Publications (45)108.54 Total impact

Article: Theoretical methods for attosecond electron and nuclear dynamics: applications to the H 2 molecule
Journal of Physics B Atomic Molecular and Optical Physics 12/2015; 48(24):242001. DOI:10.1088/09534075/48/24/242001 · 1.98 Impact Factor  [Show abstract] [Hide abstract]
ABSTRACT: The presence of net circular dichroism in the photoionization of nonchiral homonuclear molecules has been put in evidence recently through the measurement of molecularframe photoelectron angular distributions in dissociative photoionization of ${\text{H}}_{2}$ [Dowek et al., Phys. Rev. Lett. 104, 233003 (2010)]. In this work we present a detailed study of circular dichroism in the photoelectron angular distributions of ${\text{H}}_{2}$ and ${\text{D}}_{2}$ molecules, oriented perpendicularly to the propagation vector of the circularly polarized light, at different photon energies (20, 27, and 32.5 eV). Circular dichroism in the angular distributions at 20 and to a large extent 27 eV exhibits the usual pattern in which inversion symmetry is preserved. In contrast, at 32.5 eV, the inversion symmetry breaks down, which eventually leads to total circular dichroism after integration over the polar emission angle. Timedependent ab initio calculations support and explain the observed results for ${\text{H}}_{2}$ in terms of quantum interferences between direct photoionization and delayed autoionization from the ${\mathcal{Q}}_{1}$ and ${\mathcal{Q}}_{2}$ doubly excited states into ionic states $(1s{$\sigma${}}_{g}$ and $2p{$\sigma${}}_{u})$ of different inversion symmetry. Nevertheless, for ${\text{D}}_{2}$ at 32.5 eV, there is a particular case where theory and experiment disagree in the magnitude of the symmetry breaking: when ${\text{D}}^{+}$ ions are produced with an energy of around 5 eV. This reflects the subleties associated to such simple molecules when exposed to this fine scrutiny.Physical Review A 10/2014; 90(4). DOI:10.1103/PhysRevA.90.043417 · 2.81 Impact Factor  [Show abstract] [Hide abstract]
ABSTRACT: Shannon entropies and Fisher information calculated from oneparticle density distributions and von Neumann and linear entropies (the latter two as a measure of entanglement) computed from the reduced oneparticle density matrix are analyzed for the S1,3(e),P1,3(o) and D1,3(e) Rydberg series of He doubly excited states below the second ionization threshold. We find that both Fisher information and entanglement measures are able to discriminate resonances pertaining to different (K, T)(A) series.Journal of Physics Conference Series 04/2014; 488(15):152004. DOI:10.1088/17426596/488/15/152004 
Article: Timedependent Feshbach method to study resonant photoionization of He with ultrashort laser pulses
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ABSTRACT: A timedependent Feshbach formalism is proposed to study the resonant photoionization of the helium atom using ultrashort laser pulses. This spectral method consist in solving the timedependent Schrodinger equation by expanding the timedependent wavepacket in terms of eigenfunctions defined in two orthogonal halfspaces: a boundlike resonant and a nonresonant scatteringlike . The latter eigenfunctions for the projected Hamiltonians H and H are not indeed eigenfunctions of the total Hamiltonian, so that the electrostatic coupling H acts as a leaking operator → responsible for the temporal decay of resonances into the underlying continuum, keeping the physical insight of the FanoFeshbach time independent formalisms. This method allows not only for accurate descriptions of the resonance parameters (energies, widths and Fano shape parameters) but also for the temporal evolution of the photodynamics involved in the resonant photoionization when using short laser pulses. We illustrate the performance of the method by analyzing the temporal formation of i) the onephoton ionization cross section below the second ionization threshold and the buildup of Fano profiles and ii) the updown asymmetry of photoelectron angular distributions resulting from interferences of S, P and Dwaves after simultaneous photoexcitation and decay of the lowest 1Se, 1P° and 1De resonant states, by using two sequential laser pulses with XUV harmonic frequencies separated by a time delay.Journal of Physics Conference Series 04/2014; 488(1):012018. DOI:10.1088/17426596/488/1/012018  [Show abstract] [Hide abstract]
ABSTRACT: The stability of resonant states in Heliumlike atoms while under the influence of a plasma environment is studied. We analyze the variation of resonance parameters (energies and lifetimes) against the strength of the screening parameter within the DebyeHückel model. We use a Feshbachlike projection formalism with explicitly correlated CIwave functions to uncover the evolution of resonance parameters until they cross the upper Aq+(N=2) threshold, and a complex scaling method to analyze the survival of these Feshbach resonances across the threshold, which eventually makes them behave as shape resonances.Journal of Physics Conference Series 04/2014; 488(6):062010. DOI:10.1088/17426596/488/6/062010 
Conference Paper: Reply to comment on 'Timeresolved resonant photoionization of He using a timedependent Feshbach method with ultrashort laser pulses'
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ABSTRACT: We study the resonant photoionization of the Helium atom subject to ultrashort laser pulses by using a Feshbach formalism in the time domain. We solve the projected timedependent Schrodinger equation in terms of a configuration interaction spectral method, with a total wave function expanded with configurations defined within boundlike ( ##IMG## [http://ej.iop.org/images/17426596/488/3/032023/jpconf14_488_032023_eqn001.gif] ) and scatteringlike ( ##IMG## [http://ej.iop.org/images/17426596/488/3/032023/jpconf14_488_032023_eqn002.gif] ) halfspaces. The method allows for accurate descriptions of both the atomic structure (energy positions and widths) as well as for the resonant photodynamics using ultrashort laser pulses. Special attention is given to the temporal formation of Fano profiles in the one and twophoton ionization cross sections.Journal of Physics: Conference Series (XXVIII International Conference on Photonic, Electronic and Atomic Collisions (ICPEAC 2013)), Lanzhou, China; 07/2013 
Article: Feshbach projection approach to study plasma effects on doubly excited autoionizing states in helium
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ABSTRACT: We have implemented a method based on the Feshbach formalism along with an explicitly correlated configuration interaction method to perform a systematic study on the behavior of resonance parameters (energies and lifetimes) of the autoionizing states of plasmaembedded He 1,3Se, 1,3Po, and 1,3De, as a function of the screening strength. In particular, we study the evolution of the lowest states in the series located below the He+(N=2) ionization threshold in the unscreened case. At variance with oneelectron atoms (where shape resonance widths vary monotonically with the screening strength) the evolution of the Auger width with respect to screening is found to be different for each series represented by (K,T)A pseudoquantum numbers until resonances merge into the upper electronic continuum, when crossing the He+(2s) threshold. We conclude from our ab initio calculations that, although resonances pertaining to the same (K,T)A series share a similar tendency in their widths against the screening strength, general propensity rules for the robustness of lifetimes, based on the isomorphic series in the (K,T)A classification, cannot be established in plasmaembedded helium.Physical Review A 07/2013; 88(1). DOI:10.1103/PhysRevA.88.012702 · 2.81 Impact Factor  [Show abstract] [Hide abstract]
ABSTRACT: Atomic autoionization following photoabsorption is a typical example of quantum interferences governed by electronelectron correlation. Coherence between direct photoionization and autoionization paths results in "Fano profiles", widely explored in atoms in the last 60 years. The advent of femto and attosecond laser technology made timeresolved images of the delayed electron ejection in autoionization accessible, leading to the reemergence of such studies in atomic systems. The counterpart molecular phenomena show the richness, as well as the complexity, added by nuclear motion, which may proceed on similar time scales. However, Fano profiles are usually absent in measured molecular photoionization cross sections and an unequivocal parametrization of molecular autoionization signatures, similar to that introduced by Fano in atoms [U. Fano, Phys. Rev. 1961, 124, 1866] has not yet been achieved. In this work we introduce a simple semiclassical model that accounts for all the features observed in H2 photoionization and demonstrate that the interference structures observed in dissociative ionization spectra are almost exclusively due to the phase accumulated in the nuclear motion. Furthermore, we show that the temporal buildup of these structures in the energydifferential cross sections is also determined by nuclear motion. We validate our models by comparing with fulldimensional ab initio calculations solving the timedependent Schrödinger equation.ChemPhysChem 05/2013; 14(7). DOI:10.1002/cphc.201200974 · 3.42 Impact Factor  [Show abstract] [Hide abstract]
ABSTRACT: (IOP Select 2013  Also LabTalk available) We study the photoionization and autoionization of Helium atom subject to ultrashort laser pulses by using a Feshbach formalism in the time domain. We solve the timedependent Schr\"odinger equation in terms of a configuration interaction (CI) spectral method, in which the total wavefunction is expanded with configurations defined within boundlike ($\mathcal{Q}$) and scatteringlike ($\mathcal{P}$) halfspaces. The method allowsone to provide accurate descriptions of both the atomic structure (energy positions and widths) and the photodynamics. We illustrate our approach by i) calculating the timeresolved onephoton ionization below the He$^+$ ($n$=2) ionization threshold, from $1^1S^e$ and $2 ^1P^o$ initial states, then reaching the lowest autoionizing states of $^1S^e$, $^1P^o$ and $^1D^e$ final symmetries ii) studing the temporal formation of the Fano profile of $^1P^o$ resonances and iii) showing its performance in obtaining the perturbative longtime limit of one and twophoton ionization cross sections using ultrashort laser pulses following a recently developed procedure in Phys. Rev. A, {\bf 77}, 032716 (2008).Journal of Physics B Atomic Molecular and Optical Physics 03/2013; 46(5):055601. DOI:10.1088/09534075/46/5/055601 · 1.98 Impact Factor  [Show abstract] [Hide abstract]
ABSTRACT: We study the dissociative photoionization of D2 by an attosecond pulse train (APT) in the presence of a nearinfrared (IR) field. Strong oscillations in the D+ kinetic energy release spectrum with a half period of the optical cycle of the infrared field are observed and attributed to interferences between ionization pathways involving different harmonic orders of the APT due to the IRinduced coupling between the 1sσg and 2pσu ionization channels.Journal of Physics Conference Series 11/2012; 388(2):2028. DOI:10.1088/17426596/388/2/022028  [Show abstract] [Hide abstract]
ABSTRACT: A time dependent Feshbach method is implemented to study the correlated electron dynamics of He doubly excited states below the He+ (N=2) ionization threshold, using ultrashort laser pulses in XUVpump IRprobe delay schemes.Journal of Physics Conference Series 11/2012; 388(3):2039. DOI:10.1088/17426596/388/3/032039  [Show abstract] [Hide abstract]
ABSTRACT: In this work, circular dichroism in H2 (D2) photoionization is studied in detail. We have selected several photon energies for a case study: 19 eV for which only direct ionization to the 1sσg ionization channel is present, 27 eV where autoionization of Q1 1Σ+u doubly excited states takes place, and 32.5 eV for which autoionization from Q1 and doubly excited states and direct ionization to 1sσg and 2pσu channels strongly interfere. The latter case shows clear evidence of different behavior of the photoionization against radiation helicity.Journal of Physics Conference Series 11/2012; 388(2):2019. DOI:10.1088/17426596/388/2/022019  [Show abstract] [Hide abstract]
ABSTRACT: We present a study on the 1,3Se, 1,3P° and 1,3 De He resonant states below the He+ (N = 2) threshold under the influence of a plasma environment, when the Debye screening length is varied. The interaction between all charged particles is modeled with Yukawalike screened Coulomb potentials. We make use of the Feshbach projector method to characterize resonant states, implemented by using explicitly correlated CIwave functions.Journal of Physics Conference Series 10/2012; 388(15). DOI:10.1088/17426596/388/15/152034  [Show abstract] [Hide abstract]
ABSTRACT: We report experiments where hydrogen molecules were dissociatively ionized by an attosecond pulse train in the presence of a nearinfrared field. Fragment ion yields from distinguishable ionization channels oscillate with a period that is half the optical cycle of the IR field. For molecules aligned parallel to the laser polarization axis, the oscillations are reproduced in twoelectron quantum simulations, and can be explained in terms of an interference between ionization pathways that involve different harmonic orders and a laserinduced coupling between the 1sσ(g) and 2pσ(u) states of the molecular ion. This leads to a situation where the ionization probability is sensitive to the instantaneous polarization of the molecule by the IR electric field and demonstrates that we have probed the IRinduced electron dynamics with attosecond pulses.Physical Review Letters 07/2011; 107(4):043002. DOI:10.1103/PhysRevLett.107.043002 · 7.51 Impact Factor  [Show abstract] [Hide abstract]
ABSTRACT: The delayed autoionization of H2 doubly excited states into channels of different inversion symmetry gerade and ungerade is investigated by using pulses of attosecond duration (isolated or packed in trains), linearly polarized along the molecular axis. It has been shown in previous work, by using XUV laser pulses with durations of 4 fs or longer, that the molecular frame photoelectron angular distributions (MFPAD) associated with the dissociative channel H+ + H(nℓ) are not symmetric with respect to the inversion center of the molecule. In contrast, the MFPADs become symmetric for shorter fs pulses. Here we show that, although this is still the case for pulses of attosecond duration, the combination of two of these pulses with a controlled time delay may still lead to asymmetric MFPADs. From the analysis of the time evolution of the calculated MFPADs, we propose a way to elucidate autoionization lifetimes of molecular resonant states. © 2010 Wiley Periodicals, Inc. Int J Quantum Chem 110:2462–2471, 2010International Journal of Quantum Chemistry 11/2010; 110(13). DOI:10.1002/qua.22586 · 1.43 Impact Factor  [Show abstract] [Hide abstract]
ABSTRACT: Applications of the Feshbach formalism to systems of more than two active electrons are very scarce due to practical limitations in the construction of the projection operators P and Q that are inherent to the theory. As a consequence, most previous applications rely on the use of approximate quasiprojection operators, whose theoretical justification is not yet clear. In this work, an implementation of the Feshbach formalism for threeelectron atoms is presented that includes all the ingredients of the original formalism. Energy positions and autoionization widths of the lowest 2Se, 2Po, and 2De autoionizing states of Li and Ne7+ have been evaluated. The results show that the use of quasiprojection operators is justified for the evaluation of resonant positions. However, for the 2Se states of Li, the use of quasiprojection operators can lead to errors in the autoionization widths of the order of 100%.Physical Review A 08/2010; 82(2). DOI:10.1103/PhysRevA.82.022501 · 2.81 Impact Factor  [Show abstract] [Hide abstract]
ABSTRACT: Circular dichroism is a consequence of chirality. However, nonchiral molecules can also exhibit it when the measurement itself introduces chirality, e.g., when measuring molecularframe photoelectron angular distributions. The few such experiments performed on homonuclear diatomic molecules show that, as expected, circular dichroism vanishes when the molecularframe photoelectron angular distributions are integrated over the polar electron emission angle. Here we show that this is not the case in resonant dissociative ionization of H2 for photons of 3035 eV, which is the consequence of the delayed ionization from molecular doubly excited states into ionic states of different inversion symmetry.Physical Review Letters 06/2010; 104(23):233003. DOI:10.1103/PhysRevLett.104.233003 · 7.51 Impact Factor  [Show abstract] [Hide abstract]
ABSTRACT: For the past several decades, we have been able to directly probe the motion of atoms that is associated with chemical transformations and which occurs on the femtosecond (10(15)s) timescale. However, studying the inner workings of atoms and molecules on the electronic timescale has become possible only with the recent development of isolated attosecond (10(18)s) laser pulses. Such pulses have been used to investigate atomic photoexcitation and photoionization and electron dynamics in solids, and in molecules could help explore the prompt charge redistribution and localization that accompany photoexcitation processes. In recent work, the dissociative ionization of H(2) and D(2) was monitored on femtosecond timescales and controlled using fewcycle nearinfrared laser pulses. Here we report a molecular attosecond pumpprobe experiment based on that work: H(2) and D(2) are dissociatively ionized by a sequence comprising an isolated attosecond ultraviolet pulse and an intense fewcycle infrared pulse, and a localization of the electronic charge distribution within the molecule is measured that dependswith attosecond time resolutionon the delay between the pump and probe pulses. The localization occurs by means of two mechanisms, where the infrared laser influences the photoionization or the dissociation of the molecular ion. In the first case, charge localization arises from quantum mechanical interference involving autoionizing states and the laseraltered wavefunction of the departing electron. In the second case, charge localization arises owing to laserdriven population transfer between different electronic states of the molecular ion. These results establish attosecond pumpprobe strategies as a powerful tool for investigating the complex molecular dynamics that result from the coupling between electronic and nuclear motions beyond the usual BornOppenheimer approximation.Nature 06/2010; 465(7299):7636. DOI:10.1038/nature09084 · 41.46 Impact Factor  [Show abstract] [Hide abstract]
ABSTRACT: We used a splitmirror setup attached to a reaction microscope at the freeelectron laser in Hamburg (FLASH) to perform an XUVpump–XUVprobe experiment by tracing the ultrafast nuclear wavepacket motion in the D2+(1sσg) with <10 fs time resolution. Comparison with timedependent calculations shows excellent agreement with the measured vibrational period of 22±4 fs in D2+, points to the importance of accurately knowing the internuclear distancedependent ionization probability, and paves the way to control sequential and nonsequential twophoton doubleionization contributions.Physical Review A 05/2010; 81(5). DOI:10.1103/PhysRevA.81.051402 · 2.81 Impact Factor  [Show abstract] [Hide abstract]
ABSTRACT: Twophoton double ionization (TPDI) of D2 is studied for 38eV photons at the Free Electron Laser in Hamburg (FLASH). Based on model calculations, instantaneous and sequential absorption pathways are identified as separated peaks in the measured D++D+ fragment kinetic energy release (KER) spectra. The instantaneous process appears at high KER, corresponding to ionization at the molecule’s equilibrium distance, in contrast to sequential ionization mainly leading to lowKER contributions. Measured fragment angular distributions are in good agreement with theory.Physical Review A 02/2010; 81(2). DOI:10.1103/PhysRevA.81.021401 · 2.81 Impact Factor
Publication Stats
587  Citations  
108.54  Total Impact Points  
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Institutions

20032014

University of Antioquia
 Instituto de Física
Santa Fe de Antioquia, Antioquia, Colombia


20062007

Universidad Autónoma de Madrid
 Department of Chemistry
Madrid, Madrid, Spain
