Martine G de Vos

VU University Amsterdam, Amsterdamo, North Holland, Netherlands

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Publications (6)6.68 Total impact

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    ABSTRACT: There are several studies on bioaccumulation and biomagnification of nonylphenol (NP) and its ethoxylates (NPEOs), but their toxico-kinetic mechanisms remain unclear. In the present investigation, we explored the accumulation of NP and NPEOs in estuarine-marine food chains with a bioaccumulation model comprising five trophic levels. Using this model, we estimated uptake and elimination rate constants for NPEOs based on the organisms' weight and lipid content and the chemicals' Kow. Further, we calculated accumulation factors for NP and NPEOs, including biota-sediment accumulation factors (BSAF) and biomagnification factors (BMF), and compared these to independent field measurements collected in the Western Scheldt estuary in The Netherlands and field data reported in the literature. The estimated BSAF values for NP and total NPEOs were below 1 for all trophic levels. The estimated BMF values were around 1 for all trophic levels except for the highest level (carnivorous mammals and birds). For this trophic level, the estimated BMF value varied between 0.1 and 2.4, depending on the biotransformation capacity. For all trophic levels, except primary producers, the accumulation estimates that accounted for biotransformation of NPEOs into NP were closer to the field data than model estimates that did not include biotransformation, indicating that NP formation by biotransformation of NPEOs might occur in organisms. Copyright © 2015 Elsevier Ltd. All rights reserved.
    Chemosphere 05/2015; 138:33-39. DOI:10.1016/j.chemosphere.2015.05.040 · 3.34 Impact Factor
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    ABSTRACT: Het PBL-normenkader voor modellen maakt inzichtelijk of noodzakelijke procedures rond de ontwikkeling, het beheer en het gebruik van modellen correct doorlopen worden en is dus een praktisch regelgevend instrument voor kwaliteitszorg rond modellen. Aan de hand van de in het normenkader vastgestelde normen beoordeelt het PBL modellen op een uniforme manier. Het normenkader bestaat uit een serie vragen (normen) met toelichtingen en aandachtspunten. De antwoorden moeten altijd gemotiveerd worden. Bij de motivatie moet aangegeven worden in welke mate aan de aandachtspunten voldaan is.
  • Martine G. de Vos · Willem Robert van Hage · Jan Wielemaker · Guus Schreiber ·
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    ABSTRACT: In a recent approach, Baader and Distel proposed an algorithm to axiomatize all terminological knowledge that is valid in a given data set and is expressible in the description logic ELK. This approach is based on the mathematical theory of formal concept ...
    Proceedings of the seventh international conference on Knowledge capture; 06/2013
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    ABSTRACT: Aim This paper presents a tool for long-term global change studies; it is an update of the History Database of the Global Environment (HYDE) with estimates of some of the underlying demographic and agricultural driving factors. Methods Historical population, cropland and pasture statistics are combined with satellite information and specific allocation algorithms (which change over time) to create spatially explicit maps, which are fully consistent on a 5′ longitude/latitude grid resolution, and cover the period 10,000 bc to ad 2000. Results Cropland occupied roughly less than 1% of the global ice-free land area for a long time until ad 1000, similar to the area used for pasture. In the centuries that followed, the share of global cropland increased to 2% in ad 1700 (c. 3 million km2) and 11% in ad 2000 (15 million km2), while the share of pasture area grew from 2% in ad 1700 to 24% in ad 2000 (34 million km2) These profound land-use changes have had, and will continue to have, quite considerable consequences for global biogeochemical cycles, and subsequently global climate change. Main conclusions Some researchers suggest that humans have shifted from living in the Holocene (emergence of agriculture) into the Anthropocene (humans capable of changing the Earth's atmosphere) since the start of the Industrial Revolution. But in the light of the sheer size and magnitude of some historical land-use changes (e.g. as result of the depopulation of Europe due to the Black Death in the 14th century and the aftermath of the colonization of the Americas in the 16th century) we believe that this point might have occurred earlier in time. While there are still many uncertainties and gaps in our knowledge about the importance of land use (change) in the global biogeochemical cycle, we hope that this database can help global (climate) change modellers to close parts of this gap.
    12/2010; 20(1):73 - 86. DOI:10.1111/j.1466-8238.2010.00587.x
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    ABSTRACT: The environmentally persistent perfluorooctane sulfonate (PFOS) is a perfluoroalkylated acid (PFA), which has been found to accumulate and biomagnify through food webs all over the world. In the present investigation, the accumulation kinetics of PFOS was explored using the bioaccumulation model OMEGA. As accumulation behavior of PFOS may show similarities to fatty acids as well as to neutral organic compounds, different modeling approaches were used. Accumulation kinetics of PFOS was modeled similar to (1) moderately and (2) highly hydrophobic compounds, (3) metals and (4) as a combination of hydrophobic compounds and metals. Modeled elimination and uptake rate constants were compared to empirical rate constants from literature. Subsequently, model predictions were compared to field-based biota-suspended solids accumulation ratios (BSAF) in the estuarine food chain of the Western Scheldt, The Netherlands. Results show that uptake of PFOS is comparable to moderately hydrophobic compounds and elimination is best described by elimination kinetics of metals. These observations indicate that the accumulation behavior of PFOS is comparable to that of short and medium chained fatty acids.
    Chemosphere 03/2008; 70(10):1766-73. DOI:10.1016/j.chemosphere.2007.08.038 · 3.34 Impact Factor
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    Martine De Vos · Willem Robert Van Hage · Jan Ros · Guus Schreiber ·
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    ABSTRACT: Spreadsheets are frequently used by scientists to store and analyze research data. To enable integration and reusability of scientific spreadsheet data it is important to explicate the underlying concepts and relations. In this paper we explore to which extent the conceptual model of a research project can be recognized in its spreadsheet implementation. We perform a manual analysis of spreadsheets of existing research from the domain of environmental science. We formally describe the semantics of the spreadsheets in an ontology and record our approach in heuristics. We interview the original developers of the spreadsheets to compare our findings with their views. Our reconstructed conceptual model does not conflict with the developer's views, but represents a different perspective, as the developers are primarily focussed on the calculation workflow.

Publication Stats

240 Citations
6.68 Total Impact Points

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  • 2013-2015
    • VU University Amsterdam
      • Department of Computer Science
      Amsterdamo, North Holland, Netherlands
  • 2010
    • PBL Netherlands Environmental Assessment Agency
      's-Gravenhage, South Holland, Netherlands
  • 2008
    • Radboud University Nijmegen
      • Department of Environmental Science
      Nymegen, Gelderland, Netherlands