Jaehong Lim

Stanford University, Palo Alto, California, United States

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Publications (1)12.11 Total impact

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    ABSTRACT: As part of our studies of metal-catalyzed [m + n (+...o)] cycloadditions, we have previously reported the rhodium-catalyzed [5 + 2] cycloaddition of vinylcyclopropanes (VCPs) and pi-systems. These studies have led to Rh(I) complexes that catalyze these reactions in minutes at room temperature or in water without organic solvents. We describe a comparative evaluation of several chiral catalysts for the [5 + 2] reaction, evaluation of a preferred catalyst, [((R)-BINAP)Rh]+SbF6-, with substrates differing in substitution and tether types-producing enantiomeric excesses >/=95% for several systems. A predictive model for the selectivity is also presented.
    Journal of the American Chemical Society 06/2006; 128(19):6302-3. DOI:10.1021/ja058590u · 12.11 Impact Factor