Article

Unassisted eta2-coordination of polycyclic aromatic hydrocarbons to platinum(II).

Instituto de Ciencia de Materiales de Aragón, Facultad de Ciencias, Universidad de Zaragoza-C.S.I.C., C/Pedro Cerbuna 12, E-50009 Zaragoza, Spain.
Inorganic Chemistry (impact factor: 4.6). 11/2005; 44(21):7265-7. DOI:10.1021/ic050405q pp.7265-7
Source: PubMed

ABSTRACT The coordination of phenanthrene to the d8 Pt(II) center in (SP-4-2)-[Pt(C6F5)2(CO)(eta2-C14H10)] causes a slight pyramidalization at the metal-bound C atoms (C9 and C10), but no perceptible elongation of the corresponding C-C bond [C(13)-C(14) 132.0(5) vs. 133.8(5) pm in the free ligand].

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Keywords

metal-bound C atoms
 
perceptible elongation
 
slight pyramidalization