shown to be proportional to the total mass of material biodegraded during composting.Waste Management 11/2009; 30(3):402-14. · 2.43 Impact Factor -
Article: Impact of nitrate-enhanced leachate recirculation on gaseous releases from a landfill bioreactor cell.
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ABSTRACT: This study evaluates the impact of nitrate injection on a full scale landfill bioreactor through the monitoring of gaseous releases and particularly N(2)O emissions. During several weeks, we monitored gas concentrations in the landfill gas collection system as well as surface gas releases with a series of seven static chambers. These devices were directly connected to a gas chromatograph coupled to a flame ionisation detector and an electron capture detector (GC-FID/ECD) placed directly on the field. Measurements were performed before, during and after recirculation of raw leachate and nitrate-enhanced leachate. Raw leachate recirculation did not have a significant effect on the biogas concentrations (CO(2), CH(4) and N(2)O) in the gas extraction network. However, nitrate-enhanced leachate recirculation induced a marked increase of the N(2)O concentrations in the gas collected from the recirculation trench (100-fold increase from 0.2 ppm to 23 ppm). In the common gas collection system however, this N(2)O increase was no more detectable because of dilution by gas coming from other cells or ambient air intrusion. Surface releases through the temporary cover were characterized by a large spatial and temporal variability. One automated chamber gave limited standard errors over each experimental period for N(2)O releases: 8.1 +/- 0.16 mg m(-2) d(-1) (n = 384), 4.2 +/- 0.14 mg m(-2) d(-1) (n = 132) and 1.9 +/- 0.10 mg m(-2) d(-1) (n = 49), during, after raw leachate and nitrate-enhanced leachate recirculation, respectively. No clear correlation between N(2)O gaseous surface releases and recirculation events were evidenced. Estimated N(2)O fluxes remained in the lower range of what is reported in the literature for landfill covers, even after nitrate injection.Waste Management 04/2009; 29(7):2078-84. · 2.43 Impact Factor -
Article: Impact of nitrate-enhanced leachate recirculation on gaseous releases from a landfill bioreactor cell
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ABSTRACT: This study evaluates the impact of nitrate injection on a full scale landfill bioreactor through the monitoring of gaseous releases and particularly N2O emissions. During several weeks, we monitored gas concentrations in the landfill gas collection system as well as surface gas releases with a series of seven static chambers. These devices were directly connected to a gas chromatograph coupled to a flame ionisation detector and an electron capture detector (GC-FID/ECD) placed directly on the field. Measurements were performed before, during and after recirculation of raw leachate and nitrate-enhanced leachate. Raw leachate recirculation did not have a significant effect on the biogas concentrations (CO2, CH4 and N2O) in the gas extraction network. However, nitrate-enhanced leachate recirculation induced a marked increase of the N2O concentrations in the gas collected from the recirculation trench (100-fold increase from 0.2 ppm to 23 ppm). In the common gas collection system however, this N2O increase was no more detectable because of dilution by gas coming from other cells or ambient air intrusion. Surface releases through the temporary cover were characterized by a large spatial and temporal variability. One automated chamber gave limited standard errors over each experimental period for N2O releases: 8.1 ± 0.16 mg m−2 d−1 (n = 384), 4.2 ± 0.14 mg m−2 d−1 (n = 132) and 1.9 ± 0.10 mg m−2 d−1 (n = 49), during, after raw leachate and nitrate-enhanced leachate recirculation, respectively. No clear correlation between N2O gaseous surface releases and recirculation events were evidenced. Estimated N2O fluxes remained in the lower range of what is reported in the literature for landfill covers, even after nitrate injection.Waste Management. -
Article: Comparison of five organic wastes regarding their behaviour during composting: Part 1, biodegradability, stabilization kinetics and temperature rise
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ABSTRACT: This paper aims to compare household waste, separated pig solids, food waste, pig slaughterhouse sludge and green algae regarding their biodegradability, their stabilization kinetics and their temperature rise during composting. Three experiments in lab-scale pilots (300 L) were performed for each waste, each one under a constant aeration rate. The aeration rates applied were comprised between 100 and 1100 L/h. The biodegradability of waste was expressed as function of dry matter, organic matter, total carbon and chemical oxygen demand removed, on one hand, and of total oxygen consumption and carbon dioxide production on the other. These different variables were found closely correlated. Time required for stabilization of each waste was determined too. A method to calculate the duration of stabilization in case of limiting oxygen supply was proposed. Carbon and chemical oxygen demand mass balances were established and gaseous emissions as carbon dioxide and methane were given. Finally, the temperature rise was shown to be proportional to the total mass of material biodegraded during composting.Waste Management.
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