Publications (27)28.92 Total impact
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Article: Determination of the nitrous oxide emission potential of deammonification under anoxic conditions.
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ABSTRACT: Various studies have been performed to determine nitrous oxide (N2O) emissions from conventional biological nitrogen removal processes in wastewater treatment like nitrification and denitrification in the main stream. However, with respect to the overall emissions of a wastewater treatment plant, part-stream treatment for high-strength wastewater (e.g., sludge liquor) is also expected to hold a significant emission potential because of high concentrations and extreme boundary conditions. This paper presents results from a laboratory-scale study on nitrous oxide production by biomass from a deammonification process (nitritation + anammox) under anoxic conditions. It was discovered that N2O formation results from incomplete endogenous denitrification rather than anammox and is dependent on substrate availability. Based on direct measurements of the dissolved N2O concentrations in a sequencing batch reactor, the dynamic behavior of N2O production is characterized in more detail. The results show that, during anoxic conditions, the N2O emission potential of deammonification is significantly lower than from conventional denitrification.Water Environment Research 12/2011; 83(12):2199-210. · 0.88 Impact Factor -
Article: A new approach to energy-efficient treatment of wastewater produced by the fish industry in Vietnam.
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ABSTRACT: Economic growth in Vietnam in the last few years has brought about an increasing demand for energy and has had a severe environmental impact. Fish processing is one of the fastest-growing industries that discharge organically-polluted wastewater. To counter these environmental problems, new technologies for energy-efficient treatment are needed. By coupling innovative nitrogen removal systems with anaerobic treatment processes, it is possible to realise such technologies. In the present project, a combined deammonification and anaerobic carbon removal system is presented. Special requirements to enable reliable treatment are discussed, taking industrial wastewater characteristics into consideration. To evaluate energetic efficiency, energy balance calculations based on data from a fish-processing factory are made. The determined specific energy consumption and production rates show that energy recovery is possible, even when COD and nitrogen removal efficiencies of over 90% are achieved. Depending on the pre-treatment employed, energy recovery rates ranging from 0.6 to 2.5 kWh/mt raw fish can be reached.Water Science & Technology 01/2011; 64(1):279-85. · 1.12 Impact Factor -
Article: Practical identifiability of biokinetic parameters of a model describing two-step nitrification in biofilms.
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ABSTRACT: Parameter estimation and model calibration are key problems in the application of biofilm models in engineering practice, where a large number of model parameters need to be determined usually based on experimental data with only limited information content. In this article, identifiability of biokinetic parameters of a biofilm model describing two-step nitrification was evaluated based solely on bulk phase measurements of ammonium, nitrite, and nitrate. In addition to evaluating the impact of experimental conditions and available measurements, the influence of mass transport limitation within the biofilm and the initial parameter values on identifiability of biokinetic parameters was evaluated. Selection of parameters for identifiability analysis was based on global mean sensitivities while parameter identifiability was analyzed using local sensitivity functions. At most, four of the six most sensitive biokinetic parameters were identifiable from results of batch experiments at bulk phase dissolved oxygen concentrations of 0.8 or 5 mg O(2)/L. High linear dependences between the parameters of the subsets (KO2,AOB,muAOB) and (KO2,NOB,muNOB) resulted in reduced identifiability. Mass transport limitation within the biofilm did not influence the number of identifiable parameters but, in fact, decreased collinearity between parameters, especially for parameters that are otherwise correlated (e.g., muAOB) and KO2,AOB, or muNOB and KO2,NOB). The choice of the initial parameter values had a significant impact on the identifiability of two parameter subsets, both including the parameters muAOB and KO2,AOB. Parameter subsets that did not include the subsets muAOB and KO2,AOB or muNOB and KO2,NOB were clearly identifiable independently of the choice of the initial parameter values.Biotechnology and Bioengineering 05/2008; 101(3):497-514. · 3.95 Impact Factor -
Article: The valuation of malnutrition in the mono-digestion of maize silage by anaerobic batch tests.
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ABSTRACT: Anaerobic digestion is a technology which is used to produce methane from organic solids and energy crops. Especially in recent years, the fermentation of energy crops has become more and more important because of increasing costs for energy and special benefits for renewable energy sources in Germany. Anaerobic bacteria require macro and micro nutrients to grow. Absence of these elements can inhibit the anaerobic process significantly. In particular mono-substrates like maize or certain industrial wastewater often cannot provide all required nutrients. For this reason this research investigates the influence of substrate and trace elements on anaerobic digestion in detail. Different agricultural anaerobic biomasses are analysed with special regard to their trace element content. Based on these results, the influence of three trace elements (iron, cobalt, and nickel) on anaerobic digestion was studied in anaerobic batch tests at different sludge loading rates and for different substrates (maize and acetate). Biogas production was found to be 35% for maize silage and up to 70% higher for acetate with trace element dosage than in the reference reactor.Water Science & Technology 02/2008; 58(7):1453-9. · 1.12 Impact Factor -
Article: Anaerobic treatment of municipal wastewater using the UASB-technology.
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ABSTRACT: The anaerobic treatment of municipal wastewater enables new applications for the reuse of wastewater. The effluent could be used for irrigation as the included nutrients are not affected by the treatment. Much more interesting now are renewable energies and the retrenchment of CO(2) emission. With the anaerobic treatment of municipal wastewater, not only can the CO(2) emission be reduced but "clean" energy supply can be gained by biogas. Most important for the sustainability of this process is the gathering of methane from the liquid effluent of the reactor, because the negative climate-relevant effect from the degassing methane is much higher than the positive effect from saving CO(2) emission. In this study, UASB reactors were used with a flocculent sludge blanket for the biodegradation of the carbon fraction in the wastewater with different temperatures and concentrations. It could be shown that the positive effect is much higher for municipal wastewater with high concentrations in hot climates.Water Science & Technology 02/2007; 56(10):37-44. · 1.12 Impact Factor -
Article: Experimental and model-based evaluation of the role of denitrifying polyphosphate accumulating organisms at two large scale WWTPs in northern Poland.
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ABSTRACT: The capabilities of denitrifying Polyphosphate Accumulating Organisms (DPAOs) in two large-scale plants in northern Poland performing enhanced biological phosphorus removal (EBPR) were evaluated in this study. A series of batch tests with the process biomass aimed at the measurements of phosphate release (with artificial substrate and real wastewater) and subsequent phosphate uptake under anoxic/aerobic conditions. The process kinetics were predicted using ASM2d implemented in the GPS-X ver. 4.0.2 simulation package. The results from one experimental series (summer) were used for the model calibration, whereas the results from another series (spring) were used for the model validation. The model parameters were also accurately confirmed by predictions of the accompanying field measurements in the full-scale bioreactors. The experimental and simulation results revealed that a relatively small fraction of PAO could denitrify (eta(NO3,PAO) = 0.32). The denitrification rates associated with the anoxic storage of PP and the anoxic growth of PAO only constituted 16.0-21.0% of the denitrification rates associated with the anoxic activity of "ordinary" heterotrophs.Water Science & Technology 02/2006; 54(8):73-81. · 1.12 Impact Factor -
Article: Modification of ASM3 for the determination of biomass adsorption/storage capacity in bulking sludge control.
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ABSTRACT: The selector activated sludge (SAS) systems are known to prevent excessive growth of filamentous microorganisms responsible for bulking sludge, but these systems were hardly ever modelled. This study aimed to develop a model capable of predicting rapid substrate removal in the SAS systems. For this purpose, the Activated Sludge Model No. 3 (ASM3) was extended with three processes (adsorption, direct growth on the adsorbed substrate under aerobic or anoxic conditions). The modified ASM3 was tested against the results of batch experiments with the biomass originating from two full-scale SAS systems in Germany. The endogenous biomass was mixed with various readily biodegradable substrates (acetate, peptone, glucose and wastewater) and the utilisation of substrate (expresses as COD) and oxygen uptake rates (OURs) were measured during the experiments. In general, model predictions fitted to the experimental data, but a considerable number of kinetic (5) and stoichiometric (2) parameters needed to be adjusted during model calibration. The simulation results revealed that storage was generally a dominating process compared to direct growth in terms of the adsorbed substrate utilisation. The contribution of storage ranged from 65-71% (Plant A) and 69-92% (Plant B).Water Science & Technology 02/2006; 53(3):91-9. · 1.12 Impact Factor -
Article: Integrated operation of sewer system and WWTP by simulation-based control of the WWTP inflow.
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ABSTRACT: In recent years numerical modelling became a standard procedure to optimise urban wastewater systems design and operation by integration. For dynamic control of the wastewater teatment plant (WWTP) inflow, a model-based predictive concept is introduced aiming at improving the receiving water quality. An on-line simulator running parallel to the real WWTP operation reflects the actual state of operation and provides this model information to a prognosis tool which determines the best option for the WWTP inflow. The investigations showed that it is possible to reduce the NH4-N peak concentrations in the receiving water by dynamic WWTP inflow control based on predictive scenario analysis.Water Science & Technology 02/2005; 52(5):195-203. · 1.12 Impact Factor -
Article: Deammonification in the Moving‐Bed Process for the Treatment of Wastewater with High Ammonia Content
Chemical Engineering & Technology 01/2005; 28(1):49 - 52. · 1.60 Impact Factor -
Article: Einsatz der Deammonifikation im Moving‐Bed‐Verfahren zur Behandlung hoch stickstoffhaltiger Abwässer
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ABSTRACT: No abstracts.Chemie Ingenieur Technik 02/2004; 76(3):325 - 328. · 0.59 Impact Factor -
Article: Model-based evaluation on the conversion ratio of ammonium to nitrite in a nitritation process for ammonium-rich wastewater treatment.
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ABSTRACT: Modeling for nitritation process was discussed and analyzed quantitatively for the factors that influence nitrite accumulation. The results indicated that pH, inorganic carbon source and Hydraulic Retention Time (HRT) as well as biomass concentration are the main factors that influenced the conversion ratio of ammonium to nitrite. A constant high pH can lead to a high nitritation rate and results in high conversion ratio on condition that free ammonia inhibition do not happen. In a CSTR system, without pH control, this conversion ratio can be monitored by pH variation in the reactor. The pH goes down far from the inlet level means a strongly nitrite accumulation. High concentration of alkalinity can promoted the conversion ratio by means of accelerating the nitritation rate through providing sufficient inorganic carbon source(carbon dioxide). When inorganic carbon source was depleted, the nitritation process stopped. HRT adjustment could be an efficient way to make the nitritation system run more flexible, which to some extent can meet the requirements of the fluctuant of inlet parameters such as ammonium concentration, pH, and temperature and so on. Biomass concentration is the key point, especially for a CSTR system in steady state, which was normally circumscribed by the characteristics of bacteria and may also affected by aeration mode and can be increased by prolonging the HRT on the condition of no nitrate accumulation when no recirculation available. The higher the biomass concentration is, the better the nitrite accumulation can be obtained.Journal of Environmental Sciences 02/2004; 16(6):1005-10. · 1.66 Impact Factor -
Article: Electrochemical oxidation of drug residues in water by the example of tetracycline, gentamicine and aspirin.
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ABSTRACT: Electro-chemical oxidation as a method to destroy drug residues like aspirin, tetracycline or gentamicine in water was investigated with C-anodes (modified by manganese oxides) and Pt anodes. The mechanism of aspirin and tetracycline oxidation and the influence of the biocide effect was observed using GC-MS and three different microbiological tests. In general, the biological availability increases with progressive oxidation of the antibiotics.Water Science & Technology 02/2004; 49(4):201-6. · 1.12 Impact Factor -
Article: Start up of deammonification process in one single SBR system.
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ABSTRACT: A process for autotrophic nitrogen removal named aerobic/anoxic deammonification wherein NH4+ is oxidized by nearly 50% to NO2- and subsequently the ammonia is converted together with the nitrite to molecular nitrogen (N2 gas), has come to full-scale application within the last few years. In this research, sludge from a biological rotation disk located at a landfill leachate plant at Mechernich, Germany, which is capable of performing the deammonification process, was used as seed sludge for acclimating deammonification activities in laboratory scale batch-reactors. In parallel, the same tests were performed with normal activated sludge. Research results indicated that deammonification activities could be obtained from the seeded reactor and also, with limited performance, from normal activated sludge in a single SBR system after several months acclimation. It was also seen that oxygen is an important factor that influences the deammonification from both the acclimatization process and process running. Further results were approved that report an impact of nitrite as a process intermediate on the closely related process of anaerobic ammonia oxidation ("Anammox"). However, limiting concentrations on a bacteria population performing deammonification were found to be different to those reported for a pure Anammox-culture. Also the influence of another intermediate, hydrazine, was tested for speeding up the acclimating process by inducing the deammonification activities and recovering the activities of deammonification from nitrite inhibition.Water Science & Technology 01/2004; 50(6):1-8. · 1.12 Impact Factor -
Article: Efficiency of the Activated Sludge Model no. 3 for German wastewater on six different WWTPs.
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ABSTRACT: In 1999, the Activated Sludge Model No. 3 by the IWA Task Group on Mathematical Modelling for the Design and Operation of Biological Wastewater Treatment was presented. The model is used for the simulation of nitrogen removal. The simulations in this paper were done on the basis of a new calibration of the ASM 3 by Koch et al., with the easily degradable COD measured by respiration. For modelling of EBPR the BioP-Module of Rieger et al., was used. Six German wastewater treatment plants were simulated during this research to test the existing set of parameters of the models on various large scale plants. It was shown that changes for nitrification and enhanced biological phosphorus removal in the set of biological parameters were necessary. Sensible parameters and recommended values are presented in this article. Apart from the values of the changed biological parameters, we will in our examination discuss the modelling of the different activated sludge systems and the influent fractioning of the COD. Two plants with simultaneous denitrification in the recirculation ditch (EBPR) are simulated, one with preliminary dentrification, one with intermittent denitrification (EBPR), one with cascade denitrification (EBPR), and one pilot plant according to the Johannesburg-process (EBPR) which was simulated over a period of three months.Water Science & Technology 02/2003; 47(11):211-8. · 1.12 Impact Factor -
Article: Control of the growth of Microthrix parvicelle by using an aerobic selector--results of pilot and full scale plant operation.
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ABSTRACT: A two-stage wastewater treatment plant experiences bulking sludge problems in winter, correlating with Microthixparvicella abundance. Pilot and full-scale studies of the use of an aerobic selector to control M. parvicella had little success, probably resulting from long chain fatty acid retention in foam at the tank surface. Initial pilot studies with reduced foam retention showed better results.Water Science & Technology 02/2002; 46(1-2):491-4. · 1.12 Impact Factor -
Article: Deammonification in biofilm systems: population structure and function.
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ABSTRACT: For the development of alternative concepts for the cost effective treatment of wastewaters with high ammonium content and low C/N-ratio, autotrophic consortia of micro-organisms with the ability to convert ammonium directly into N2 are of particular interest. Several full-scale industrial biofilm plants eliminating nitrogen without carbon source for years in a stable process, are suspected for some time to harbor active anaerobic ammonium oxidizers in deeper, oxygen-limited biofilm layers. In order to identify the processes of the single-stage nitrogen elimination (deammonification) in biofilm systems and to allocate them to the responsible micro-organisms, a deammonifying moving-bed pilot plant was investigated in detail. 15N-labelled tracer compounds were used as well as 16S rDNA libraries and in situ identification of dominant organisms. The usage of rRNA-targeted oligonucleotide probes (FISH) was particularly emphasized on the ammonium oxidizers of the beta-subclass of Proteobacteria and on the members of the order Planctomycetales. The combined application of these methods led to a deeper insight into the population structure and function of a deammonifying biofilm.Water Science & Technology 02/2002; 46(1-2):223-31. · 1.12 Impact Factor -
Article: Online-simulation of the WWTP to minimise the total emission of WWTP and sewer system.
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ABSTRACT: In this paper, the application of a WWTP-Online-Simulation with the objective to reduce the total emission into the receiving waters is explained. Apart from an introduction and a short description of the possible reduction potentials, first results of the current research project (financed by the German ministry BMBF) are presented. Results of the pilot plant with different experiments of increased stormwater inflow than usual and different control strategies showed the possibility to treat stormwater up to the quadruple dry-weather flow while still meeting the effluent values. However, this is not always guaranteed, and thus a monitoring system with integrated control strategies which is adapted to the load case "stormwater" with prognosis load cases becomes necessary. In the presented example, the simulation (Activated Sludge Model 2d) achieved an excellent match with the measured effluent values of the aeration tank (NH4-N, NO3-N) over a period of several months. The most important prerequisites for good (online-) simulation results are the exact knowledge of the plant and the plausibility and alternative concepts for the measured values in case of sensor failure.Water Science & Technology 02/2002; 45(3):101-8. · 1.12 Impact Factor -
Article: Integrated modelling as an analytical and optimisation tool for urban watershed management.
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ABSTRACT: In recent years numerical modelling has become a standard procedure to optimise urban wastewater systems design and operation. Since the models were developed for the subsystems independently, they did not support an integrated view to the operation of the sewer system, the wastewater treatment plant (WWTP) and the receiving water. After pointing out the benefits of an integrated approach and the possible synergy effects that may arise from analysing the interactions across the interfaces, three examples of modelling case studies carried out in Germany are introduced. With these examples we intend to demonstrate the potential of integrated models, though their development cannot be considered completed. They are set up with different combinations of self-developed and commercially available software. The aim is to analyse fluxes through the total wastewater system or to integrate pollution-based control in the upstream direction, that is e.g. managing the combined water retention tanks as a function of state variables in the WWTP or the receiving water. Furthermore the interface between the sewer and the WWTP can be optimised by predictive simulations such that the combined water flow can be maximised according to the time- and dynamics-dependent state of the treatment processes.Water Science & Technology 02/2002; 46(6-7):141-50. · 1.12 Impact Factor -
Article: DEAMMONIFICATION: A COST-EFFECTIVE TREATMENT PROCESS FOR NITROGEN-RICH WASTEWATERS
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ABSTRACT: Nitrogen elimination through autotrophic micro-organisms is currently in the focus of research projects on the treatment of wastewater with high nitrogen contents, for instance, to develop and fix dimensioning parameters for controlled full-scale applications. In fact, several leachate treatment plants have already shown for years that the steady operation of nitrogen elimination without carbon demand is possible. Due to the low growth rates of the participating microorganisms, these processes can be found in particular in biofilm systems, which also open the way for the simultaneous running of the two basic processes, in particular, the nitritation and the oxidization of the remaining ammonium by nitrite to N2 and H2O.In the following, we will discuss the basis of the operation results of industrial and pilot-scale plants the operation stability of the aerobic/anoxic deammonification, and outline our experiences, in particular, for the conversion in biofilm systems and for the treatment of leachate, sludge liquor and industrial wastewaters.Proceedings of the Water Environment Federation. 12/2001; -
Article: Suspended solids from industrial and municipal origins.
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ABSTRACT: The origins of suspended solids are the effluents of municipal and industrial wastewater treatment plants and storm sewage treatment. This paper deals with the sources of industrial and municipal wastewater treatment and the single treatment of side streams. An overview of the common treatment processes is given and the main sinks for suspended solids are named and described. The food industry is based on the processing of organic matter (fruits, etc.). During the single processing steps three main fractions occur, inorganic material (e.g., from the washing step), organic residues (e.g., the peel), and suspended solids (SS) in the wastewater. Today higher rates of recycling (water and raw materials) can be found in all kinds of industrial processes. The principle is that avoidance should take precedence over utilization which should take precedence over disposal. Numerous possibilities of production-integrated measures exist, e.g., conveyance of production circuits, product recovery, and stepped cleaning. Despite and/or due to these efforts, huge amounts of residues occur. They are the main sink for suspended solids. Only seldom is landfilling used to treat these residues. Usually utilization as animal nourishment or biological (aerobic or anaerobic) or thermal (incineration) treatment methods are used. Huge capacities for a codigestion of agroindustrial residues (substrates) and wastewater sludge can be found in municipal digesters. As most of the food processing factories are indirect dischargers, the largest amount of the SS fraction in the wastewater is led to municipal wastewater treatment plants. Rarely, a connection between the SS concentrations in the influent and those in the effluent can be observed in conventional wastewater treatment. As a polishing step, filtration methods gain more and more importance with regard to suspended solids removal.Ecotoxicology and Environmental Safety 11/2001; 50(2):135-42. · 2.29 Impact Factor
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Institutions
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2003–2011
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Leibniz Universität Hannover
- Institute of Water Quality and Waste Management
Hannover, Lower Saxony, Germany
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