Masaru Tanaka

The University of Tokyo, Edo, Tōkyō, Japan

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Publications (1)6.32 Total impact

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    ABSTRACT: [reaction: see text] High stereoselectivities were found in a wide range of superacid-catalyzed Pictet-Spengler cyclization reactions. Particularly in the cases of 2-alkyl-N-benzylidene-2-phenethylamines, an enhanced stereoselectivity was observed under the superacid conditions as compared with the corresponding weak acid (TFA)-catalyzed (monocationic) cyclization reaction of the N-benzylidene-2-(3',4'-dimethoxy)phenethylamines that bear electron-donating groups on the cyclizing aromatic ring. The computational study also supported the energetic favorability of the cyclization of the N,N-diprotonated imine and revealed a significantly early transition-state structure.
    Organic Letters 07/2003; 5(12):2087-90. · 6.32 Impact Factor

Publication Stats

12 Citations
6.32 Total Impact Points

Top Journals


  • 2003
    • The University of Tokyo
      • Faculty and Graduate School of Pharmaceutical Sciences
      Edo, Tōkyō, Japan