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ABSTRACT: Trace metal accumulation in tree rings of Jeffrey pines (Pinus jeffreyi) from the Lake Tahoe basin (Sierra Nevada, CA, USA) was determined using high resolution inductively coupled plasma mass
spectrometry (HR-ICP–MS). The objectives of this study were (1) to establish baseline values for aluminium (Al), chromium
(Cr), manganese (Mn), iron (Fe), cobalt (Co), nickel (Ni), copper (Cu), zinc (Zn), strontium (Sr), cadmium (Cd), barium (Ba),
and lead (Pb); (2) to investigate the intra-tree and inter-tree variability of these trace metals, and (3) to assess differences
in metal concentrations related to automobile traffic. Two field collection sites were selected with similar ecologic attributes,
one proximal to a heavily traveled highway, and the other isolated from any local source of auto emissions. At each site two
trees with similar features were selected, and two increment cores collected from each tree. Cores were cross-dated, cleaned
of contamination, dissected into 5-year increments, ashed, and acid digested, before analysis by HR-ICP–MS. Time series spanning
191–326years were developed for the 12 trace metals. Variability was high within and between trees, most likely because of
physiologic mechanisms for element sequestration and allocation. The best intra-tree correlation was found for Ba, Sr, Mn,
and Co; of these elements, Co showed an overall increase over time, whereas Sr and Ba displayed an opposite trend, and Mn
fluctuated over time. Mean Co concentration at the near-highway site was higher, whereas mean Sr, Ba, and Mn concentrations
were lower, than at the control site.
Journal of Forest Research 04/2012; 13(6):347-356. · 0.77 Impact Factor
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ABSTRACT: The acid content of ice core samples provides information regarding the history of volcanism, biogenic activity, windblown dust, forest fires, and pollution-induced acid rain. A continuous ice core analysis allows for collection of high-resolution data in a very efficient manner, but this technique has not been readily applied to the measurement of pH and acidity in ice cores. The difficulty arises because the sample is highly undersaturated with respect to carbon dioxide (CO(2)) immediately after melting, making it difficult to maintain stable concentrations of dissolved carbon dioxide and carbonic acid (H(2)CO(3)). Here, we present a solution to this problem in the form of a small flow-through bubbling chamber that is supplied with a known concentration of CO(2). The bubbling action allows for quick equilibration while the small size of the chamber limits sample mixing in order to maintain high resolution. Thorough error analysis provides a measurement uncertainty of ±0.20 μM or ±5% of the acidity value, whichever is greater, and the T95 signal response time is determined to be 1.25 min. The performance of the technique is further evaluated with data from a 63-year ice core from northwest Greenland for which all major ion species were also measured. The measured acidity closely matches the acidity derived from a charge balance calculation, indicating that all of the analytes were measured accurately. The performance specifications that we provide are applicable to ice cores with low concentrations of alkaline dust (<500 ppb), which includes the vast majority of ice cores that are collected. To date, the method has not been evaluated with samples containing high alkaline dust concentrations, such as Greenland cores from the last glacial period, where measurement could be made difficult by memory effects as particles coat the internal surfaces of the sample stream.
Environmental Science & Technology 12/2011; 46(3):1659-66. · 4.80 Impact Factor
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ABSTRACT: A novel 'selection curve' method is developed to interpret annual layers in the West Antarctic ice sheet (WAIS) Divide ice core based on dielectric properties (DEP). Because dielectric measurements are non-contact and represent the integrated response of the ice volume, they are particularly useful for the brittle zone of the core. Seasonal differences in ice chemistry create an annual signal in DEP, though multiple peaks of varying strength within a year may complicate the interpretation of annual layers. The selection curve algorithm uses a spline curve whose shape selects successive annual peaks in plots of DEP. This spline curve was scaled to the average annual-layer thickness at a given depth, where the layer thickness was best estimated using the fast Fourier transform (FFT) power spectrum within a sliding 10 m window. To explore the accuracy and stability of the method, several spline curves were generated from varying lengths of calibration data taken from multiple depths in the WAIS core. Using 50 m of manually interpreted calibration data, the selection curve method matched a manual interpretation throughout the entire 1200 m dataset to within 2% root-mean-square error (RMSE). This method is equally applicable to glaciochemical and other time/depth series measurements.
Journal of Glaciology 08/2011; 57(204):763-769. · 2.30 Impact Factor
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ABSTRACT: 1] An updated accumulation map for Greenland is presented on the basis of 39 new ice core estimates of accumulation, 256 ice sheet estimates from ice cores and snow pits used in previous maps, and reanalysis of time series data from 20 coastal weather stations. The period 1950–2000 is better represented by the data than are earlier periods. Ice-sheet-wide accumulation was estimated based on kriging. The average accumulation (95% confidence interval, or ±2 times standard error) over the Greenland ice sheet is 30.0 ± 2.4 g cm À2 a À1 , with the average accumulation above 2000-m elevation being essentially the same, 29.9 ± 2.2 g cm À2 a À1 . At higher elevations the new accumulation map maintains the main features shown in previous maps. However, there are five coastal areas with obvious differences: southwest, northwest, and eastern regions, where the accumulation values are 20–50% lower than previously estimated, and southeast and northeast regions, where the accumulation values are 20–50% higher than previously estimated. These differences are almost entirely due to new coastal data. The much lower accumulation in the southwest and the much higher accumulation in the southeast indicated by the current map mean that long-term mass balance in both catchments is closer to steady state than previously estimated. However, uncertainty in these areas remains high owing to strong gradients in precipitation from the coast inland. A significant and sustained precipitation measurement program will be needed to resolve this uncertainty.
J. Geophys. Res. 01/2009; 114.
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ABSTRACT: 1] An analysis of 96 snow pit and ice cores distributed over the Greenland ice sheet is used to determine the main drivers of variability in the preserved records of nitrate concentration. The data set provides samples from spatially distributed locations, allowing us to investigate the effect of snow accumulation rate, temperature, and sublimation on nitrate concentration. The mean ice sheet concentration in the dry snow zone (2000 ! mean annual sea level (masl)) is 132 ng g À1 , ranging between 47 and 265 ng g À1 with a standard deviation of ±37 ng g À1 . Nitrate flux varies between 1.1 and 14.7 mg cm À2 a À1 with a mean of 4 ± 2 mg cm À2 a À1 . Large-scale spatial variability exists as a result of accumulation gradients, with concentration 5% greater in the northern plateau, yet flux over the northern plateau is 30% lower than the dry snow zone as a whole. While spatially, flux appears to be more dependent on accumulation, preservation of flux shows increasing dependence on concentration with increasing accumulation. The relationship between concentration and accumulation is nonlinear, showing less dependence in the low-accumulation regions versus high-accumulation regions. Accumulation alone is insufficient to account for the observed variability in nitrate flux in the low-accumulation regions, and evidence supports the need for additional components to a transfer function model for nitrate that includes photochemistry, temperature, and sublimation. Spatial variability across the ice sheet is nonuniform, and changes in nitrate concentration have occurred in some regions at a greater rate than others. While the data support that overall the ice sheet acts as an archive of paleoatmospheric concentration despite the effects of postdepositional processing, one needs to consider spatial variables to properly account for trends and variability in the records. This is tested by evaluating past spatial relationships and yields the result that the significant geographic shifts with respect to reactive N concentrations have occurred over the ice sheet in the past century.
J. Geophys. Res. 01/2009; 114.
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ABSTRACT: Toxic heavy metals emitted by industrial activities in the midlatitudes are transported through the atmosphere and deposited in the polar regions; bioconcentration and biomagnification in the food chain mean that even low levels of atmospheric deposition may threaten human health and Arctic ecosystems. Little is known about sources and long-term trends of most heavy metals before approximately 1980, when modern measurements began, although heavy-metal pollution in the Arctic was widespread during recent decades. Lacking detailed, long-term measurements until now, ecologists, health researchers, and policy makers generally have assumed that contamination was highest during the 1960s and 1970s peak of industrial activity in North America and Europe. We present continuous 1772-2003 monthly and annually averaged deposition records for highly toxic thallium, cadmium, and lead from a Greenland ice core showing that atmospheric deposition was much higher than expected in the early 20th century, with tenfold increases from preindustrial levels by the early 1900s that were two to five times higher than during recent decades. Tracer measurements indicate that coal burning in North America and Europe was the likely source of these metals in the Arctic after 1860. Although these results show that heavy-metal pollution in the North Atlantic sector of the Arctic is substantially lower today than a century ago, contamination of other sectors may be increasing because of the rapid coal-driven growth of Asian economies.
Proceedings of the National Academy of Sciences 09/2008; 105(34):12140-4. · 9.68 Impact Factor
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ABSTRACT: The Antarctic Peninsula has displayed significant climate change over recent decades. Understanding contemporaneous changes in accumulation is made difficult because the region's complex orography means that ice-core data are not necessarily representative of a wider area. In this paper, the patterns of regional spatial accumulation variability across the Antarctic Peninsula region are presented, based on an Empirical Orthogonal Function (EOF) analysis of European Centre for Medium Range Forecasts Reanalysis (ERA40) data over the 23-year period from 1979 through 2001. Annual and seasonal trends in the sign and strength of these patterns are identified, as is their relationship with mean sea level pressure, temperature and indices of large-scale circulation variability.The results reveal that the first pattern of accumulation variability on the Peninsula is primarily related to pressure in the circumpolar trough and the second pattern to temperature: together the two EOFs explain ∼45–65% of the annual/seasonal accumulation. The strongest positive trend in an EOF occurs with EOF2 in the austral autumn March-April-May (MAM). This is highly correlated with the Southern Annular Mode (SAM) in this season, suggesting stronger westerly winds have caused an increase in orographic precipitation along the west Antarctic Peninsula. A significant correlation with ENSO occurs only in the winter EOF1, associated with blocking in the Bellingshausen Sea.Inter-annual ERA40 accumulation is shown to compare favourably with an ice core in the south of the Peninsula, but, for a variety of reasons, correlates poorly with accumulation as measured in an ice core from the northern tip. Opposite trends in accumulation at these two sites can be explained by the spatial pattern and trend of EOF2 in MAM and thus by recent changes in the SAM. The results of this study will aid in the understanding of temporal accumulation changes observed in the regional ice-core record. Copyright © 2007 Royal Meteorological Society
International Journal of Climatology 11/2007; 28(11):1409 - 1422. · 2.91 Impact Factor
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ABSTRACT: Black carbon (BC) from biomass and fossil fuel combustion alters chemical and physical properties of the atmosphere and snow albedo, yet little is known about its emission or deposition histories. Measurements of BC, vanillic acid, and non-sea-salt sulfur in ice cores indicate that sources and concentrations of BC in Greenland precipitation varied greatly since 1788 as a result of boreal forest fires and industrial activities. Beginning about 1850, industrial emissions resulted in a sevenfold increase in ice-core BC concentrations, with most change occurring in winter. BC concentrations after about 1951 were lower but increasing. At its maximum from 1906 to 1910, estimated surface climate forcing in early summer from BC in Arctic snow was about 3 watts per square meter, which is eight times the typical preindustrial forcing value.
Science 10/2007; 317(5843):1381-4. · 31.20 Impact Factor
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ABSTRACT: Crustal dust in the atmosphere impacts Earth's radiative forcing directly by modifying the radiation budget and affecting cloud nucleation and optical properties, and indirectly through ocean fertilization, which alters carbon sequestration. Increased dust in the atmosphere has been linked to decreased global air temperature in past ice core studies of glacial to interglacial transitions. We present a continuous ice core record of aluminum deposition during recent centuries in the northern Antarctic Peninsula, the most rapidly warming region of the Southern Hemisphere; such a record has not been reported previously. This record shows that aluminosilicate dust deposition more than doubled during the 20th century, coincident with the approximately 1 degrees C Southern Hemisphere warming: a pattern in parallel with increasing air temperatures, decreasing relative humidity, and widespread desertification in Patagonia and northern Argentina. These results have far-reaching implications for understanding the forces driving dust generation and impacts of changing dust levels on climate both in the recent past and future.
Proceedings of the National Academy of Sciences 05/2007; 104(14):5743-8. · 9.68 Impact Factor
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ABSTRACT: 1] We report new century-scale ice core records of hydrogen peroxide (H 2 O 2), a major atmospheric oxidant, from 23 locations across the West Antarctic Ice Sheet (WAIS) and use the spatial variability of (multi-) annual mean H 2 O 2 concentrations in snow and firn to investigate the sensitivity of ice core H 2 O 2 preservation to mean annual temperature and accumulation rate. In agreement with the ice-air equilibrium partitioning, H 2 O 2 uptake in near-surface firn was found to be greatest at low temperatures, while postdepositional losses from degassing increase as accumulation rates decrease. This resulted in almost complete loss of H 2 O 2 at warm (>À25°C), low-accumulation sites (<13 cm yr À1), but excellent preservation of records at cold, high-accumulation sites. A two-parameter semiempirical model fitted to the 1911–1960 H 2 O 2 means across all sites predicts >94% deviations from the ice-air equilibrium at high-accumulation sites (>30 cm yr À1), but close-to-equilibrium values on the East Antarctic Plateau, where it is dry (<11 cm yr À1). It also estimates a weighted average of the annual atmospheric H 2 O 2 cycle of 1–3 pptv, about 10% of the levels at the bottom of the H 2 O 2 range observed in winter and early spring in coastal Antarctica. Sensitivities from the model fit suggest that recent changes of annual mean temperature observed in Antarctica have no noticeable effect on the H 2 O 2 record in the interior of West Antarctica and that interannual variability of annual H 2 O 2 is dominated by variations in regional-scale accumulation under the current WAIS climate. Intermittent correlations between the first PC time series of accumulation rate and H 2 O 2 concentration anomalies and the annualized SOI during the 20th century are statistically significant (r > 0.6, p < 0.05) during extended El Niño–La Niña events and explain the occurrence of significant spectral peaks at ENSO-like periodicities (2–7 years) in the H 2 O 2 record. Core records of H 2 O 2 at high-accumulation sites (>30 cm yr À1) are most suitable for detection of temporal changes in atmospheric concentration, although a long-term H 2 O 2 record will be well preserved under the current environment at the WAIS Divide core site.
J. Geophys. Res. 01/2006; 111.
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ABSTRACT: 1] Nitrate records from six Greenland ice cores covering the period 1789 to 1995 show a significant correlation in concentration for averaging periods greater than 10 years, as well as an approximately 60% increase in average concentration during the last 75 years. Annual nitrate fluxes contain low-frequency trends driven primarily by changes in concentration, while higher-frequency variability is driven by changes in snow accumulation. Increases in concentration yield nearly 30% higher nitrate flux (2.5 to 3.2 mg m À2 yr À1) and an 11% increase in variability during the 1895 to 1994 period versus the prior 100 years. Nitrate trends in the cores during the last 100 years are also correlated with global nitrate emissions, with a highly significant average r value of 0.93 for the six cores. During the period of anthropogenic influence, nitrate is positively correlated with the North Atlantic Oscillation, while prior to that the correlation is negative, and less significant, suggesting a link between transport of anthropogenic emissions and the North Atlantic Oscillation. Significant preanthropogenic periodicities identified through singular spectrum analysis show decadal variability in the nitrate record leading to shifts as great as 30% from the mean state but none as great as the anthropogenic-driven deviation.
J. Geophys. Res. 01/2006; 111.
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ABSTRACT: Satellite radar altimetry measurements indicate that the East Antarctic ice-sheet interior north of 81.6 degrees S increased in mass by 45 +/- 7 billion metric tons per year from 1992 to 2003. Comparisons with contemporaneous meteorological model snowfall estimates suggest that the gain in mass was associated with increased precipitation. A gain of this magnitude is enough to slow sea-level rise by 0.12 +/- 0.02 millimeters per year.
Science 07/2005; 308(5730):1898-901. · 31.20 Impact Factor
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ABSTRACT: The troposphere above the West Antarctic Ice Sheet (WAIS) was sampled for hydroperoxides at 21 locations during 2-month-long summer traverses from 2000 to 2002, as part of US ITASE (International Transantarctic Scientific Expedition). First time quantitative measurements using an HPLC method showed that methylhydroperoxide (MHP) is the only important organic hydroperoxide occurring in the Antarctic troposphere, and that it is found at levels ten times those previously predicted by photochemical models. During three field seasons, means and standard deviations for hydrogen peroxide (H2O2) were 321+/-158 pptv, 650+/-176 pptv and 330+/-147 pptv. While MHP was detected, but not quantified in December 2000, levels in summer 2001 and 2002 were 317+128 pptv and 304+/-172.2 pptv. Results from firn air experiments and diurnal variability of the two species showed that atmospheric H2O2 is significantly impacted by a physical snow pack source between 76 and 90degS, whereas MHP is not. We show strong evidence of a positive feedback between stratospheric ozone and H2O2 at the surface. Between November-27 and December-12 in 2001, when ozone column densities dropped below 220 DU (means in 2000 and 2001 were 318 DU and 334 DU, respectively), H2O2 was 1.7 times that observed in the same period in 2000 and 2002, while MHP was only 80% of the levels encountered in 2002. Photochemical box model runs suggest that NO and OH levels on WAIS are closer to coastal values, while Antarctic Plateau levels are higher, confirming that region to be a highly oxidizing environment. The modeled sensitivity of H2O2 and particularly MHP to NO offers the potential to use atmospheric hydroperoxides to constrain the NO background and thus estimate the past oxidation capacity of the remote atmosphere. Index Terms: 0365 Atmospheric Composition and Structure: Troposphere: composition and chemistry; 0322 Atmospheric Composition and Structure: Constituent sources and sinks; 1610 Global Change: Atmosphere (03 15,0325); 0736 Cryosphere: Snow (1827, 1863); 0724 Cryosphere: Ice Cores (4932) Keywords: hydrogen peroxide, methylhydroperoxide, Antarctica, air-snow exchange, stratospheric ozone, atmospheric oxidation capacity
02/2005;
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ABSTRACT: 1] In a yearlong investigation of the air-snow transfer function for nitrate (NO 3 À) at the Greenland Environmental Observatory, Summit (3203 m above sea level), surface snow concentrations measured every other day were compared with levels measured in 10 snow pits dug adjacent to accumulation stakes. Concentrations in the surface snow ranged from 0.4 to 34 mM with a mean of 2.9 ± 1.9 mM. Measured firn profiles in the snow pits had a maximum NO 3 À concentration of 12 mM and a mean of 2.7 ± 0.5 mM. Reconstructed profiles from surface snow observations and accumulation data closely matched the observed profiles. The small difference in preserved concentrations from observed surface snow concentrations gives evidence of only 7% postdepositional loss at this site (mean annual accumulation $23 g cm À2 yr À1). Removing the three highest outliers (which may originate from local sources) of surface snow concentration drops the mean to 2.7 mM, further demonstrating preservation. Results indicate that at this site accumulation is the most significant process affecting preservation of nitrate in the firn. Other rapid postdepositional processes may impact surface snow concentrations, but do not appear to significantly change the preserved record. The inverse analysis of converting preserved records to surface snow concentrations provides equivalent evidence of the same preservation.
J. Geophys. Res. 01/2004; 109.
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ABSTRACT: Impurities trapped in ice sheets and glaciers have the potential to provide detailed, high temporal resolution proxy information on paleo-environments, atmospheric circulation, and environmental pollution through the use of chemical, isotopic, and elemental tracers. We present a novel approach to ice-core chemical analyses in which an ice-core melter is coupled directly with both an inductively coupled plasma mass spectrometer and a traditional continuous flow analysis system. We demonstrate this new approach using replicated measurements of ice-core samples from Summit, Greenland. With this method, it is possible to readily obtain continuous, exactly coregistered concentration records for a large number of elements and chemical species at ppb and ppt levels and at unprecedented depth resolution. Such very-high depth resolution, multiparameter measurements will significantly expand the use of ice-core records for environmental proxies.
Environmental Science and Technology 02/2002; 36(1):7-11. · 5.23 Impact Factor
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ABSTRACT: Understanding the photochemistry of the Antarctic region is important for several reasons. Analysis of ice cores provides historical information on several species such as hydrogen peroxide and sulfur-bearing compounds. The former can potentially provide information on the history of oxidants in the troposphere and the latter may shed light on DMS-climate relationships. Extracting such information requires that we be able to model the photochemistry of the Antarctic troposphere and relate atmospheric concentrations to deposition rates and sequestration in the polar ice. This paper deals with one aspect of the uncertainty inherent in photochemical models of the high latitude troposphere: that arising from imprecision in the kinetic data used in the calculations. Such uncertainties in Antarctic models tend to be larger than those in models of mid to low latitude clean air. One reason is the lower temperatures which result in increased imprecision in kinetic data, assumed to be best characterized at 298K. Another is the inclusion of a DMS oxidation scheme in the present model. Many of the rates in this scheme are less precisely known than are rates in the standard chemistry used in many stratospheric and tropospheric models.
02/1999;
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ABSTRACT: 1] Sensitivity studies with physically based numerical air–snow–firn transfer models for formaldehyde (HCHO) and hydrogen peroxide (H 2 O 2) show that even though nonlinear processes determine the preservation of HCHO and H 2 O 2 in snow and firn, changes in atmospheric mixing ratios are linearly recorded in ice cores under otherwise constant environmental conditions. However, temperature, snowpack ventilation, and rate and timing of snow accumulation also affect the ice core records of reversibly deposited species and must be considered when inferring past atmospheric mixing ratios. The results of the sensitivity studies allow quantitative separation of these factors in ice core records. Past temperatures and accumulation rates are generally determined in ice cores and the preservation of HCHO and H 2 O 2 is not highly sensitive to snowpack ventilation, leaving changes in seasonality of snow accumulation as the main source of uncertainty in a reconstruction of past atmospheric mixing ratios., Sensitivity of hydrogen peroxide (H 2 O 2) and formaldehyde (HCHO) preservation in snow to changing environmental conditions: Implications for ice core records, J. Geophys. Res., 108(D1), 4023, doi:10.1029/2002JD002528, 2003.
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ABSTRACT: Average H 2 O 2 (HCHO) mixing ratios measured above the snowpack at South Pole were 278 pptv (103 pptv) in December 2000 and between 4 to 43 times (1.4 to 2.6) the expected value based on gas-phase photostationary state model calculations. The larger difference is realized if dry deposition of both species is included in the model. H 2 O 2 and HCHO fluxes from the snowpack were independently determined from gradient measurements in the air above the snow surface, from firn air measurements and from the temporal concentration changes in near-surface snow. On average, the snowpack at South Pole was releasing on the order of 1 x 10 13 and 2 x 10 12 molecules m -2 s -1 of H 2 O 2 and HCHO, respectively, in December 2000. This is consistent with the volumetric fluxes needed for the photostationary state model to reproduce the observed atmospheric mixing ratios of both H 2 O 2 and HCHO. The highly elevated levels of both species found in firn air further support the above estimates. In the case of HCHO, it was also shown that there was good agreement between the measured flux and the physical air-snow exchange model as driven by changes in snow temperature from winter to summer. Shading experiments suggest that the net production of HCHO within the snow by heterogeneous photochemical processes most likely do not exceed photochemical destruction by more than 15% of the measured fluxes. The very rapid changes observed in atmospheric HCHO, which are also seen in NO and OH, can be understood in terms of dynamical processes that lead to rapid changes in the atmospheric mixing depth.
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ABSTRACT: Annual and monthly snow accumulation for the Greenland Ice Sheet was derived from ECMWF forecasts [mainly 40-yr ECMWR Re-Analysis (ERA-40)] and further meteorological modeling. Modeled accumulation was validated using 58 ice core accumulation datasets across the ice sheet and was found to be 95% of the observed accumulation on average, with a mean correlation of 0.53 between modeled and observed. Many of the ice core datasets are new and are presented here for the first time. Central and northern interior parts of the ice sheet were found to be 10%–30% too dry in ERA-40, in line with earlier ECMWF analysis, although too much (>50% locally) snow accumulation was modeled for interior southern parts of Greenland. Nevertheless, 47 of 58 sites show significant correlation in temporal variability of modeled with observed accumulation. The model also captures the absolute amount of snow accumulation at several sites, most notably Das1 and Das2 in southeast Greenland. Mean modeled accumulation over the ice sheet was 0.279 (standard deviation 0.034) m yr−1 for 1958–2003 with no significant trend for either the ice sheet or any of the core sites. Unusually high accumulation in southeast Greenland in 2002/03 leads the authors to study meteorological synoptic forcing patterns and comment on the prospect of enhanced climate variability leading to more such events as a result of global warming. There is good agreement between precipitation measured at coastal meteorological stations in southern Greenland and accumulation modeled for adjacent regions of the ice sheet. There is no significant persistent relation between the North Atlantic Oscillation index and whole or southern Greenland accumulation. Author Posting. © American Meteorological Society 2006. This article is posted here by permission of American Meteorological Society for personal use, not for redistribution. The definitive version was published in Journal of Climate 19 (2006): 344–358, doi:10.1175/JCLI3615.1. JM acknowledges support from NASA’s Cryospheric Sciences Program and the Arctic Section of NSF’s Office of Polar Programs.