Synthesis and Structural Characterization of a Stable Dimeric Boron(II) Dication

Anorganisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany.
Angewandte Chemie International Edition (Impact Factor: 11.26). 12/2007; 46(47):9110-3. DOI: 10.1002/anie.200703616
Source: PubMed


Bor-muda triangle: The first representative of a new type of boron cation is formed as the product of the reaction between B2Cl2(NMe2)2 and the guanidine derivative hppH (see scheme). The BB bond length is typical for a single bond, and both boron atoms and the hpp nitrogen atoms bound directly to them form a trigonal prism.

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