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International Journal of Surface & Coatings Technology, v.203, 3708-3717 (2009).
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ABSTRACT: The influence of a nitridation treatment on the microstructure and the properties of (W,Ti)C-based cemented carbides with Co and Ni binders is investigated. Nitridation results in the formation of a very fine-grained (Ti,Ta,Nb)(C,N) phase (γN-phase) with inclusions of binder and WC clusters in the near-surface region of the cemented carbides. Rietveld refinements of X-ray diffractograms reveal differences in the domain size and the microstrains of the γN-phase for cemented carbides with Co-binder and Ni-binder. Nitridation reduces the domain size and increases microstrains in the γ-phase. The chemical composition, the morphology and defects of the binder were investigated by TEM/EDX before and after the nitridation treatment. The results reveal that a high nitrogen activity leads to the preferred dissolution of the core-rim structure of the mixed cubic carbide grains during the formation of the γN-phase. The nitridation heat treatment improves the wear and corrosion resistance of cemented carbides with both Co-binder and Ni-binder.
Surface and Coatings Technology 202(24):5962-5975. · 1.87 Impact Factor
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Fortschritte in der Metallographie (2006),239-246.
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Surf. Coat. Technol. 201(2006)3314,3327.
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Mat. Wiss. Werkstofftech. 38(2007)11,907-914.
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Int. J. Refract. Met. Hard Mater. 27(2009),768-776.
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ABSTRACT: Cemented carbides coated with CVD multilayers are commonly used in metal cutting turning and milling operations. For many applications, a micro-blasting finishing procedure based on an impact treatment of the surfaces is carried out in order to smooth the coated surface and reduce sharp cutting edges. In this work, micro-blasting with corundum in aqueous solution at pressures between 0.05 and 0.3 MPa was applied to CVD TiN/Ti(C,N)/κ-Al2O3 multilayer coatings deposited onto cemented carbides in order to investigate its influence on the micro-topography, microstructure and residual stresses. The results showed that the micro-blasting reduces the surface roughness and affects the coating thickness. TEM investigations revealed no significant changes on the microstructure of the κ-Al2O3 top layer. Synchrotron X-ray investigations showed that the residual stress state of the as-deposited κ-Al2O3 top layer is not affected by the micro-blasting treatment under the conditions investigated.
Surface and Coatings Technology.